ON THE POSSIBILITY TO IMPROVE COMMERCIAL VEHICLE SI ENGINE OPERATION WHEN FUELED BY HYDROGEN DIRECT INJECTION

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ON THE POSSIBILITY TO IMPROVE COMMERCIAL VEHICLE SI ENGINE OPERATION WHEN FUELED BY HYDROGEN DIRECT INJECTION *Alexandru RACOVITZA a, Bogdan RADU a, Radu CHIRIAC a, a University POLITEHNICA Bucharest, 313 Splaiul Independentei, sect.6, Bucharest 060042, Romania Dept. of Thermodynamics, Engines, Thermal and Refrigerant Systems *Corresponding author: alexandru_racovitza@yahoo.com Abstract. The use of the spark ignition engines for passenger cars under the more and more restrictive and difficult in reaching emissions legislation standards seams to become attractive for the next period. The new technologies of fueling and air-fuel mixtures formation as stratified charges by gasoline and hydrogen in-cylinder direct injection, associated with methods of downsizing and downspeeding offer new perspectives to increase spark ignition engines efficiency. H2- O2 type fuels, with low spark-energy requirement, wide flammability range and high burning velocity maintain as important candidates for being used as fuels in spark-ignition engines, also offering CO2 and HC free combustion and lean operation resulting in lower NOx emissions. The present work is linked to a research project dedicated to the characteristics simulation study of a commercial Renault K7M710 engine fueled with Hydrogen using Direct Injection, by applying AVL BOOST simulation code. Keywords: SI Engine, Gasoline and Hydrogen Direct Injection, Efficiency, Low Emissions. 1. INTRODUCTION With the introduction of more restrictive emissions legislation and fuel economy standards, significant effort is being made to improve spark ignition gasoline engines efficiency because of their dominant use for passenger cars and better potential for market adaptation. Modern trends adopted by SI engines manufacturers are related to the use of gasoline direct injection (GDI) combined with downsizing and downspeeding concepts in order to reduce fuel consumption despite the obvious constrains of excessive thermal and mechanical loads, leading to knocking combustion and low-speed pre-ignition. To overcome these effects, one distinctive category of studies is related to variable valve timing (VVT) cycle operation using variable valves overlap with every engine speed regime [5]. A reduction of the main exhaust emissions levels has been experimented applying exhaust gas recirculation (EGR) when operating a turbocharged SI engine using gasoline direct injection (GTDI). At high load conditions similar analysis and conclusions to the partial load ones are obtained. The EGR also allowed the combustion to be phased in a more efficient angle by reducing the risk of knocking, which helped reduce the exhaust gas temperature, despite the elimination of the fuel enrichment strategy. A reduction on CO and soot raw emissions was also obtained when introducing EGR, as at partial load conditions, but a high reduction in NO x, CO, HC and soot emissions was observed after the catalyst since the fuel enrichment strategy is eliminated when cooled EGR is introduced. Results confirm that introducing EGR is a suitable strategy to control knocking and reduce simultaneously exhaust gas temperature and fuel consumption [6]. With the increasing use of direct injection, particulate emissions from gasoline engines have also become a subject of exhaust emission legislation. A key focus is on considering the health effects of particles and their accumulated components, such as polycyclic aromatic hydrocarbons (PAH) [7]. The recent introduction of a Particle Number (PN) limit of 6 10 11 km 1 for all Direct Injection Gasoline (GDI) vehicles registered in Europe after September 2017, is

