NEC TOKIN America Inc. Sep. 2016
What is a Super capacitor? When two different phases of solid and liquid come into contact, positive and negative charge are distributed confronting each other in a very small distance on the boundary surface. A layer which spreads in the vicinity of this boundary surface is called the Electrical Double Layer. Electric Double Layer Conventional type of Caps Electro Double Layer Capacitor Rechargeable Battery 1uF 10mF 1F 100F 10000F 2
What is EDLC (Super capacitor)? Power Density (W/kg) Al electrolytic capacitor Electric Double Layer Capacitor (EDLC, Supercap) Secondary Battery Energy Density (Wh/kg) EDLC: Relatively High Energy Density & High Power Density 3
Comparison of Energy Storage Devices Energy Storage Principle Operating Temperature Super Capacitors Aluminum Electrolytic Caps Electric Double Layer Dielectric Polarization Ni-Cd Batteries Chemical Reaction Lithium Rechargeable Batteries Chemical Reaction -40 C to 85 C -40 C~+105 C -10 C to 65 C -20 C to 50 C Working Voltage 1.8V to 18V 6.3V~ 1.2V ~3V Energy Density (Wh/kg) 0.5-5 <0.1 50-80 100-150 Charging time Several seconds Several seconds Several hours Several hours Charging Current Limitation Restrictions on Charge/Discharge Automated Mounting Material Safety Failure Mode None None Limited Limited Infinite Infinite Limited 1000 times Applicable (FC & FM series) No harmful Material Open Nothing further (safe) Limited 1000 times Applicable Not Applicable Not Applicable No harmful Material Short Heating, Explosion Cadmium Short Heating, Explosion No harmful Material Short Ignition, Explosion Liquid leakage 4
Battery or Super cap? - Super cap Advantages Maintenance free Simple installation (5.5V SMD available) Wide operating temperature -40 C to 85 C Available Quick charging Infinite Charge/Discharge cycle Open Failure Mode No damage with reverse voltage (No polarity except Organic Electrolyte type) Environmentally Friendly-No use of hazardous material such as Cd and Pb 5
Why NEC TOKIN Super capacitor? NEC TOKIN Competitors Temperature Widest Operating Temp. Range -40ºC ~ +85ºC Guarantee* @ 5.5V Rating -20ºC ~70ºC -40ºC ~ +85ºC @ 3.5V, limited voltage condition Life Moisture, Shock Resistant Rubber Vulcanization Process Sealing Longer life: Aqueous Type Gasket Sealing Weak for Moisture, Shock Shorter life: Organic Type Cost Saving Mounting Cost SMD 5.5V Product Available SMD 3.5V rating only. Failure Mode OPEN Short 6
Structure of Super Capacitor (Aqueous electrolyte type) Standalone Type Can Case Outer Case Capacitor Base Cell Conductive Current Collecting Electrode Sealing Synthetic Rubber Capacitor Base Cell Isolation Case Sleeve Pins Resin Mold Type (FM series) Mold material Polybutylene Terephthalate(PBT) Automatic mounting Separator (porous organic film) Activated Carbon+Electrolyte (Dilute Sulfuric Acid) Pins Capacitor Base Cell FC series Surface mounting Outer Case Capacitor Base Cell Isolation Case 7 Plate Pins
