Page 1 of 6 MATERIAL SAFETY DATA SHEET No. 2 Distillate 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Synonyms: High Sulfur Diesel Fuel; #2 Distillate; #2 High Sulfur Diesel - Dyed; No. 2 Low Sulfur Distillate; Low Sulfur Diesel Fuel; #2 Distillate; #2 Low Sulfur Diesel - Dyed; Premium Diesel Formula: Mixture Chemical Family: Hydrocarbons CAS Number: 68476-34-6 SAP Code: 1014071; 1014072; 1014073; 1014074; 1014075; 1014076; 1014077; 1014078; 1014079; 1014080; 1014081; 1014082; 1014083; 1014085; 1014087; 1014088; 1014089; 1014090; 1014091; 1014092; 1014093; 1014096; 1014098; 1014100; 1014549; 1014550; 1014551; 1014552; 1014759; 1014760; 1014982; 1014983; 1014984 Product Code: 34260; 34360; 35260; 35360 MSDS Number: 001847 NFPA Ratings: Health 1, Flammability 2, Reactivity 0 HMIS Ratings: Health 1, Flammability 2, Reactivity 0 Manufactured By: Phillips 66 Company A Division of Phillips Petroleum Company Bartlesville, Oklahoma 74004 Phone Numbers Emergency: (918) 661-8118 Technical Information: (918) 661-1672 For Additional MSDSs: (800) 762-0942 2. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Specification and CAS # Weight % In Product ACGIH TLV ACGIH Short Term Exposure Limit ACGIH Ceiling Limits ACGIH Skin Designation OSHA Final PEL OSHA - Final PELs - Ceiling Limits OSHA - Final PELs - Skin Notation Diesel fuel no. 2 68476-34-6 100 NE NE NE NE NE NE NE Sulfur 7704-34-9 < 0.5 NE NE NE NE NE NE NE Benzene 2.5 ppm; 8 < 0.005 0.5 ppm 71-43-2 mg/m3 NE skin - potential for cutaneous absorption 1 ppm TWA (Areas exempted by the Benzene Standard, 29 CFR 1910.1028, will have a 10 ppm 8 hour TWA and 5 ppm STEL) NE NE * 1% = 10,000 ppm.
Page 2 of 6 3. HAZARDS IDENTIFICATION Emergency Overview Combustible liquid. Irritant. Lung Aspiration Hazard. Potential Acute Health Effects Eye Contact: May cause moderate irritation. Skin Contact: Skin Irritant. May cause severe irritation. Prolonged or repeated contact with the liquid may cause defatting of the skin resulting in drying, redness, and possibly blistering. Dermal LD50 for diesel fuel is 9 ml/kg (rat) Inhalation: Inhaled Hydrocarbons cause central nervous system depression at high concentrations resulting in headache, dizziness, and ultimately unconsciousness. Ingestion: May be irritating to intestines causing nausea and vomiting. If swallowed, may be aspirated resulting in inflammation and possible fluid accumulation in the lungs. Oral LD50 for diesel fuel is 9 ml/kg (rat). Subchronic and Chronic Effects: No Known Applicable Information Aggravated Medical Conditions: No Known Applicable Information 4. FIRST AID MEASURES Eye Contact: Flush eyes with running water for at least 15 minutes. If irritation or adverse symptoms develop, seek medical attention. Skin Contact: Immediately wash skin with soap and water for at least 15 minutes. If irritation or adverse symptoms develop, seek medical attention. Inhalation: Remove from exposure. If breathing is difficult, give oxygen. If breathing ceases, administer artificial respiration followed by oxygen. Seek immediate medical attention. Ingestion: Do not induce vomiting. Seek immediate medical attention. Notes To Physician: Gastric lavage using a cuffed endotracheal tube may be performed at your discretion. 5. FIRE FIGHTING MEASURES Flash Point: >100F (>38C) FP Method: PMCC, ASTM D-93 Ignition Temperature: Unknown Flammable Limits (% by Volume in Air) Lower Explosive Limit - Not Established Upper Explosive Limit - Not Established Fire Extinguishing Media: Carbon Dioxide, Dry Chemicals, Foam
Page 3 of 6 Fire Fighting Procedures: Evacuate area and fight fire from a safe distance. Shut off source, if possible. Firefighters should be equipped with self-contained breathing apparatus and turn out gear. Use water spray to cool nearby containers and structures exposed to fire. Do not spray water directly on fire - product will float and could be reignited on surface of water. Fire and explosion hazards: Carbon and sulfur oxides and various hydrocarbons formed when burned. 6. ACCIDENTAL RELEASE MEASURES Sweep or gather up material and place in proper container for disposal or recovery. 7. HANDLING AND STORAGE Do not get in eyes, on skin, or on clothing. Avoid breathing vapors, mist, fume or dust. Do not swallow. May be aspirated into lungs. Wear protective equipment and/or garments described in Section 8 if exposure conditions warrant. Wash thoroughly after handling. Immediately remove and launder contaminated clothing before reuse. Use with adequate ventilation. Keep away from heat, sparks, and flame. Store in closed container. Store in well -ventilated area. Bond and ground during transfer. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Eye Protection: If splash hazards are present use chemical goggles and a face shield. Respiratory Protection: Not generally required unless needed to prevent respiratory irritation. If Used As Fuel: This section does not address exposure to by-products of combustion, such as carbon monoxide. It is therefore recommended that the expert assistance of an industrial hygienist or other qualified professional be sought. When entering or exiting from areas where the exposure concentration is unknown or if conditions immediately dangerous to life or health (IDLH) exist, use a NIOSH approved self-contained breathing apparatus (SCBA) or equivalent operated in a pressure demand or other positive pressure mode. Skin Protection: Use gloves resistant to the material(s) being used (Nitrile). Suggestions for the use of specific protective materials are based on readily available published data. Users should check with specific manufacturers to confirm the performance of their products. Ventilation: Use adequate ventilation. Other Personal Protection: Personal protection information shown in Section 8 is based upon general information as to normal uses and conditions. Where special or unusual uses or conditions exist, it is suggested that the expert assistance of an industrial hygienist or other qualified professional be sought. Exposure Limits: See Section 2 (Composition/Information on Ingredients). 