expected to necessitate a widespread application of Gasoline Particulate Filters (GPF) [8]. Among other fuels alternatively used in SI direct injection engines, hydrogen and hydrooxygenated compounds improve the combustion characteristics in terms of better brake thermal efficiency (BTE) and emissions levels. An experimental investigation on effects of hydrogen fractions (less equal to 11% by mass) on lean burn combustion and emission characteristics of SI gasoline engine was conducted on a modified premixed gasoline engine equipped with a hydrogen direct-injection system, under values of relative air-fuel ratio in-between 1.0 and 1.5. With the increasing hydrogen addition fraction, the combustion speed increases, mean effective pressure and thermal efficiency are improved. Moreover, flame development and propagation duration are shortened, the peak firing pressure increases and its corresponding crank angle also increases, together with the maximum rate of heat release, the maximum mean gas temperature and the maximum rate of pressure rise, leading to HC and CO emissions decrease and oppositely to NO x emission increase. As known, hydrogen direct injection does not reduce volumetric efficiency, therefore engine power performance improves. The addition of hydrogen enables stable combustion at 1.5 relative air-fuel ratio and the BTE increases, along with a significant reduction in CO and NO x [9]. Hydrogen fuel source could be provided by exhaust gas reforming by thermochemical energy recovery technology with potential to improve gasoline engine efficiency. The principle relies on achieving energy recovery from the hot exhaust stream by endothermic catalytic reforming of gasoline and a fraction of the engine exhaust gas. The reformatted hydrogen is routed back by recirculation into the intake manifold, the method being known as reformed exhaust gas recirculation (REGR) [10]. An experimental research where gasoline-air mixture was enriched with Hydrogen Rich Gas (HRG) produced by electrical dissociation of water has been carried out on a passenger car SI engine at light and partial loads. Thus, the addition of HRG has been deduced to have a positive effect on the global combustion process, reducing CO and HC emissions while the maximum relative air-fuel ratio value of 1.2 was a limit imposed by engine running stability [11]. Moreover, a following investigation was conducted to establish the effects of adding HRG to a LPG fuelled SI engine, pushing up to even leaner limits the air-fuels mixtures (1.65). The new HRG gas had been obtained by a special alkaline dynamic electrolysis of water, under high process efficiency. Its chemical analysis shown the presence of 64...67% (vol.) H 2, 31...33% O 2 and 0...5% other H 2-O 2 constituents. The results highlighted that HC, CO and CO 2 emissions decreased, while NO x generally remained high [12]. In another study it was experimentally investigated the effect of hydroxygen (H 2+O 2) addition on performance and emissions of a gasoline engine. Flow rate of hydroxygen gas mixture was adjusted to 0%, 3.75% (2.5% H 2+1.25% O 2) and 7.5% (5% H 2+2.5% O 2) byvolume of intake charge for entire speed range of the engine and subsequently water was injected into the intake manifold of the SI engine to decrease NO x emissions which were significantly increased with hydroxygen addition. Mass flow ratio of water with respect to gasoline was kept constant as 0.25/1. According to the tests, carried out at 50% load and engine speeds between 1500 and 5000 rpm, total hydrocarbons, oxides of nitrogen and carbon monoxide were measured and COV imep, brake power, brake thermal efficiency and BSFC were calculated. Thus, brake power, brake thermal efficiency and nitrogen oxides were increased up to 11.7%, 5.9% and 141.1%, whereas COV imep, BSFC, total hydrocarbons and carbon monoxide were decreased down to 15.2%, 5.6%, 74.5% and 59.5%. The maximum increase of NO x emission with hydroxygen addition was decreased from 141.1% to 82.7% with water injection [13]. 2. PROPOSED SI ENGINE MODIFICATIONS FOR GASOLINE AND H 2 INJECTION The simulation research assisted by AVL Boost software package [4] started from the features of a commercial passenger car SI engine, the Renault- Logan K7M710 1.6L type, which has been converted to a turbocharged and direct injection configuration in order to reveal the comparison between both performance and efficiency characteristics. The analysed engine, naturally aspirated and provided with a multipoint indirect fuel injection system initially featured: 4 cylinders in-line, 79.5 mm bore, 80.5 mm stroke, 9.5:1 compression ratio, 1595 cm 3 total displacement, maximum power of 64 kw at 5500 rpm, maximum torque of 128 Nm at 3000 rpm.