NEC TOKIN Advantages in Derating NEC TOKIN: Cell structure Max. voltage per cell = 1.2Vmax/cell Conductive Current Collecting Electrode Conductive current collecting Synthetic rubber for sealing Sealing synthetic Separator Activated carbon + Electrolyte (Dilute Sulfuric Acid) Aqueous type (5.5V rated part) Separator (porous organic film) Activated carbon + electrolyte (dilute sulfuric acid) Competitor: Cell structure Max. voltage per cell = 3.0Vmax/cell Activated carbon Cap Case ケース Separator Gasket sealing Organic type (5.5V rated part) 2.750V/cell 2.750V/cell 2 cells About 30% margin/cell 6 cells Can case type About 8% margin/cell Coin type
NEC TOKIN Advantages in Sealing NEC TOKIN: Aqueous type basic cell structure; Competitor: Organic type basic cell structure Rubber cross-link bonding Conductive current collecting electrode Sealing Synthetic Rubber Separator (Porous Organic Film) Activated Carbon + Electrolyte (Dilute Sulfuric Acid) Activated carbon + Aqueous electrolyte Tight sealing by rubber cross-link bonding. Aqueous electrolyte = High moisture resistance Cross-link bonding = Strong shock resistance Cap Electrode Gasket (Packing) Porous Separator Electrode Case Gasket packing Activated carbon + Organic electrolyte Gasket packing sealing Organic electrolyte = Low moisture resistance Gasket packing = Low resistance to shock
Life Time Comparison Supercap vs. Organic Type Electric Double Layer Capacitor Supercapacitor NEC/TOKIN Aqueous Type EDLC has LONGER life. Organic Type Electric Double Layer Cap 10
Open Failure Mode Open Failure Mode Does not damage other components in circuit No heat generated What happens: Gas forms in electrode, between the electrode and activated carbon remained The remained activated carbon increases ESR, finally opened circuit No leakage of acid COMPETITION: Conductive Current Collecting Electrode Activated Carbon & Dilute Sulfuric Acid, H2SO4 Sealing is broken down and causes leakage, finally causes a short circuit. Base Cell 11
Product Line-Up Current Power Low ESR High ESR A ma μa For Low Impedance Application - Aqueous Type FE, FA, FS, FT, FME HV Large Capacitance - Organic Type Other Application - Aqueous Type FY, FG, FC, FM, FR Super Capacitors Time 1 Minute 1 Hour 1 Day 1 Week 1 Month 1
Focused Products (Aqueous electrolyte type) OLD Series NEW Series: FYH FYD FYL FA FE µa current applications FR 5.5V Up to 1F FG 3.5 V to 5.5V Up to 4.7F FT 5.5V Up to 5.6F FGR 5.5V Up to 2.2F FGH 3.5 V to 5.5V Up to 1F ma current applications FS 5.5 V to 12V Up to 5F High Temp (85º C) Lower Profile Smaller size & Better Performance FM FMR type 5.5V Up to 0.33F FC 3.5 V to 5.5V Up to 1F FCS 3.5 V to 5.5V Up to 0.47F In Red: Promotion Products : -40º C to 85º C Products, ** For FCS, 240hour guarantee : -25º C to 70º C Products ** Automatic mounting Surface mounting Reflow Peak 235ºC Surface mounting Reflow Peak 260ºC 13
