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Cargo Handling Sheet Caradol SP 30-45

Product Details: Product Name: Caradol SP 30 45 Shipping Name: Chemical Family: Product Code: MSDS: Acyronitrile-Styrene Copolymer Dispersion in Polyether Polyol Polyol U317C http://www.euapps.shell.com/msds/gotomsds?loc=shellchemicals Physical Properties: Density: 1.020kg/m3 @ 20 deg C. Specific Gravity: Dynamic Viscosity: 6,000 (mpa) @ 20 deg C. 1,500 (mpa) @ 50 deg C. Vapor Pressure: t available Boiling Point: >200 deg C. Melting Point: t available Pour Point: -15 deg C. Flash Point: >140 deg C. Marpol Details: Marpol Annex: II IMO Ship Type: 3, Shell Chemicals requires a ship type 2 IMO Pollution Category: Oil Like: High Viscosity: Solidifying: Y Yes USCG: USCG group 20, not compatible with group 12 2

Cargo Handling Requirements: Prepurging of Vessel s Tanks: Pre-purge Oxygen Content: Pre-purge Dew Point: Blanket Required: Percent Oxygen in Nitrogen Blanket: Vapor Space Purge: N/A N/A Yes <5%, See also Regional Requirements notes Loading Temperature Range: 25 50 deg C. Transit Temperature Range: 25 50 deg C. (International) Ambient 50 deg C. (EU barges) Discharge Temperature Range: 40 50 deg C. (International) Ambient 50 deg C. (EU barges) Maximum Heating Coil Temperature: <100 deg C. Adjacent Maximum Cargo Temperature: 50 deg C. Transshipments are not permitted unless the responsible Shell Chemical charterer has been consulted and the operation approved by the Regional Marine Technical Advisor. Regional Requirements: See notes tes: For voyages between Amsterdam, Rotterdam, Antwerp, and the UK, no nitrogen blanket required. tes: For barge voyages in Europe Stainless steel required. tes:- International vessels presenting coated tanks, contact local Chemicals MTA. tes: Loading in Europe, no wall wash required tes: If Nitrogen blanket is in place and Carrier chooses to transship, carrier must reapply nitrogen blanket on the cargo, both on the discharging and receiving ship, at their time, risk, and expense. 3

Tank Acceptance Requirements: All shore and ship cargo lines and tanks, where not dedicated for the product, are to be presented clean (residual free), dry, odor free, and rust free, or dedicated barges, with good gaskets and pressure tested heating coils. Stainless Steel or Coated Tanks: Coated, carrier to verify suitability of coating for product. See also Regional Requirements notes. Wall Wash Required: Wash Specifications: As per local requirements. See also Regional Requirements notes. As per local requirements. Maintenance of heating coils is to be verified in the ship s log. If product is to be heated, heating coils are to be confirmed leak free. If product is not heated, heating coils are to be drained, dried and blanked off. Sample testing and Product release/ Acceptance Requirements. Loading: Shore tank approved by location based on local process. Manifold samples tested in the field for appearance only, or local process. Product release based on local process. Discharge: Product acceptance based on key tests on arrival samples from each tank based on local process. Safety Information and Incident Reporting Safety Information: For more detailed information, refer to the MSDS or e-sds for reportable spill/release quantities whether in the water, air or ground. Incident Reporting: If an incident occurs outside the territorial limits of the USA, call Shell International Trading and Shipping in London on (44) 207-934-7777. If the spill/release marine incident occurs within the territorial limits of the USA, call the Shell 24 hr. incident number at 713-241-2532. The USA National response center telephone number is 1-800-424-8802 For additional marine cargo handling advice or information, contact Captain Eddie Trotter at (+1 713 241 3535) 4

Shell Chemical LP PO Box 4407 Houston Texas 77210 USA Tel +1 866 897 4355 Internet http://www.shell.com/chemicals Disclaimer The information contained in this publication is, to the best of our knowledge, true and accurate, but any recommendations or suggestions that may be made are without guarantee, since the conditions of use are beyond our control. Furthermore, nothing contained herein shall be construed as a recommendation to use any product in conflict with existing patents covering any material or its use. Shell Chemicals The expression Shell Chemicals refers to the companies of the Shell Group of companies that are engaged in the chemical businesses. Each of the companies that make up the Shell Group of companies is an independent entity and has its own separate identity. 5