The modifications brought to the initial engine consisted in installing a turbocompressor group, switching from indirect injection to direct injection, together with decreasing the compression ratio and slightly increasing the maximum engine speed. Considering these, the new obtained turbocharged direct injected engine highlighted: 96 kw rating power at 6000 rpm, 145 Nm rating torque at 4500 rpm, 4-in-line cylinders, 79.5 mm bore, 82.5 mm stroke, 9:1 compression ratio, 1597 cm 3 total displacement, a configuration very similar to Ford Escort RS 1.6 l Turbo [14,15]. The compressor delivers to the engine 1.6 bar turbocharging pressure and the maximum pressure for gasoline direct injection is 100 bar in comparison with 67 bar for the original engine. and to 54% at 5500 rpm. At 5000 rpm, for the direct injection engine, the rated power was 97 kw, compared to 64 kw, which is the top value for the original engine. The maximum torque highlighted value, for the modified engine is 181 Nm at 3100 rpm, while in the case of the original K7M710 engine the corresponding top value is 128 Nm at 3000 rpm [14,15]. For the modified engine, at full load and 5500 rpm engine speed, the peak pressure value is 81 bar and the IMEP is 15.4 bar, while in the case of the original engine, the maximum pressure is 67 bar and the IMEP is 10.6 bar. Modelling the processes from the turbocompressor group implies the use of the AVL Boost v.2013.1 computer programs. The equations refer to the conservation of the global energy exchanged from the inside to the outside of the cylinder and to the heat and mass flows through the inlet and outlet systems. At this point, a Wiebe type relation has been proposed to describe the heat release from the cylinder and a Woschni type formula (1990) to express the heat transfer to the cylinder surroundings. The mass flow is given by the equations of sonic and subsonic flow through the valves as by the injection characteristic imposed to the gasoline injector [14,15]. The schematic of the entire functional engine resulted from the analysis of all system components and connecting elements is shown in Fig.1. The above described engine configuration is further modified in order to find the most effective strategy to ensure H 2 direct injection together with the gasoline direct injection. The theoretical schematic of the engine to be fuelled in parallel with gasoline and hydrogen by parallel direct injections is plotted in Fig.2 [15,16,17]. The simulation of both engines performances using the AVL Boost software package [4] allows the direct comparison of the rating power, rating torque, indicated mean pressure (IMEP) and brake specific fuel consumption (BSFC) for a range of engine speeds within 750 rpm and 5500 rpm. Figure 3 shows the variation of the effective power versus the engine speed. Comparing these values, a continuous increase could be noticed for the turbocharged engine for all the analysed speed range, from 30% at 1000 rpm, to 48% at 3000 rpm Fig. 1. GDI turbocharged engine (AVL BOOST schematic) Fig. 2. Schematic of SI Engine fueled by gasoline and hydrogen direct injection

3. RESULTS OBTAINED BY GASOLINE AND HYDROGEN SI ENGINE FUELING The theoretical simulation work has been completed in order to reveal the potential of using small to high hydrogen fractions (2,5,10,20,50 and 100% mass.) in SI direct injection engine regarding the increase of its performances and efficiency together with the drop of the main emissions. The first conclusions are encouraging the use of high percentages of hydrogen within the full range of engine speeds, theoretically being verified that the higher the hydrogen fractions are used the better the engine operational results become. Figure 3 shows the variation of the rating power for several used hydrogen mass fractions, at full load, within the entire scale of engine speeds. What is to be remarked is the significantly increase of the power with the increase of the Hydrogen percentage. As a result, starting with the use of small amounts of H 2 up to 100% gasoline replacement, comparing to G100 (no Hydrogen), the gain of power is from 1.3 % at 2% H 2 until 28.3% at H100 (only Hydrogen). This increase of the power is based both on the increase of the BMEP values, which rise in percents from 1.3% at 2% H 2 to 28.3% at H100. (see Fig.4) and on the increase of the maximum firing pressure values, increasing from 0.7 % at 2% H 2 until 16.3% at H100 (see Fig.5). These variations are subsequent to that of the maximum rate of the firing pressure, which could be always kept under a maximum