The Contribution of Lubricants to Sustainability in Shipping. Sustainable Shipping Conference, 09/30/2009, San Francisco JP. ROMAN

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The Contribution of Lubricants to Sustainability in Shipping Sustainable Shipping Conference, 09/30/2009, San Francisco JP. ROMAN

OUTLINE The TOTAL Group and LUBMARINE Lubricants and Environment Marine Lubricants Contribution to Sustainability Conclusions

OUTLINE The TOTAL Group and LUBMARINE Lubricants and Environment Marine Lubricants Contribution to Sustainability Conclusions

TOTAL the 4th largest integrated oil & gas Co. worldwide UPSTREAM OPERATIONS IN 40 COUNTRIES exploration & production activities (oil, natural gas, LNG) a production of 2.5 million bep/day DOWNSTREAM OPERATIONS IN 160 COUNTRIES refining, marketing, trading and shipping of crude oil and refined products leader in Western European refining/marketing and leader in African marketing 16 500 service stations worldwide RENEWABLE ENERGIES solar energy, biomass, alternative motor fuels

LUBMARINE in TOTAL Exploration & Production Refining & Marketing Gas & Power Chemicals Specialties Division Lubricants Solaize Research Center (near Lyon France)

The LUBMARINE network Organisation based on a network of Total affiliates and partners worldwide assistance same quality of products guarantee of deliveries 2004 1961 GALP PTT Portugal Thailand Repsol Petrolimex Spain Vietnam Copetrole JEC Egypt Japan Ipiranga Brazil YPF Argentina HPCL India

OUTLINE The TOTAL Group and LUBMARINE Lubricants and Environment Marine Lubricants Contribution to Sustainability Conclusions

LUBRICANTS and ENVIRONMENT (1) CRUDE OIL vegetable raw materials Chemical Synthesis Refining Processes ADDITIVES BASE OILS FINISHED LUBRICANT with standardized performance and physico-chemical specifications

LUBRICANTS and ENVIRONMENT (2) Lubricants can be detrimental to the environment hydrocarbon raw material waste oil ground and water pollution A lubricant can contribute to sustainability by limiting the negative effects selection of «green» raw materials and components formulations «easy-to-degrade» optimized balance of base oils limited amount of additives recyclability by contributing significantly to the technological improvements improved reliability of engines and equipments active contribution to emissions limitation reduced friction and improved fuel efficiency

OUTLINE The TOTAL Group and LUBMARINE Lubricants and Environment Marine Lubricants Contribution to Sustainability Conclusions

MARINE LUBRICANTS FAMILIES 2-stroke type lubricants for main engines Marine Cylinder Lubricant (MCL) lost lubrication of the cylinder units high levels of additives 4-stroke type lubricants for main engines and generators System Oils cranckase lubricant for 2-stroke engines low level of additives Trunk Piston Engine Oils (TPEO) cranckase lubricant for 4-stroke engines medium to high level of additives Lubricants for equipments wide range of applications industrial lubricant type (compressors, hydraulics.) limited level of additives

MARINE LUBRICANTS BREAKDOWN IN LUBMARINE TPEO for operations with distillates Auxiliary Products TPEO for operations with HFO System Oil (SO) Marine Cylinder Lubricant (MCL)

LUBMARINE s INNOVATIVE PRODUCTS BIO L UBE S ra nge

MARINE CYLINDER LUBRICANTS TALUSIA UNIVERSAL New patented formulation technology Enhanced neutralization ability with reduced BN Cleanliness and thermal resistance improved despite the BN reduction Antiwear capability demonstrated after thousands of hours of field tests Suitable for both high & low sulphur HFO convenient INSIDE & OUTSIDE of ECA Just one lubricant to manage (purchase, supply, on-board management) simplification No risk of mismatch between the fuel oil and the lube oil safety Used like a regular high BN lube oil without changing the set-up of the lubrication systems ; potential economy of lube oil consumption with the electronical lubricators savings Demonstrated reliability of 2-stroke engines on any kind of vessel Approved by the 2-stroke engine manufacturers 21 000 h of approval test accumulated on MAN Diesel and Wärtsilä engines ; test in service on a long-stroke MHI engine. Test in service on the Green Ship CMA-CGM ANDROMEDA continuous operation with a 1% sulfur content LSHFO (new regulation limit from July 2010) A profound change in the chemistry of MCL Necessary to contribute to the compliance of the future fuel & emissions regulations The contribution to a constant The control of the lube oil efficiency of engines is a key factor consumption is a critical target the future MCL have to perform well partnerships with engine even when degraded manufacturers are fundamental

