ID Test Standard Amount Required Price for Cost Recovery Projects (Can $) 1 2 3 4 5 Sulfur compounds distribution by boiling point (GC-SCD) Sulfur compound speciation by GC-SCD Nitrogen compounds distribution by boiling point (GC-NCD) Nitrogen compounds speciation by GC-NCD SARA (Asphaltene+ Saturates+Aromatics+Polars) 6 Asphaltenes (C5 or C7) 7 SOAP (Sat, Olefins, Arom, Polars) by SPE (Solid Phase Extraction) In-house method 2 g 396 In-house method 2 g by quotation In-house method 2 g 396 In-house method 2 g by quotation ASTM D2007M/ASTM D2549M In-house method/astm D6560/D3279 10 g 634 10 g 152 In-house method 1 ml 752 8 SAP (Sat, Arom, Polars) by SPE In-house method 1 ml 462 9 Total Olefins by SPE In-house method 1 ml 290 10 Olefins distributed by boiling point (Separation by SPE +Sim Dist) 11 Hydrocarbon Types by SFC In-house method 1 ml 726 ASTM D5186/CGSB 3.0-2002 2 ml 320 12 Hydrocarbon Types by FIA ASTM D1319 2 ml 293 13 14 15 Saturates/Mono/Di/Poly Aromatics by RI-HPLC (BP: 150-400 C) Hydrocarbon Types (204-540 C) by GC-MS (Olefins not included) Hydrocarbon Types (204-540 C) by GC-MS (Olefins included) ASTM D6591Mod/IP-391 Modified ASTM D2007M or SAP/ASTM D2786/ASTM D3239 SOAP by SPE/ASTM D2786/ASTM D3239 2 ml 308 10 g 884 5 g 1175 16 Hydrocarbon Types by GC-FIMS In-house method 1 ml by quotation 17 Naphthalenes by UV ASTM D1840 18 Total Naphthenic Acids 19 Hydrocarbon Types Distribution by Boiling Point (by GC-SIMDIS- MS) (Olefins not included) In-house method by SPE- IR ASTM D2007M or SAP/ASTM D2786/D3239/D2887(X2)/ Calc 1 g + incl. Density info 244 2 g 607 10 g 1723
20 21 22 23 24 Hydrocarbon Types Distribution by Boiling Point (by GC-SIMDIS- MS) (Olefins included) Hydrocarbon Types by GC-MS Robinson Method Detailed Hydrocarbon Analysis (DHA) by High Resolution GC (RT-204 C) Hydrocarbon Types (RT-204 C) by PIONA (Without prefractionator) Hydrocarbon Types (RT-525 C) by PIONA (With prefractionator) SOAP by SPE/ASTM D2786/D3239/D2887(X3)/ Calc In-house method adapted from the Robinson Method CAN/CGSB-3.0 No.14.3- M94 10 g 2422 1 ml 363 1 ml 560 ASTM D6839 1 ml 508 In-house method based on ASTM D6839/ASTM D2887 1 ml 851 25 H/C Ratio by GC-AED In-house method 2 ml 770 26 27 Qualitative GC-MS (Capillary GC+MS identify major components) Quantitative GC-MS (SCAN or SIM with ISTD quantification of n compounds) In-house method 1 ml 304 In-house method 5 ml 500 28 Distillation (atmospheric pressure) ASTM D86 200 ml 137 29 30 31 32 33 34 200 ml charge) 500 g charge) 1000 g charge) 3000 g charge) Small Spinning Band Distillation (up to 3 liters, up to 5 cuts, up to 350 C) Large Spinning Band Distillation (up to 12 liters, up to 5 cuts, up to 350 C) 35 Distact (Short Path Distillation) ASTM D1160 250 ml 714 ASTM D1160 550 ml 873 ASTM D1160 1100 ml 1109 ASTM D1160 3200 ml 1443 In-house method up to 3.2 liters 1440 In-house method up to 13 liters 3485 KDT-6 from Chemtech Services Inc up to 10 liters 1440 (one cut) 36 TBP 15/5 Distillation (3 liters) ASTM D2892/D5236 4 liters 3485 37 Dewatering for ASTM D2892/5236 High Volume (up to 3.2 liters, High Speed Sorvall Evol. RC Centr. 700 ml 792
