Common Technical Training Workshop January CASTOR-SP2: overview. Jan Hopman (TNO)

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CASTOR - ENCAP - CACHET - DYNAMIS Common Technical Training Workshop 22-24 January 2008 CASTOR-SP2: SP2: Overview Jan Hopman (TNO) 1

CASTOR-SP2 SP2 Members Knowledge IFP NTNU SINTEF TNO USTUTT Industrial Alstom-Power BASF DONG Energy Doosan-Babcock Electrabel EON-Engineering Engineering (D,UK) Gaz de France PPC RWE SIEMENS StatoilHydro Vattenfall 2

CASTOR-SP2 SP2 objectives Development of absorption liquids, with a thermal energy consumption of 2 GJ/tonne CO 2 at 90% recovery rates (4 GJ/tonne CO 2 with reference process) Resulting costs per tonne CO 2 avoided not higher than 20 to 30 /tonne CO 2, depending on the type of fuel (40 to 50 /tonne CO 2 with reference process) European pilot plant tests showing the reliability and efficiency of the post-combustion capture process 3

CASTOR-SP2: SP2: work-packages WP 2.1: Evaluation, Optimisation and Integration of post-combustion capture WP 2.2: New solvent development WP 2.3: Membrane contactor development WP 2.4: Advanced process development WP 2.5: Pilot plant validation with real flue gases 4

WP2.1: Integration studies Integration Carbon Capture in Power Plants for following base cases: 393 MWe CCGT (Siemens) MWe bituminous (Doosan( Babcock) MWe lignite (RWE/Alstom Alstom) 1. 393 2. 600 MWe 3. 1000 MWe 4. 380 MWe lignite (PPC) Economic models for each base case presentation by TNO 5

WP2.2: New solvents Several solvents investigated Presentation by SINTEF, NTNU, USTUTT, IFP Models developed and validated Presentation by SINTEF, DONG, NTNU Three solvents tested at CASTOR- pilotplant-esbjerg: 1. MEA 2. CASTOR-1 1 solvent 3. CASTOR-2 2 solvent 6

WP2.3: Membranes Three membrane types developed and tested: Transversal flow module Flat membrane module Fibre module Practical data generated transversal flow module Flat sheet module Liquicell 7

WP2.4: Advanced processes Process optimization of the absorption / desorption loop (Gaz( de France, IFP) Packing material characterization (IFP) Presentation by IFP Two packings fully characterized (IMTP50 & ME252Y) Hydrodynamic test on pilot plant (Esbjerg) equipped with IMTP50. New generation random packing IMTP50 (Koch-Glitsch) HC structured packing Mellapak 252 Y (Sulzer) 8

WP2.5: Pilotplant tests CASTOR pilot-plant plant at DONG-Esbjerg Presentation by DONG, Vattenfall Four test runs: MEA-1 MEA-2 CASTOR-1 1 solvent CASTOR-2 2 solvent 9

CASTOR-SP2: SP2: Conclusions - 1 1. Development of absorption liquids, with a thermal energy consumption of 2 GJ/tonne CO 2 at 90% recovery rates Reference process: ~4GJ/tonne CO2 With CASTOR2 solvent: down to 3.5GJ/tonne CO2 (12%) With integration: down to 3.2 GJ/tonne CO2 (20%) 2. Resulting costs per tonne CO 2 avoided not higher than 20 to 30 /tonne CO 2, depending on the type of fuel Reference process: 40-50 /tonne CO2 With MEA process optimization: 35-37 37 /tonne CO2 (2005 ref) First steps to the ambitious goals are made 10

CASTOR-SP2: SP2: Conclusions - 2 3. European pilot plant tests showing the reliability and efficiency of the post-combustion capture process Operational pilot plant Validation procedures Validation experience Validation results Environmental awareness Queue of requests from industry CASTOR made validation basis for Post-Combustion Combustion-CaptureCapture development 11

CASTOR-SP2: SP2: presentations 10h15 Solvents and corrosion (SINTEF, NTNU, USTUTT, IFP) 10h35 Process modelling and model validation (SINTEF, DONG, NTNU) 11h10 Economic modelling & integration (TNO) 11h30 Packing characterisation (IFP) 11h50 Experiments on pilot plant (DONG, Vattenfall) 12

TNO-CATO Pilot Plant CATO Pilot CATO Pilot CATO Pilot 250 kg CO2/hr (~0.1%) Opening 3 April 2008: www.co2-cato.nl/symposium cato.nl/symposium 13