Summary Technical Advantage of Supercap No Maintenance Infinite Charge/Discharge Cycle Fast Charge/Discharge Cycle No Charge Current Limit NEC TOKIN Supercap Advantage Open Failure mode = Safe (Competitors: Short failure mode) Better sealing technology=longer Life -40 C~85 C Operating Temperature Range Available SMD = Saving mounting cost Product Focus FC, FCS Series for SMD µa Current Backup FM Series for Automatic mounting µa Current Backup FG Series FGR type for µ A Current Backup, -40 C~85 C Temp. Range FT Series for ma Current Backup, -40 C~85 C Temp. Range 14
Product Slides 15
Part Number FC Series(FCS type) for Surface Mounting Features Reflow 260 C Operating Temperature Range -40 C to 85 C High Rated Voltage 5.5V, and 3.5V available Applications µa Memory Backup Power Supply Line Backup Max. Rated Voltage (Vdc) Nominal Capacitance (F) Max. ESR (at 1kHz) (Ω) ΦD Height max. FCS0H473ZF 5.5 0.047 100 10.7 5.5 FCS0H104ZF 5.5 0.10 50 10.7 5.5 FCS0H224ZF 5.5 0.22 50 10.7 8.5 FCS0V104ZF 3.5 0.10 100 10.7 5.5 FCS0V224ZF 3.5 0.22 50 10.7 5.5 FCS0V474ZF 3.5 0.47 50 10.7 8.5 16
Machine Pickable FM Series in Ammo Pack Features Resin-mold Automatic Assembly -40ºC~85ºC Temp. Range for FMR series. Application µa Backup Part Number Max. Rated Voltage (Vdc) Nominal Capacitance (F) Max. ESR(at 1kHz) (Ω) Dimension typ. FM0H103ZF / 223ZF / 473ZF 5.5 0.010 / 0.022 / 0.047 300 / 200 / 200 10.5 x 11.5 X 5.0 FM0H104ZF / 224ZF 5.5 0.10 / 0.22 100 / 100 10.5 x 11.5 X 6.5 FM0V473ZF / 104ZF 3.5 0.047 / 0.10 200 / 100 10.5 x 11.5 X 5.0 FM0V224ZF 3.5 0.22 100 10.5 x 11.5 X 6.5 FM0J473ZF 6.5 0.047 200 10.5 x 11.5 X 6.5 FMC0H473ZF 5.5 0.047 100 10.5 x 11.5 X 5.0 FMC0H104ZF 5.5 0.10 50 10.5 x 11.5 X 6.5 FMC0H334ZF 5.5 0.33 25 14.0 x 15.0 X 9.0 FMC0H334ZF-R (85ºC rated) 5.5 0.33 25 14.0 x 15.0 X 9.0 FMR0H473ZF (85ºC rated) 5.5 0.047 200 10.5 x 11.5 X 6.5 FMR0H104ZF (85ºC rated) 5.5 0.10 50 10.5 x 11.5 X 6.5 FMR0V104ZF (85ºC rated) 3.5 0.10 50 10.5 x 11.5 X 6.5 18
FME / FML Series in Ammo Pack Features Resin-mold Lower ESR than FM type Automatic Assembly Application ma Backup Part Number Max. Rated Voltage (Vdc) Nominal Capacitance (F) Max. ESR(at 1kHz) (Ω) Dimension typ. FME0H223ZF 5.5 0.022 40 10.5 x 11.5 X 5.0 FME0H473ZF 5.5 0.047 20 10.5 x 11.5 X 5.0 FML0H333ZF 5.5 0.033 6.5 10.5 x 11.5 X 5.0 19
85ºC Rated FR Series (µa current backup) Features Wide Operating Temperature Range -40ºC~85ºC Applications Memory Backup Motors, Actuator etc. (for high current loads) Part Number Max. Rated Voltage (Vdc) Nominal Capacitance (F) Max. ESR (at 1kHz) (Ω) ΦD Height max. FR0H223ZF 5.5 0.022 220 11.5 14.0 FR0H473ZF 5.5 0.047 110 14.5 14.0 FR0H104ZF 5.5 0.10 150 14.5 15.5 FR0H224ZF 5.5 0.22 180 14.5 21.0 FR0H474ZF 5.5 0.47 100 16.5 21.5 FR0H105ZF 5.5 1.0 60 21.5 22.0 20