38 39 40 CHN (Carbon, Hydrogen, Nitrogen) Total Sulfur (by XRF or Combustion/IR) Trace Sulfur (by GC-SCD or GC- AED, 0.1-100 ppm) ASTM D5291 /(ASTM D5373) ASTM D4294/D1552/D4239 1 g 137 3 ml 107 ASTM D5623 1 ml 330 41 Elemental Sulphur GC-AED or SCD 1 ml 3363 42 Trace Nitrogen (by Chemiluminescence Detection) ASTM D 4629 1 ml 121 43 Loss on ignition 2 g 92 44 Metals by ICP-MS In-house method 100 g 302 45 46 Chlorine in Crude Oil and Petroleum fractions (ASTM D86 Distillation, Potentiometric Titration of Chloride) Oxygen (by direct determination by Elementar Oxygen Analyzer) 47 Simulated Distillation by GC 48 Refinery Gas Analysis (gas bag) 49 50 51 52 53 Refinery Gas Analysis-on line (24 hours monitoring) Photoacoustic FTIR Spectra (Far IR) Photoacoustic FTIR Spectra (Mid IR) Photoacoustic FTIR Spectra (Near IR) Dispersive Photoacoustic Spectra (UV/Vis) ASTM D4929 or in-house instrumental method In-house instrumental method ASTM D2887/D2887 Ext/D6352/D7169 Agilent 3000 Fast Micro GC Online Agilent 3000 Fast Micro GC 200 ml for D4929 or 2 ml for inhouse Instrum. method 594 1 g 160 2 ml 460 500 ml 152 568 IFS66v/s 10 mg 360 IFS88 10 mg 360 IFS88 10 mg 360 In-house 200 mg 360 54 Dispersive Raman Spectra Renishaw 200 mg 360 55 Fourier Transform Raman Spectra Bruker FRA 106 200 mg 360 56 Absorption Spectra (UV/Vis/NIR) Cary 5E 200 mg 360 57 58 Transmission FTIR (Far IR) Transmission FTIR (Mid IR) IFS66v/s 1 g 360 IFS88 1 g 360
59 Transmission FTIR (Near IR) IFS88 1 g 360 60 Quantum Cascade Laser PAS (Mid IR) Daylight Solutions (4.55um, 9.7um) 61 Fluorescence Spectrum In-house 360 62 13C Aromaticity 63 13C Spectrum 64 1H Spectrum 65 Olefin content by 1H NMR 66 Specialized NMR Services Inova 600 Mhz NMR Inova 600 Mhz NMR Inova 600 Mhz NMR Modified CAPP method with Inova 600 Mhz NMR 2-D experiments, carbon chemical functional group fingerprinting, etc 360 2 g 606.00 2 g 606.00 2 g 250.00 2 g 449.00 by quotation 67 Aniline Point ASTM D 611 20 ml 114 68 Ash of coals/coke ASTM D 5142 2 g 46 69 Ash of Petroleum Products ASTM D 482 10 g 114 70 Ash sulfated ASTM D 874 10 g 137 71 Bromine Number (BN) ASTM D 1159 5 g 178 72 Catalyst Steaming ASTM D 4463 10 g 620 73 Calorific Value ASTM D 2015 3 g 200 74 Cetane number ASTM 613 1 L 494 75 Cloud Point ASTM D 2500 40 g 164 76 Color ASTM D1500 20 ml 103 77 Copper Corrosion Test ASTM D130 30 ml 111 78 79 Dean-Stark Soxholet extraction (large- 300 g) Dean-Stark Soxholet extraction (small-50 g) In-house method 300 g 290 In-house method 50 g 145 80 Density of petroleum liquids ASTM D 4052 3 ml 57 81 82 Density of Solids by He Pycnometer Density of viscous petroleum products ASTM D 2638 D5550 2 g 144 ASTM D 2320 5 g 152 83 Diene Value (MAV) UOP 326-82/ UOP 326-07 20 g 344 84 Flash Point ASTM 93 75 ml 143 85 Freezing Point ASTM 2386 50 g 143
