Fuel Cell Systems For Aeronautic Applications A Clean Way from Kerosene to Energy

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DGLR / VDI / RAeS Vortragsreihe an der HAW / Berliner Tor Presented by O 2 + - H 2 Hans-Jürgen Heinrich Manager Engineering H 2 O Fuel Cell Systems For Aeronautic Applications A Clean Way from Kerosene to Energy Hamburg, 10 th of May 2007

Contents Introduction Airbus Activities Synergy Effects System Requirements and Environmental Conditions Fuel Cell System Motivation for Fuel Cell System Application Fuel Cell Systems Architecture Airbus Fuel Cell System Strategy Step 1: Demonstrator Step 2: Fuel Cell Emergency Power System Step 3: Fuel Cell Power Unit Step 4: Fuel Cell as Primary Source Step 5: Alternative Fuels Industrialization Conclusion

Introduction Airbus Activities Airbus is one driver of industrialization and early application of fuel cell systems. Airbus is leading or involved in national and international projects to encourage the fuel cell technology progress. Airbus supports Joint Ventures of companies, authorities, universities and associations. Airbus supports the system supplier in design and development of airworthy qualified fuel cell systems. High level Aircraft requirements result in synergy effects on similar transportation applications.

Introduction Synergy Effects Automotive Aircraft 200 000 2000 Production MW / year 200 Aircraft Stationary / Maritime Automotive decrease cost Specific System Weight Targets Specific System Volume Targets 3 kg/kw 2,5 l/kw 1 kg/kw 1,5 l/kw

Introduction System Requirements and Environmental Conditions Variable outside pressures and temperatures, varying between 2000 ft / +43000 ft and -72 C / +56 C Aircraft maneuver loads Vibrations Installation area (pressurized / unpressurized) Transient requirements incl. starting Fuel supply (kerosene vs. hydrogen) Cooling Mission - profiles and safety For each application on board of an Aircraft the most suitable fuel cell system configuration must be defined.

Contents Introduction Fuel Cell System Fuel Cell Operation Comparison Fuel Cell vs. Heat Engine Development and Technical Targets Motivation for Fuel Cell System Application Fuel Cell Systems Architecture Airbus Fuel Cell System Strategy Step 1: Demonstrator Step 2: Fuel Cell Emergency Power System Step 3: Fuel Cell Power Unit Step 4: Fuel Cell as Primary Source Step 5: Alternative Fuels Industrialization Conclusion

Fuel Cell System Fuel Cell Operation Continuously change of chemical energy (hydrogen and oxygen) directly to electrical energy and heat without combustion Fuel Cell Air Hydrogen Anode: 2 H 2 -> 4 H + + 4 e - H 2 = Hydrogen Molecule H + = Proton e - = Electron Overall Reaction: 2 H 2 Electricity Water Water Cathode: O 2 + 4 e - -> 2O 2-2 O 2- + 4 H + -> 2 H 2 O O 2 = Oxygen Molecule O 2- = Oxygen Ion H 2 O = Water + O 2 2 H 2 O + Electrical Energy + Heat

Fuel Cell System Comparison Fuel Cell vs. Heat Engine η G 0 r Re v = = 0 rh ~ 83% Thermal Energy With T 1 =540 C; T 2 =36 C η C T = 1 T 2 = 1 ~ 62% Heat Engine Mechanical Energy η el = P P el mech =~ 90% Chemical Energy Fuel Cell 0 r Re v = = 0 rh ~ 83% η Fuel Cell = η Rev = (-237,13 kj mol -1 )/(-285,8 kj mol -1 ) = 0,8297 = ~83% η Heat Engine = η η Rev C η el = 0,83 0,62 0,9 = 0,46 = ~46% η G Electrical Energy Theoretical maximal achievable Efficiency: ~83%

Fuel Cell System Development and Technical Targets 8,00 7,00 6,00 5,00 DOE System (fueled with gasoline) DOE System(fueled with H2) Airbus Target for System Specific Weight 4,00 3,00 2,00 1,00 0,00 2000 2002 2004 2006 2008 2010 2012 2014