85ºC Rated FT Series (ma current backup) Features Low ESR Wide Operating Temperature Range -40ºC~85ºC Applications ma Memory Backup, Motors, Actuator etc. (for high current loads) Part Number Max. Rated Voltage (Vdc) Nominal Capacitance (F) Max. ESR (at 1kHz) (Ω) ΦD Height max. FT0H104ZF 5.5 0.10 16 11.5 8.5 FT0H224ZF 5.5 0.22 10 14.5 12.0 FT0H424ZF 5.5 0.47 6.5 16.5 13.0 FT0H105ZF 5.5 1.0 3.5 21.5 13.0 FT0H225ZF 5.5 2.2 1.8 28.5 14.0 FT0H335ZF 5.5 3.3 1.0 36.5 15.0 FT0H565ZF 5.5 5.6 0.6 44.5 17.0 21
12V Available FS Series (ma current backup) Features 5.5V, 11V, 12V Available Applications ma Memory Backup, Motors, Actuator etc. (for high current loads) Part Number Max. Rated Voltage (Vdc) Nominal Capacitance (F) Max. ESR (at 1kHz) (Ω) ΦD Height max. FS0H223ZF 5.5 0.022 60 11.5 8.5 FS0H473ZF 5.5 0.047 40 13.0 8.5 FS0H104ZF 5.5 0.10 25 16.5 8.5 FS0H224ZF 5.5 0.22 25 16.5 13.0 FS0H474ZF 5.5 0.47 13 21.5 13.0 FS0H105ZF 5.5 1.0 7 28.5 14.0 FS1A474ZF 11.0 0.47 7 28.5 25.5 FS1A105ZF 11.0 1.0 7 28.5 31.5 FS1B105ZF 12.0 1.0 7.5 28.5 38.0 FS1B505ZF 12.0 5.0 4 44.8 60.0 22
85ºC Rated FGR Series (µa current backup) Features Operating Temp Range: -40ºC~85ºC Applications µa Memory and RTC Backup Part Number Max. Rated Voltage (Vdc) Nominal Capacitance (F) Max. ESR (at 1kHz) (Ω) ΦD Height max. FGR0H474ZF 5.5 0.47 120 14.5 18.0 FGR0H105ZF 5.5 1.00 65 16.5 19.0 FGR0H225ZF 5.5 2.2 35 21.5 19.0 23
FG Series(µA current backup) Features Low Leakage Current Operating Temp Range: -25ºC~70ºC 5.5V and 3.5V Available Applications µa Memory and RTC Backup Part Number Max. Rated Voltage (Vdc) Nominal Capacitance (F) Max. ESR (at 1kHz) (Ω) ΦD Height max. FG0H103ZF 5.5 0.010 300 11.0 5.5 FG0H223ZF 5.5 0.022 200 11.0 5.5 FG0H473ZF 5.5 0.047 200 11.0 5.5 FG0H104ZF 5.5 0.10 100 11.0 6.5 FG0H224ZF 5.5 0.22 100 13.0 9.0 FG0H474ZF 5.5 0.47 120 14.5 18.0 FG0H105ZF 5.5 1.00 65 16.5 19.0 FG0H225ZF 5.5 2.2 25 21.5 19.0 FG0H475ZF 5.5 4.7 35 28.5 22.0 FG0V155ZF 3.5 1.5 65 16.5 14.0 24
FGH Series Lower Profile Features Low Profile compared with FG series Operating Temp Range: -25ºC~70ºC Applications µa Memory and RTC Backup Part Number Max. Rated Voltage (Vdc) Nominal Capacitance (F) Max. ESR (at 1kHz) (Ω) ΦD Height max. FGH0H104ZF 5.5 0.10 100 11.0 5.5 FGH0H224ZF 5.5 0.22 100 11.0 7.0 FGH0H474ZF 5.5 0.47 65 16.5 8.0 FGH0H105ZF 5.5 1.0 35 21.5 9.5 25
FC Series(FC type) for Surface Mounting Features Peak Reflow at 235 C Operating Temperature Range -25 C to 70 C High Rated Voltage 5.5V, and 3.5V available Applications µa Memory Backup Power Supply Line Backup Part Number Max. Rated Voltage (Vdc) Nominal Capacitance (F) Max. ESR (at 1kHz) (Ω) ΦD Height max. FC0H473ZFTBR24 5.5 0.047 50 10.5 5.5 FC0H104ZFTBR24 5.5 0.10 25 10.5 5.5 FC0H224ZFTBR24 5.5 0.22 25 10.5 8.5 FC0H474ZFTBR32-SS 5.5 0.47 13 16.0 9.5 FC0H105ZFTBR44-SS 5.5 1.0 7 21.0 10.5 FC0V104ZFTBR24 3.5 0.10 50 10.5 5.5 FC0V224ZFTBR24 3.5 0.22 25 10.5 5.5 FC0V474ZFTBR24 3.5 0.47 25 10.5 8.5 26
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