86 Insolubles, Pentane ASTM D4055 5 g 137 87 Insoluble, Hexane In-house method 5 g 137 88 Insoluble, Heptane ASTM D3279 5 g 137 89 Insolubles, THF In-house method 5 g 137 90 Insolubles, Toluene ASTM D4072 5 g 137 91 Mercaptan Sulfur in Distillates (up to 270 C) ASTM D3227 10 g 220 92 Micro Activity Test (MAT) ASTM D5154 10 g 455 93 Micro Carbon Residue (MCRT) ASTM D 4530 1 g 132 94 95 96 97 Moisture of coals, coke, catalysts etc Moisture of crude oil by KF titration Molecular Weight of hydrocarbons by VPO Molecular Weight by Freezing Point Depression ASTM D 5142 2 g 46 ASTM D 4377/D1744 2 g 121 ASTM D 2503 200 mg 218 In-house method 1 g 145 98 Octane Number (Motor) ASTM D2700 1 Liter 407 99 Octane Number (Research) ASTM D2699 1 Liter 407 100 Penetration Point ASTM D 5 20 g 112 101 Pour Point ASTM D 97 40 g 143 102 TGA: general In-house method 2 g 363 103 TGA: FTIR In-house method 2 g 595 104 Proximate Analysis of coals,coke, catalyst etc (moisture/ash/vol.matt.) ASTM D 5142 5 g 79 105 Refractive Index ASTM D1218 1 ml 61 106 Reid Vapor Pressure ASTM D 323 50 g 174 107 Salt in Crude Oil ASTM D 6470M 40 g 290 108 Shell Hot Filtration Test (SHFT) Shell SHFT 10 g 244 109 Smoke Point ASTM D1322 20 ml 232 110 Softening Point ASTM D 36 20 g 112 111 Total Acid Number (TAN) ASTM D 664 2-20 g 133 112 Total Base Number (TBN) ASTM D2896 5 g 137
113 114 Dynamic Viscosity (by Brookfield/Capillary/Stabinger viscometer) Water and Sediments in Fuel by Centrifuge ASTM D 5018/D544/D7042 12 g 133 ASTM D1796 100 ml 114 115 Centrifugation (4X1 liter) Sorvall RC-3C Centrifuge up to 3 liter 180 116 P-Value 20 g 528 117 Wiehe Compatibility Test Wiehe method 20 g 528 118 Fouling of Liquid Hydrocarbons 119 120 121 122 123 124 125 126 127 Existent Gum in Fuel by Jet Evaporation Oxydation Stability of Gasoline (Induction Period Method) Oxydation Stability of Aviation Fuels (Potential Residue Method) Oxydation Stability of Distillate Fuel Oil (Accelerated Method) Thermal Oxyd. Stability of Aviat. Turbine Fuels (JFTOT) Distillate Fuel Storage Stability at 43 C Octel 180 or 90, 150 C Accelerated Fuel Oil Stability Test Density of Solids by He Pycnometer Particle Size Distribution by Laser Granulometry 128 BET Surface Area 129 BET Surface Area and Pore Size Distribution Alcor HLPS (Hot Liquid Process Simulator) 1 liter 1440 ASTM D381 100 g 172 ASTM D525 100 g 264 ASTM D873 100 g 330 ASTM D 2274 500 ml 482 ASTM D 3241 100 g 396 ASTM D4625 500 g 508 ASTM D6468 100 g 330 ASTM D2638 or D5550 20 g 144 ASTM D4464/D197/C1070 In-house method by N2 adsorption with Micromeritics ASAP 2020 In-house method by N2 adsorption with Micromeritcs ASAP 2020 20 g 144 200 mg 300 200 mg 480