Biofuel Supply Chains

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Biofuel Supply Chains Professor Patricia J. Harvey p.j.harvey@gre.ac.uk

Two scenarios: Electricity, desalination, sterilisation for remote communities: biofuel-chp Transport -marine auxiliary power: glycerol-chp

Scenario1: Power

Distribution centralised, with grid operators Coal-fired power station ~ 30-35% efficiency 10% losses in transmission

Power distribution -decentralised 15% flue 5% radiation loss 50% heat 37-48% electricity

CHP potential

Fossil fuel supply chain Well-established Feedstock extraction Feedstock logistics Fuel production Fuel distribution Fuel use Power station, ICE Fossil fuel: coal, oil (petroleum), natural gas ICE s, power stations built to suit materials Centralised grid - economies of scale Biofuel supply chains: Vision, Challenges, Technologies 3 March 2011

Biofuel Supply chain(s)? Feedstock production Cultivate harvest. Feedstock logistics transport store distribute Biofuel production Convert to biofuel Distribution Handle blend transport store Biofuel supply chains: Vision, Challenges, Technologies Biofuel use 3 March 2011

Where are the bottlenecks? Feedstock Feedstock production Agriculture negatives Incentives Microalgae cultivation know-how Feedstock distribution 70% water bulky Biofuel supply chains: Vision, Challenges, Technologies 3 March 2011

Where are the bottlenecks? Biofuel production Biofuel soup Proteins, lipids (oils, fats), polysaccharides, lignin, cellulose 1µ M Technology Lignocellulosics biobutanol

Where are the bottlenecks -what do we (think) we need? Heating (gas) 45% Hot water (gas) 16% lighting (elec) 1% TV (elec) 0.5% Cooking (elec) 3% Dishwasher (elec) 2% Fridge/freezer (elec) 2% Washer/drier (elec) 0.5% Car (petrol) 30% Source: New Scientist Sept 2006

Integration of biofuels into existing supply chain? Biodiesel - engine mods Bioethanol engine mods Biogas Power Cable Distribution Decentralised or centralised? Consumer installations? Operation, service, maintenance of the entire scheme

Scenario 2

Marine Auxiliary Engines Glycerol as a Biofuel

Why glycerol? Water-soluble Biodegradable, non-toxic Non-flammable Non-volatile High boiling point Carbon (CO 2 ) neutral from biodiesel production Plant Oil + alcohol Fatty acid esters + glycerol (biodiesel)

Will it combust in CHP? 2010 -New combustion method. McNeil Combustion Cycle Standard diesel engines burn liquid/gaseous fuels of any cetane number without additives/chemical processing Patent no GB2460996B Int. Application No.: PCT/EP2009/053274

Glycerol combustion Engine size Electrical efficiency 10-50 kwe 37% 100-1000 kwe 42% 1000 10000 kwe 48% Emissions Particulate NOx SOx Amount Below detection limits 0.1g/kWh(3000 rpm engine speed) negligible

Marine auxiliary power generation Comply with ship regulations (SOLAS, SECA, ISO 8127) Spills: minimal risk to marine environment Mitigate CO 2 0.7 mt glycerol burnt in CHP eliminates ~ 1 mt pa CO 2 Energy efficient Thermal battery An existing engine can be used withoutmodification to the hardware

Ship retrofit Technology Pipeline 1MW CHP engine, ~4800 t glycerol 1y

Glycerol supply? European glycerol manufacture from biodiesel

Glycerol supply? Africa-Europe Energy Partnership Hydrotreated vegetable oil (HVO) Alternative markets for glycerol

Glycerol from halotolerant microalgae Osmotic stabilizer Halophytes 4.0M salt ~85% biomass (dw) as cytoplasmic glycerol Israeli technology: ~40 tons glycerol d -1 km -2 Ami Ben-Amotz

Oil price / war = must do

1 st Energy Crisis 1975, Glycerol Algal Farm, 500 hectares in Sinai NBTEilat

Glycerol Supply chain? Feedstock production Feedstock logistics Biofuel production Distribute Biofuel use mindmap