limit of approximately 5 bar/deg.ca, being avoided a rough engine running (see Fig.6). The variation of the rated torque with the engine speed at full load respecting the chosen H 2 mass fractions could be also explained by the variation of the top firing pressure, being connected with that of BMEP and overall influenced by the variation of the rated power. As Figure 7 shows, for all hydrogen fractions the calculated values for the torque maintain the trendline of the values for G100, with the top value corresponding to 3000 rpm. Like the rated power values, the rated torque values increase in percents from 1.3% at 2% H 2 proportion to 28.3% at H100. Fuel economy is well improved by the use of greater hydrogen mass fraction because of its much higher lower heat value (LHV) comparing to that of gasoline. The increasing obtained rating powers together with the higher energetic fuel fractions lead to significant reduction of BSFC. Its minimum value for G100 (no hydrogen) is obtained at 2000 rpm, same engine speed for all the bottom values of BSFC, independently of the hydrogen used fraction. In percentages, the minimum BSFC drops continuously by hydrogen substitution as for example with 4% when the substitution degree is 2% up to 65% when gasoline is completely replaced by hydrogen - 100% H 2 (see Fig.8). Such important reduction in BSFC is equivalent to an increase in the engine brake efficiency of only 20% due to the important difference existing in the lower heating values of the two pure fuels. The main types of SI engine emissions (especially CO and NO x) are decreasing by using higher amounts of hydrogen, this being one of the basic goals assumed by this simulation work. Regarding the variation of NO x concentration from the exhaust gas, this is varying from a reduction by 2% at 2% H 2 fraction to a maximum decrease of 46% at H100, compared to the use of gasoline only (as revealed in Fig. 9). Although the numbers dispersion is high, the main effect of using higher H 2 percentages also occurs in reducing the CO concentration even at high engine speeds, being practically eliminated when using H100 (see Fig.10).

130 120 110 100 90 80 70 60 Pe Pe G98%H2% Pe Pe Pe Pe Pe G50% H50% G98%H2% Pe [kw] 50 40 30 20 Fig. 3. Variation of the rated power vs. engine speed at full load 22 21 20 19 18 17 16 15 14 13 BMEP [bar] BMEP BMEP G98%H2% BMEP BMEP BMEP BMEP BMEP G100 12 Fig. 4. Variation of BMEP vs. engine speed at full load 110 105 100 95 pmax [bar] pmax pmax G98%H2% pmax pmax pmax pmax pmax G98%H2% 90 85 80 75 Fig. 5. Variation of the maximum firing pressure vs. engine speed at full load

5.2 5 4.8 4.6 4.4 4.2 4 3.8 3.6 3.4 3.2 3 dp/da max [bar/deg] dp/da max dp/da max G98%H2% dp/da max dp/da max dp/da max dp/da max dp/da max 2.8 Fig. 6. Variation of the maximum firing pressure rate vs. engine speed at full load 300 280 260 240 220 Me [Nm] Me Me G98%H2% Me Me Me Me Me 200 180 160 140 Fig. 7. Variation of rated torque vs. engine speed at full load BSFC [g/kwh] 300 275 250 225 200 175 150 BSFC BSFC G98%H2% BSFC BSFC BSFC BSFC BSFC G98%H2% 125 100 75 50 Fig. 8. Variation of BSFC vs. engine speed at full load

13 12 11 10 9 NOx NOx G98%H2% NOx NOx NOx NOx NOx NOx [g/kwh] 8 7 6 5 4 Fig. 9. Variation of NOx vs. engine speed at full load 1.4 1.2 1 0.8 0.6 CO CO G98%H2% CO CO CO CO CO G98%H2% CO [g/kwh] 0.4 0.2 0 4. CONCLUSIONS Fig. 10. Variation of CO vs. engine speed at full load substitution degree and is determined by carbon replacement with hydrogen; The results of this study can be summarized in the following conclusions: 1. The substitution of gasoline by hydrogen in direct injection operating mode for the spark ignited engines could improve both maximum power and efficiency; 2. The increase of engine output is associated with the increase of the indicated high pressure trace area for similar stoichiometric mixture operation maintaining the maximum peak pressure rise under a safety threshold; 3. The reduction of CO emission is encountered for the whole engine speed range investigated, is more pronounced with the increase of the 4. The reduction of NOx emissions which seems apparently surprising for higher level of substitution degree could be explained by the reduced oxygen mass fraction available for NO formation resulted in the case of increased fractions of hydrogen; this is probably determined by the increased reactivity of hydrogen which consumes in stoichiometric combustion a large amount of oxygen from the same air flow rate as in the case of pure gasoline or in the cases with reduced fractions of hydrogen.