FUTURE MARINE CYLINDER LUBRICANTS 2010 2011 2012 5 S = 4.5% 2015 2020 80 BN70 70 Talusia HR70 4 S = 3.5% BN50-60 60 Talusia Universal (BN57) Sulphur in fuel (%) BN40 40 Talusia Universal II Talusia LS40 2 30 TARGET S = 1.5% S=1% 1 BN10-20 Talusia VLBN 20 10 S = 0.5% S = 0.1% 0 2005 2007 2009 2011 2013 2015 2017 2019 2021 2023 0 2025 BN (mg KOH/g) 50 3

TRUNK PISTON ENGINE OILS AURELIA TI Top tier TPEO Cleanliness of engines BN retention Viscosity control MAN 48/60 engine after 4845 h of test WÄRTSILÄ DEUTZ SEMT PIELSTICK MAN Diesel YANMAR GUANGZHOU DIESEL DAIHATSU MAK/CATERPILLAR ROLLS ROYCE

FUTURE 4-STROKE TYPE LUBRICANTS Future AURELIA Achievement (and retention) of fuel economy performance Extension of draining/top-up intervals Full compatibility with post-treatment systems INNOVATOR-4C Test Bed Compartimented MAN 5L 16/24 The future TPEO/SO have to be designed to contribute to the reduction of CO2 and contaminants emissions

AUXILIARY LUBRICANTS Mineral lubricants can be harmful for the soils and the water Mineral lubricants contain elements not compatible with the biosphere 1 liter of mineral lubricant = 1 000 000 liters of polluted water Biolubricants are a solution to minimize adverse effects on the environment BIOLUBRICANT A fresh lubricant/grease that is BIODEGRADABLE and NON TOXIC

BIODEGRADABILITY DEFINITION Biodegradability is a decomposition by a biological breakdown A natural destruction of a substance by living organisms (bacteria) Takes place in the ground and in the aquatic environment Initial Product Secondary Product (non toxic) CO2 + H2O STANDARDS Coordinating European Council (CEC) Organization for Economic Cooperation and Development (OEDC) An international reference standard OEDC 301B = ultimate degradation to CO2 over 60% after 28 days

CHARACTERISTICS COMPARISON BIONEPTAN 100 Hydraulic Mineral Lube Oil Chemical type unsaturated ester mineral basestock Viscosity Index over 180 100 Pour point - 46-24 Flash point 285 230 Biodegradability (OEDC 301B) over 80% 30% EP performance (FZG stage) 11 10 Oxidation stability ++ + Operating temperature - 30 to 100-20 to 90

LUBMARINE S BIOLUBRICANTS RANGE HYDRAULIC SYSTEMS STERN TUBE BEARINGS & MULTIPURPOSE OPEN GEARS BIONEPTAN BIOHYDRAN TMP (100,150, 220) BIOMULTIS SEP 2 (32, 46, 68,100) BIOCARTER (150, 220, 320, 460) WIRES & ROPES ADplusBIO

CONCLUSIONS (1) Marine Lubricants can contribute to sustainability in shipping Marine lubricants have to be finely tuned to engine technologies and fuels regulations to be efficient for sustainability The items to investigation when looking at lubes sustainability are: the raw materials consumption control the reliability and the efficiency of the lubricated systems the contribution to CO2 emission limitation Biodegradability or recyclability

CONCLUSION (2) «We do not inherit the earth from our parents, but we borrow it to our children.» Antoine de Saint Exupéry