Contents Introduction Fuel Cell System Motivation for Fuel Cell System Application Ecological and Economical Aircraft Operation Aspects Conventional Electrical Power Generation vs. Fuel Cell System Aircraft Mission Fuel and Money Savings Fuel Cell Systems Architecture Airbus Fuel Cell System Strategy Step 1: Demonstrator Step 2: Fuel Cell Emergency Power System Step 3: Fuel Cell Power Unit Step 4: Fuel Cell as Primary Source Step 5: Alternative Fuels Industrialization Conclusion

Motivation for Fuel Cell System Application Ecological and Economical Aircraft Operation Aspects Ecological Aspects: Noise reduction Emission reduction Higher fuel economy Economical Aspects: Weight Reduction Low Maintenance Mission Improvements Elimination of RAT and APU Battery Reduction Potential for on-board water generation

Motivation for Fuel Cell System Application Conventional Electrical Power Generation vs. Fuel Cell System APU Engine No Bleed/Electric Engine Fuel Cell System NO X (Nitrogen Oxides) Emission Reduction NO X Total NO X reduction on ground and in flight CO 2 (Carbon Dioxide) Emission Reduction CO 2 20% 60% CO 2 reduction in flight and on ground No NO X CO 2

Motivation for Fuel Cell System Application Aircraft Mission Example: A330-300: ~100 000 L per flight of ~10 000 km (Average Fuel Consumption) Fuel Use: up to 5 %* Aircraft Systems 95-97% Propulsion up to 5000 L per flight for Aircraft Systems operation

Motivation for Fuel Cell System Application Fuel Savings Efficiency Fuel Use per Flight (10.000 km) Conventional Electrical Power Generation ~40% (Maximum possible today) ~5.000 Liter Fuel Cell System ~60% (Target) ~3.500 Liter Kerosene Savings up to 1.500 Liter per Flight Annual Savings for a fleet of 30 Aircraft A330-300 On average ~ 380 trips per year Assumed Kerosene Costs for 2020: 125 $/barrel (0,79 $/L) Fuel Savings: Money Savings: ~16 Mio L per Year ~13 Mio $ per Year + Emission Fees

Contents Introduction Fuel Cell System Motivation for Fuel Cell System Application Fuel Cell Systems Architecture System Architecture Overview Fuel Processing Comparison PEMFC SOFC Airbus Fuel Cell System Strategy Step 1: Demonstrator Step 2: Fuel Cell Emergency Power System Step 3: Fuel Cell Power Unit Step 4: Fuel Cell as Primary Source Step 5: Alternative Fuels Industrialization Conclusion

Fuel Cell Systems Architecture System Architecture Overview System Integration Kerosene m = ~60 kg/h System Control Water m = ~80 kg/h Air m = ~900 kg/h Fuel Processing m = ~880 kg/h EXH AU S T Fuel Fuel Cell Cell Heat Management H E A T P th = ~160 kw Electricity P el = ~400 kw

Fuel Cell Systems Architecture Key Challenge Fuel Processing Fuel Processing is the Conversion of Kerosene into a hydrogen rich gas. Three Parts are normally necessary: Desulfurization: Removal of sulfur from kerosene. Reforming: Conversion of kerosene into a hydrogen rich gas (Reformat). Gas Cleaning: Cleaning of the reformat (depending on fuel cell). Fuel Processing Air Kerosene Water Desulfuri- zation Adsorption Reforming Steam reforming Partial Oxidation Autothermal Reforming Gas Cleaning Shift Reactor Membrane Preferential Oxidation Hydrogen (+ Rest)

Fuel Cell Systems Architecture Dehydrogenation Challenge: Standard Fuel Processing Methods are too complex. A simple, lightweight and robust solution must be found! Kerosene m = ~1.200 kg/h Fuel Processing Reforming Dehydrogenation of Kerosene Hydrogen Rest Kerosene Dehydrogenation could be one possible solution m = ~17 kg/h m = ~1.183 kg/h