ACKNOWLEDGMENTS The authors of this paper acknowledge the AVL Advanced Simulation Technologies team for its significant support offered to them in performing the simulation part of this work. REFERENCES [1] Mohannadi A., Shoji M., Nakai Y., Ishikura W., Tabo, E., Performance and combustion characteristics of direct injection SI hydrogen engine, International Journal of Hydrogen Energy, 32, 296-304, 2007. [2] Wu Z.-J., Yu X., Fu L.-Z., Deng J., Hu Z.-J., Li L.-G., A high efficiency oxyfuel internal combustion engine cycle with water direct injection for waste heat recovery, ELSEVIER Energy 70, 110-120, 2014. [3] Klein D.J., Dica C., Georgescu C., Pamfilie C.,Chiriac R., Method of using lean air-fuel mixtures al all operating regimes of a SI engine, US Patent no. US008127750B2 /March 6, 2012. [4] AVL BOOST Theory and AVL BOOST UsersGuide, https://www.avl.com/ro/boost [5] Macklini D.N., Zhao H., High load performance and combustion analysis of a four-valve direct injection gasoline engine running in the two-stroke cycle, ELSEVIER, Applied Energy 159,117 131, 2015. [6] Lujan J.M., Climent H., Novella R., Rovas-Perea M.E., Influence of a low pressure EGR loop on a gasoline turbocharged direct injection engine, ELSEVIER Applied Thermal Engineering, 432-443, 2015. [7] Überall A., Otte R., Eilts P., Krahl J., A literature research about particle emissions from engines with direct gasoline injection and the potential to reduce these emissions, ELSEVIER Fuel 147, 203-207, 2015. [8] Mamakos A., Steininger N., Martini G., Panagiota D., Drossionos Y., Cost effectiveness of particulate filter installation on Direct Injection Gasoline vehicles, ELSEVIER Atmospheric Environment 77 16-23, 2013. [9] Du Y., Yu X., Wang J., Wu H., Dung W., Gu J., Research on combustion and emission characteristics of a lean burn gasoline engine with hydrogen direct-injection, ELSEVIER International Journal for Hydrogen Energy, 41, 3240-3248, 2016. [10] Fennel D., Herreros J., Tsolakis A., An experimental investigation on the performance characteristics of a hydroxygen enriched gasoline engine with water injection, ELSEVIER International Journal for Hydrogen Energy, 39, 5153-5162, 2014. [11] Chiriac R., Apostolescu N., Dica C., Effects of Gasoline- Air Enrichment with HRG Gas on Efficiency and Emissions of a SI Engine, SAE Paper 2006-01-3431, SAE International Congress, 2006. [12] Birtas A., Voicu I., Niculae Gh., Racovitza A., Chiriac R., Apostolescu N., Petcu C., Effects of LPG-Air Enrichment with HRG Gas on Performance and Emissions of a SI Engine, FISITA Paper no. F2010-A-064, FISITA International Congress, 2010. [13] Karagöz Y., Yürsuk L., Sandalci T., Dalkiliç A.S., An experimental investigation on the performance characteristics of a hydroxygen enriched gasoline engine with water injection, ELSEVIER International Journal for Hydrogen Energy, 40, 692-702, 2015. [14] Dârţu A., A study of the performances of direct injected turbocharged K7M710 engine, (in Romanian) Project License, University POLITEHNICA Bucharest, July 2014. [15] Dârţu A., Racovitza A., Chiriac R., Simulating the performances of a DI turbocharged SI engine obtained by converting the commercial K7M710 engine. A case study, Automotive Engineering Revue, 8, nr.4, 2014. [16] http://alset.at/our-solutions/ [17] http://autotehnic.files.wordpress.com/2013/08/