Tadiran Lithium Battery Packs for Long Term Ocean Deployments Lee Gordon Doppler Ltd. 858-486-4077 lee@dopplerltd.com Alkaline Pack for a Doppler Profiler Long Term Ocean Deployments Duration: weeks to years Instruments alternate low power standby and high power operation Instrumentation is often designed for alkaline battery packs, then investigators decide they want more Replacement PulsesPlus Lithium Pack With 3x the Capacity
Voltage Curves for a Typical Doppler Profiler Deployment 45 Voltage (VDC) 40 35 30 25 Alkaline Lithium 20 0 20 40 Time (days) 60 Everything about the deployment setup is the same, only the duration changes.
Capacity vs. Duration @ 20 C 20C 2500 2000 Capacity (WHr) 1500 1000 500 TL4930 TL5930 TL6930 0 0.0 5.0 10.0 15.0 20.0 Duration (months) TL6930 D Primary Cell Capacity depends on current, which depends on duration (shorter duration deployments using higher current)
Capacity vs. Duration @ 0 C 0C 2500 2000 Capacity (WHr) 1500 1000 500 TL4930 TL5930 TL6930 0 0.0 5.0 10.0 15.0 20.0 Duration (months) TL6930 D Primary Cell
Capacity vs. Temperature 250 200 25C 0C 25C D-Cell Capacity (kj) 150 100 0C 25C 50 0C 0 TL6930 Spiral Alkaline TL6930 D Primary Cell TL6930 self discharge at 25ºC is 0.7% while spiral and alkaline cells have 3% self discharge.
Hybrid Layer Capacitors (HLCs): Capacitors or Rechargable Lithium Cells? Stored charge (Coulombs) 1200 1000 800 600 400 200 0 1400F dv dt 500F = i C = 1 dq C dt 0 0.5 1 1.5 2 2.5 3 3.5 4 HLC voltage (VDC) 1400F HLC1550A 500F HLC1550A (AA) ~1 A 10 min 3.9-3.5 VDC HLC1520A (0.4 AA) ~0.25 A 10 min 3.9-3.5 VDC HLCs are rechargeable lithium cells, but over narrow voltage ranges, they behave like high-value capacitors.
Voltage Curves for a Typical Doppler Profiler Deployment Branch 3 5 1 2 4 7 Schematic of a typical PulsesPlus battery pack. 1: Primary lithium cells 2: HLC 3,4: Schottky diode 5,6: PTC (positive temperature coefficient thermistor) 7: Voltage cut-off circuit 6 Cells are organized by branches instead of strings. A branch holds primary cells, wired in parallel, which charge one or more HLCs. Tadiran PulsesPlus cells and packs have no fuses. PTCs protect like fuses that reset automatically when you remove the overload.
Cutoff circuit Turns off the pack when it is about 97% depleted to prevent reverse currents in branches. The pack holds the remaining charge for more than a decade. Uses insignificant battery power (much less than the battery pack s self discharge). Protects against short circuits (but not too hastily!). It cuts off the pack after 100 µs at >8 A and turns the pack back on when the load is removed. Provides an LED status indicator (pack OK and new, used, or depleted). Simply short the pack to run this test. Internally records voltage and temperature to provided estimates of how much of the pack s capacity has been consumed. This circuit is primarily useful for production ocean instrumentation. If you are confident you can recover your system before the pack depletes, you do not need one.
Model Schematic Battery Primary Cell HLC Steady Load Pulse Load 100Ω 0.1Ω 1M 300Ω 12V 0.1F On 1 s, off 9 s This model is not intended to reproduce a specific battery pack, but rather is intended to illustrate how HLCs enable the pack to supply more of its capacity to the instrument as opposed to internal dissipation.
Model Results: Comparison With & Without the HLC Dissipation (W) 0 10 10-1 10-2 10-3 10-4 10-5 Battery Load HLC Battery 3.3 % HLC 0.03 % 10-6 10-7 0 2 4 6 8 10 12 14 Load 97.7% 0.30 0.25 Battery Load Dissipation (W) 0.20 0.15 0.10 Battery 25 % 0.05 0.00 0 2 4 6 8 10 12 14 Time (s) Load 75% Without the HLCs, 25% of the battery capacity is dissipated by the primary cell s internal resistor. With the HLCs, the internal dissipation drops to 3% and most of the energy goes to the instrument.
Anode (Lithium) Electrolyte Cathode Insulator Differences Between Low Current and High Current Primary Cells Spiral Wound Primary Cell (High Current) Bobbin Primary Cell (Low Current) Bobbin cells are simpler, less expensive and, because they hold more lithium, they store more energy. Spiral-wound cells supply high currents by building the battery in sheets. The large surface area also increases selfdischarge and increases the chance of shorts between the cathode and anode. The ability to source high currents mean that shorts can become explosive.
Hermetic Seal Prevents Leakage and Outgassing Glass seal between anode and lid Laser weld between lid and can
Pack Mechanical Design Lithium Packs need just a little more room, so plan ahead Lithium cell AA HLCs 1 mm gaps 2.5 mm Alkaline cell AAA HLCs no gaps