Fuel Cell Systems Architecture Different types of fuel cells with different working conditions are available: Comparison PEMFC SOFC Proton Exchange Membrane Fuel Cell (PEMFC) Fuel Cell with polymer (sulfonic acid polymer Nafion) as electrolyte. Solid Oxide Fuel Cell (SOFC) Fuel Cell with ceramic (Y 2 O 3 -stabilized ZrO 2 Yttria-stabilized zirconia) as electrolyte. Advantages Challenges - High development status (>100 kw el ) - Many thermal cycles possible - Water generation at cathode side - Low working temperature (~80 C) - Complex cooling system - Sensitive against CO - Complex Fuel Processing - Humidification needed - High working temperature (~800 C) - Simple Cooling System - Insensitive against Gas Impurities - Simple Fuel Processing - Highest efficiencies - No humidification needed - Only few thermal cycles possible - Low development status for mobile application (20 kw el ) - Water generation at anode side

Contents Introduction Fuel Cell System Motivation for Fuel Cell System Application Fuel Cell Systems Architecture Airbus Fuel Cell System Strategy Step by Step Approach Industrialization Approach Step 1: Demonstrator Step 2: Fuel Cell Emergency Power System Step 3: Fuel Cell Power Unit Step 4: Fuel Cell as Primary Source Step 5: Alternative Fuels Industrialization Conclusion

Airbus Fuel Cell System Strategy Step by Step Approach Step 5 H 2 Vessel 2007 Time Step 1 Flying Test Bed H 2 Vessel Step 2 Fuel Cell Emergency Power System mid of next decade Kerosene Step 3 Fuel Cell Power Unit end of next decade Kerosene Step 4 20XX Primary Power Supply? Alternative Fuels

Airbus Fuel Cell System Strategy Industrialization Approach Industrialization Kerosene Reforming SOFC Integration 2004 Concepts Overall Airbus Fuel Cell Activities Research & Technology PEM Integration mid of next decade Application to Programs

Contents Introduction Fuel Cell System Motivation Fuel Cell Systems Architecture Airbus Fuel Cell System Strategy Step 1: Demonstrator Overview Installation Area Test Data Collection Step 2: Fuel Cell Emergency Power System Step 3: Fuel Cell Power Unit Step 4: Fuel Cell as Primary Source Step 5: Alternative Fuels Industrialization Conclusion

Step 1: Demonstrator Overview STEP 1 Target (2007) Build Up of a Fuel Cell System Demonstrator Flight Test of the Fuel Cell System Motivation First Safe Fuel Cell System operation on board Flight Test Data Collection, dynamic, heat, loads etc. System Specification Power: 20 kw el Fuel Cell: PEMFC Fuel: Pressurized Hydrogen and Oxygen

Step 1: Demonstrator Installation Area Cooler Power Electronics Fuel Cell H 2 -Storage O 2 -Storage Storing Position 4 Cargo Door

Step 1: Demonstrator Test Data Collection Flight Test Engineering Station

Contents Introduction Fuel Cell System Motivation for Fuel Cell System Application Fuel Cell Systems Architecture Airbus Fuel Cell System Strategy Step 1: Demonstrator Step 2: Fuel Cell Emergency Power System Overview Proposed Installation Area Installation Concept Step 3: Fuel Cell Power Unit Step 4: Fuel Cell as Primary Source Step 5: Alternative Fuels Industrialization Conclusion

Step 2: Fuel Cell Emergency Power System Overview STEP 2 Target (mid of next decade) Substitution of the Ram Air Turbine (RAT) by Fuel Cell Emergency Power System (FCEPS) RAT FCEPS Advantages Support of the All Electric Aircraft Concept Weight Reduction Short System Starting Time Low Maintenance Costs Health Monitoring possible

Step 2: Fuel Cell Emergency Power System Proposed Installation Area Installation area Ram Air Turbine Ram Air Turbine Proposed Fuel Cell Emergency Power System installation area Proposed Electrical Motor Pump installation area

Step 2: Fuel Cell Emergency Power System Installation Concept Motor controller and AC/DC Converter Existing Water Tank Fuel Cell Stack Oxygen Vessels Cooling Pump View from aft cargo compartment into Aircraft lining

Contents Introduction Fuel Cell System Motivation for Fuel Cell System Application Fuel Cell Systems Architecture Airbus Fuel Cell System Strategy Step 1: Demonstrator Step 2: Fuel Cell Emergency Power System Step 3: Fuel Cell Power Unit Overview System Concept Tail Cone Integration Concept Step 4: Fuel Cell as Primary Source Step 5: Alternative Fuels Industrialization Conclusion

