Cargo Handling Sheet. Caradol SP Document date; 7 January 2014 Revision 6

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Cargo Handling Sheet Caradol SP 30-45 Document date; 7 January 2014

Product Details: Product Name: Caradol SP 30-45 Shipping Name: Chemical Family: Product Code: MSDS: Acrylonitrile-Styrene Copolymer Dispersion in Polyether Polyol Polyols U317C http://www.shell.com/chemicals/responsible-energy/msds-search.html Physical Properties: Density: 1,020 kg.m3 @ 20 deg C. Dynamic Viscosity: 6,000 (mpas) @ 20 deg C. 1,500 (mpas) @ 50 deg C. Vapor Pressure: n/a Boiling Point: >200 deg C. Pour Point: -15 deg C. Flash Point: > 140 deg C. tes: Transshipments are not permitted unless the responsible Shell Chemical charterer has been consulted and the operation approved by the Regional Marine Technical Advisor. Marpol Details: Marpol Annex: II IMO Ship Type: 3 Shell Chemicals requires a ship type 2 IMO Pollution Category: Oil Like: High Viscosity: Solidifying: Y Yes USCG: USCG group 20, not compatible with group 12 2

Cargo Handling Requirements: Prepurging of Vessel s Tanks: Blanket Required: Percent Oxygen in Nitrogen Blanket: Vapor Space Purge: Yes <5% See Regional Requirements notes Loading Temperature Range: 25-50 deg C. Transit Temperature Range: 25 50 deg C. (International) Ambient 50 deg C. (EU barges) Discharge Temperature Range: 50 60 deg C. Maximum Heating Coil Temperature: <100 deg C. Adjacent Maximum Cargo Temperature: 50 deg C. Regional Requirements: See tes tes: For voyages between Amsterdam, Rotterdam, Antwerp, and the UK, no nitrogen blanket required. tes: For barge voyages in Europe Stainless steel required. tes: International vessels presenting coated tanks, contact local Chemicals MTA. tes: Inter Europe and UK, no wall wash required. tes: If Nitrogen blanket is in place and Carrier chooses to transship, carrier must reapply nitrogen blanket on the cargo, both on the discharging and receiving ship, at their time, risk, and expense. Tank Acceptance Requirements: All shore and ship cargo lines and tanks are to be presented clean (residual free), dry, odor free, and rust free, with good gaskets and pressure tested heating coils. Stainless Steel or Coated Tanks : Wall Wash Required: Wash Specifications: Coated, carrier to verify suitability of coating for product. See also Regional Requirements notes. As per local requirements, see also Regional Requirement notes As per local requirements. 3

Cargo Sampling, Testing & Sample Retain Requirements. Sample testing and Product Release Loading: Shore tank approved by location based on local process. Manifold samples tested in the field for appearance only. Product release based on location process. Discharge: Product acceptance based on location process. Manifold samples tested in the field for appearance only. Safety Information and Incident Reporting. Safety Information: For more detailed information, refer to the SDS or EDS for reportable spill/release quantities whether in the water, air or ground. Incident Reporting: International Registered Vessels: call Shell International Trading and Shipping in London on (44) 207-934-7777. Jones Act Vessels: call the Shell 24 hr. incident number at 713-241-2532. The USA National response center telephone number is 1-800-424-8802 For additional marine cargo handling advice or information, contact Captain Eddie Trotter at (+1 713 241 3535) 4

Shell Chemical LP PO Box 4407 Houston Texas 77210 USA Tel +1 866 897 4355 Internet http://www.shell.com/chemicals Disclaimer The information contained in this publication is, to the best of our knowledge, true and accurate, but any recommendations or suggestions that may be made are without guarantee, since the conditions of use are beyond our control. Furthermore, nothing contained herein shall be construed as a recommendation to use any product in conflict with existing patents covering any material or its use. Shell Chemicals The expression Shell Chemicals refers to the companies of the Shell Group of companies that are engaged in the chemical businesses. Each of the companies that make up the Shell Group of companies is an independent entity and has its own separate identity. 5