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Appearance: Odor: Odor Threshold (ppm): Boiling Point: Melting/Freeze Point: Liquid Light yellow to amber. May be dyed red. Mild Unknown Approximately 300-690F (149-366C) Not Established
Page 4 of 6 Vapor Pressure: Not Established Vapor Density (Air=1): >1 Specific Gravity @ 20 C (Water=1): 0.82-0.88 @ 60/60F (16/16C) Percent Volatile by Volume: 100 Evaporation Rate (Butyl Acetate=1): <1 Water Solubility: Negligible Viscosity: 1.7-4.1 cst @ 40C 10. STABILITY AND REACTIVITY Stability: Stable Hazardous Polymerization: Will Not Occur Incompatability (Materials to Avoid): Oxygen and strong oxidizing agents. Hazardous Decomposition Products: Carbon and sulfur oxides may form when burned. 11. TOXICOLOGICAL INFORMATION Other Health Effects: Combustion (burning) of most carbon-containing material forms carbon monoxide. Carbon monoxide inhalation may cause carboxyhemoglobinemia. Chronic exposure to carbon monoxide causes fatigue, poor memory, loss of sensation in fingers, visual disturbances and insomnia. Carboxyhemoglobinemia is frequently misdiagnosed as flu. Sensitive sub-populations to the inhalation of carbon monoxide exist. Carbon monoxide displaces oxygen in the bloodstream and therefore, can adversely effect people with pre-existing heart disease, pregnant women and smokers. Combustion, a normal use of diesel fuel, results in an exhaust that has been associated with lung cancer in animals. There is limited evidence to suggest an assoication between occupational exposure to diesel exhaust and lung cancer in humans. 12. ECOLOGICAL INFORMATION No data at this time. 13. DISPOSAL CONSIDERATIONS Disposal should be made in accordance with federal, state and local regulations. 14. TRANSPORT INFORMATION DOT Shipping Description: Fuel oil (No. 2), 3 or Combustible liquid, NA 1993, III Non-Bulk Package Marking: Fuel oil ( No. 2 ), NA 1993 Bulk Package Placard/Marking: Flammable or Combustible / 1993 Hazardous Substance/RQ: None Packaging References: 49 CFR 173.150, 173.203, 173.242
Page 5 of 6 IMDG Shipping Description: Diesel fuel, 3, UN 1202, III Non-Bulk Package Marking: Diesel fuel, UN 1202 Bulk Package Placard/Marking: ICAO/IATA Proper Shipping Name: ICAO/IATA Hazard Class: 3 15. REGULATORY INFORMATION EPA SARA 311/312 (Title III Hazard Categories) Flammable/1202 Diesel fuel UN/ID Number: UN 1202 Packing Group: III Subsidiary Risk: None Non-Bulk Package Marking: Diesel fuel, UN 1202 Acute Health: Chronic Health: Fire Hazard: Pressure Hazard: Reactivity Hazard: Yes No Yes No No Diesel fuel no. 2 100 68476-34-6 Regulated Substance on TSCA Inventory: Listed Canada - Domestic Substances List: Listed Sulfur < 0.5 7704-34-9 Regulated Substance on TSCA Inventory: Listed Pennsylvania Right to Know List: Listed New Jersey Right-to-Know List: Listed Massachusetts Right To Know List: Listed Florida Toxic Substances List: Listed Canada - Domestic Substances List: Listed Benzene < 0.005 71-43-2 Section 313 of Title III of the SARA and 40 CFR Part 372: Listed Clean Water Act - Toxic Pollutants: Listed Clean Water Act - Hazardous Substances: Listed Clean Water Act S307 Priority Pollutant: Listed Pennsylvania Right to Know List: Listed New Jersey Right-to-Know List: Listed NJ Environmental Hazardous Substances List: Listed Michigan Critical Materials List: Listed Massachusetts Right To Know List: Listed Florida Toxic Substances List: Listed Canada - Domestic Substances List: Listed 16. OTHER INFORMATION Revision Summary: Section 1. Chemical Product and Company Identification. Preparer: Health, Environment and Safety Department Date Prepared: 01/10/2002
Page 6 of 6 Supersedes: 05/10/2001 Phillips Petroleum Company (references to Phillips Petroleum Company or Phillips includes its divisions, affiliates and subsidiaries) believes that the information contained herein (including data and statements) is accurate as of the date hereof. NO WARRANTY OF MERCHANTABILITY, FITNESS FOR ANY PARTICULAR PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS MADE AS CONCERNS THE INFORMATION HEREIN PROVIDED. The information provided herein relates only to the specific product designated and may not be valid where such product is used in combination with any other materials or in any process. Further, since the conditions and methods of use of the product and information referred to herein are beyond the control of Phillips, Phillips expressly disclaim any and all liability as to any results obtained or arising from any use of the product or such information. No statement made herein shall be construed as a permission or recommendation for the use of any product in a manner that might infringe existing patents.