Step 3: Fuel Cell Power Unit Overview Target (end of next decade) Power Generation by Fuel Cell System STEP 3 Advantages Support of the All Electric Aircraft Concept Weight Reduction Mission Improvements Elimination of RAT and APU and battery reduction Potential for on-board water generation Emission Reduction System Specification Power Output: 400 kw el (possible configuration: 4*100 kw-system) Fuel: Kerosene Specific Weight: 1 kg/kw Specific Volume: 1,5 L/kW

Step 3: Fuel Cell Power Unit System Concept Fuel Cell Stack Reformer Exhaust Heat Exchanger Condenser Vaporiser Exhaust Turbine Gas Cleaning Desulfurization

Step 3: Fuel Cell Power Unit Tail Cone Integration Concept

Contents Introduction Fuel Cell System Motivation for Fuel Cell System Application Fuel Cell Systems Architecture Airbus Fuel Cell System Strategy Step 1: Demonstrator Step 2: Fuel Cell Emergency Power System Step 3: Fuel Cell Power Unit Step 4: Fuel Cell as Primary Power Source Overview Advanced Aircraft Configurations Step 5: Alternative Fuels Industrialization Conclusion

Step 4: Fuel Cell as Primary Power Source Overview STEP 4 Target (20XX) Primary Power Generation by Fuel Cell System System Specification Power Output: 1000 kw el Fuel: Kerosene High Mature, Reliable and Safe Fuel Cell System!

Step 4: Fuel Cell as Primary Power Source Advanced Aircraft System Configurations Electrical Powered Air Conditioning Advanced Main Engines Electrical Actuators Fuel Cell System Emerging technologies: ¾ Optimized electrical and mechanical systems ¾ Power supply by fuel cell systems ¾ Advanced cabin system concepts ¾ New Aircraft system architectures

Contents Introduction Fuel Cell System Motivation for Fuel Cell System Application Fuel Cell Systems Architecture Airbus Fuel Cell System Strategy Step 1: Demonstrator Step 2: Fuel Cell Emergency Power System Step 3: Fuel Cell Power Unit Step 4: Fuel Cell as Primary Power Source Step 5: Alternative Fuels Overview Industrialization Conclusion

Step 5: Alternative Fuels Overview STEP 5 Target (20XX) Power Generation by Fuel Cell System with Alternative Fuels Renewable Biomass CO 2 -Uptake = CO 2 -Emissions Conversion New Tank System Alternative Fuels: Desulfurized Kerosene Hydrogen Ethanol/Methanol Biofuels New Aircraft Generation Hydrogen Fuelled Aircraft New Tank System Fuel Cell System without Fuel Processing

Contents Introduction Fuel Cell System Motivation for Fuel Cell System Application Fuel Cell Systems Architecture Airbus Fuel Cell System Strategy Step 1: Demonstrator Step 2: Fuel Cell Emergency Power System Step 3: Fuel Cell Power Unit Step 4: Fuel Cell as Primary Power Source Step 5: Alternative Fuels Industrialization Partners Airbus Growing Systems Test Lab Conclusion

Industrialization Partners: Universities and Institutes: Companies: Industrialisation Partners:

Industrialization Growing Systems Test Lab in Hamburg Test Rig with Integrated PEM Fuel Cell Test Rig with Reformer for SOFC Application Test Rig for SOFC

Contents Introduction Fuel Cell System Motivation for Fuel Cell System Application Fuel Cell Systems Architecture Airbus Fuel Cell System Strategy Ongoing Projects and Activities Step 1: Demonstrator Step 2: Fuel Cell Emergency Power System Step 3: Fuel Cell Power Unit Step 4: Fuel Cell as Primary Power Source Step 5: Alternative Fuels Industrialization Conclusion

Conclusion Airbus is involved/driving projects and tasks to bring forward the fuel cell industrialization with major suppliers especially in aeronautical applications Airbus will gain an early integration with the step by step approach Soon experience with applied hardware Fundamental basis for further development Airbus is committed to apply fuel cell systems with strong support by industrial partners and system suppliers Airbus is at the forefront of fuel cell technology and innovation Our advanced, environmental friendly and economical products will ensure an excellent competitiveness

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