WET COMPRESSION. What it Is Not. What it Is. Is not traditional inlet air cooling, like a fogger or a chiller

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IGTI 2011 June 8 th, 2011

What it Is 8 to 25% (~12% 7EA) Power Augmentation at any wet bulb temperature above 45 F Complimentary Technology -used in series w/ inlet cooling & other GT upgrades Technology demonstrated for more than 10 years and >>300,000 fleet hours Applied to a wide range of GT s, aero and frame, for five GT OEMs Small droplets size, remain entrained in inlet air flow, reducing impingement GT OEMs have been Caldwell s repeat customers for Wet Compression WET COMPRESSION What it Is Not Is not traditional inlet air cooling, like a fogger or a chiller Is not a system that limits your other options Is not a new, untested concept Is not a limited Application Is not damaging to compressor

Four-fold effect: Water Inter-cools the CT compressor: COMPRESSOR EFFICIENCY DRAMATICALLY IMPROVED Mass flow enhancement (minor, but measurable) Lower CDT allows more fuel to be fired (at constant firing temperature) Adiabatic Cooling of inlet air: Cools air to very near WBT @ bell-mouth Usually operated with an existing fogger or evap cooler upstream Overall net impact ~ 9-13 MW on a GE 7EA, simple cycle

e MW per stag Compressor Efficiency Improvement 10 100 GE 7EA 9 90 compressor shaft parasitic power 8 requirements before and after 80 7 standard pressure ratio = 12.70 70 6 5 4 3 2 1 0 1 2 3 4 5 6 7 8 9 1011121314151617 stage 60 50 40 30 20 10 0 cumula ative MW 11 MW

T-S Diagram of Compressor & Combustor Heat (2 to 3) 3 T Constant 2 A firing temp. 2 S Change in CDT (-122 F) is 2 W the equivalent of replacing electric heating of air vs. fuel heating of air Compress (1 to 2) 1 Blue colored line is new Wet Compression path S

Wet Compression Effects on Stage Operating Pressure Press sure Wet Dry Intercooling reduces front end compressor work Water and increased HP rotor speed increase mass flow and CDP Axial Position Turbine pressure increased in all stages Compressor HP LP GEN Two Stage Turbine

WC Cycle Performance Effects Dry, Base Load Operation Fuel Air Exhaust Gen Comp Turb Wet Compression - 1% Overspray Air Fuel +8% 1% H 2 O 2560 Estimated Cycle Performance Effects: CT Power 11.8% CT Heat Rate -1.0% CT Fuel Flow 10.7% CT Exhaust Flow 0.0% CT Exhaust Energy?% Steam Production 20% 2.0% STG Power 2.0% Gen Comp Turb Pwr +9% Exhaust Flow +1% Enthalpy +1% Energy + 2% Duct Burner Flow?%

WC NOx Emission Effects Dry Base Load Operation Air Fuel Gen Comp Turb Exhaust NOx 42 ppmvd NOx 74 lb/hr Dry O 2 14.2% Wet Compression - 1% Overspray Air Fuel +8% 1% H 2 O Gen Comp Turb Exhaust Flow +1% Pwr +9% NOx 38 ppmvd NOx 71 lb/hr Dry O 2 13.8% Estimated Emission Effects: CT NOx reduced 10 to 20 percent in conventional diffusion flame combustion systems on a dry volumetric PPM basis corrected to 15% oxygen Mass emission rates are reduced by approximately half as much since oxygen content is reduced with wet compression. Dry low NOx emissions levels are affected by combustion system dynamics and may require tuning to hold NOx PPM constant or slightly increase emission rates. Mass emissions will increase due to the oxygen correction.

Environmental Benefits: 7EA 207EA, duct-fired, pre-fit w/ evap cooling Improves SC HR ~4%. Emissions Before with WC delta Reduces NOx PPM on conventional diffusion (WI / SI) burners; and requires integration with dry-low NOx burners Gas Turbine Emissions (total for 2 units) - burning gas fuel NOx as NO2 65 73 7.4 CO 110 110 0.0 UHC as CH4 19 20 0.6 Duct Burner Emissions (total for 2 units) - burning gas fuel NOx as NO2 33 37 3.6 CO 18 18 00 0.0 UHC as CH4 11 11 0.4 Plant Total Emissions NOxasNO2 NO2 20 22 2.2 CO 128 128 0.0 NH3 27 27 0.8 Overall NOx usually limited by SCR system Increase in Criteria Pollutants << 40 TPH trigger for NSR

Wet Compression Nozzle Location existing fogging nozzle location or evap cooler system silencing panels Wet Compression System Nozzle Rack Location

Array Manifold 7EA

Manifold Installation

WCT Nozzle Spray Pattern

Cardinal Cogen - GE Frame 6B No Wet Compression With Wet Compression Ambient dry bulb 58 F 59 F Ambient wet bulb 52 F 52 F Compressor Inlet Air Temp 57.9 F 52 F Compressor Discharge Pressure 153 psig 158 psig Compressor Discharge Temp 664 F 614 F Gas Flow 6.1 lb/sec 6.6 lb/sec Theoretical Firing Temp 2023 F 2023 F Turbine Exhaust Temp 1029 F 1017 F Turbine Power Output 35.33 MW 38.6 MW

Duct Work Treatment 6B

Wet Compression Arrays 6B

WCT Skid On Test

Rolls Royce ISI SKID

Table 1: Performance Comparison of Various Combustion Turbines Combustion Turbine Siemens W501FC Siemens V84.2 GE LM2500 PE GE Frame 6B SWPC W501D5A Alstom GT-24 GE Frame 7EA Overspray, % 1.3 1.0 2 1 2 1.2 1.5% Compressor Discharge Temperature Reduction, F 90 50 Data not available 50 100 48 90 Fuel Flow Increase, % N.D. N.D. 4 8.2 13.2 5.5 11.5% Change in Base No Change No Change No Change No Change No Change No Change No Change Load Firing Temperature, ºF CT Power Increase, MW Steam Turbine Power Increase, MW 17 5.2 1.6 3.3 15 15.5 9 Simple Cycle Simple Cycle -.5 0.3 (est.) 2 (est.) 1.8(est.) Simple Cycle CT Heat Rate N.D. 2 0 1 2 2 1.05% Improvem ent, % NOx Info -10% N.D. -14% DLN DLN No Change -54%

Wet Compression Experience Patented Wet Compression Technology licensed from Dow Chemical 10 years of continuous improvement > 300,000 hours of operating experience on more than 60 CTs Engine 1 st Installed Engine 1 st Installed Engine 1 st Installed W501A 1995 GE 6B 2002 GT 24 2002 W501D5A 1997 LM2500 2003 GT 26 2004 W501D5 1999 GE 7EA 2008 RR T60 2009 V94 2001 W501F 2004 8 units and growing

Wet Compression Summary Significant efficiency improvement << 1 year payback Ambient Independent: consistent, predictable power augmentation Short outage, low-impact installation > 300,000 hours of operating experience Safe and Reliable no impact to Reliability, Availability, Maintainability (RAM)

Wet Compression Customers Projects installed in: USA South America Africa Projects installed in: USA, South America, Africa, Europe, Asia, Australia