SDS ID NO.: 0346MAR019 Revision Date 03/16/2016 SAFETY DATA SHEET 1. IDENTIFICATION Product Name: Synonym: Product Code: Chemical Family: Recommended Use: Restrictions on Use: Marathon Petroleum Biodiesel B99 B99 Biodiesel, Soy Biodiesel, Rapeseed Biodiesel, Tallow Biodiesel, Canola Biodiesel, Soybean Esters B99 Biodiesel, SME Soy Methyl Ester, Biodiesel, B99.9, Biomass Based Diesel 0346MAR019 Fatty Acid Methyl Esters Fuel. All others. Manufacturer, Importer, or Responsible Party Name and Address: MARATHON PETROLEUM COMPANY LP 539 South Main Street Findlay, OH 45840 SDS information: 1-419-421-3070 Emergency Telephone: 1-877-627-5463 Classification 2. HAZARD IDENTIFICATION OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Skin sensitization Category 1B Carcinogenicity Category 2 Aspiration toxicity Category 1 Acute aquatic toxicity Category 2 Hazards Not Otherwise Classified (HNOC) Label elements Danger EMERGENCY OVERVIEW May cause an allergic skin reaction Suspected of causing cancer May be fatal if swallowed and enters airways Toxic to aquatic life SDS ID NO.: 0346MAR019 Product name: Marathon Petroleum Biodiesel B99 Page 1 of 12
Appearance Yellow Liquid Physical State Liquid Odor Slight Precautionary Statements - Prevention Obtain special instructions before use Do not handle until all safety precautions have been read and understood Avoid breathing mist/vapors/spray Wear protective gloves/protective clothing/eye protection/face protection Contaminated work clothing should not be allowed out of the workplace Avoid release to the environment Precautionary Statements - Response IF exposed or concerned: Get medical attention IF ON SKIN: Wash with plenty of soap and water If skin irritation or rash occurs: Get medical attention Wash contaminated clothing before reuse IF SWALLOWED: Immediately call a POISON CENTER or doctor Do NOT induce vomiting Precautionary Statements - Storage Store locked up Precautionary Statements - Disposal Dispose of contents/container at an approved waste disposal plant 3. COMPOSITION/INFORMATION ON INGREDIENTS Biodiesel is a complex mixture of C16-C18 methyl esters derived from the processing of vegetable oil or animal fat and diesel fuel. Composition Information: Name CAS Number % Concentration 61788-61-2 0-100 67784-80-9 0-100 73891-99-3 0-100 Biodiesel (Fatty Acid, Methyl Ester) 68937-84-8 0-100 129828-16-6 0-100 68476-34-6 <1 All concentrations are percent by weight unless material is a gas. Gas concentrations are in percent by volume. First Aid Measures 4. FIRST AID MEASURES General Advice: Inhalation: Skin Contact: In case of accident or if you feel unwell, seek medical advice immediately (show directions for use or safety data sheet if possible). Move victim to fresh air. Provide respiratory support, if necessary. Get medical attention if cough or other respiratory symptoms develop. Immediately wash exposed skin with plenty of soap and water while removing contaminated clothing and shoes. Get medical attention if irritation or rash occurs. Wash contaminated clothing before re-use. SDS ID NO.: 0346MAR019 Product name: Marathon Petroleum Biodiesel B99 Page 2 of 12
Eye Contact: Ingestion: Flush immediately with large amounts of water for at least 15 minutes. Eyelids should be held away from the eyeball to ensure thorough rinsing. Gently remove contacts while flushing. Get medical attention if irritation persists. If swallowed, DO NOT induce vomiting. If spontaneous vomiting occurs, keep head below hips, or if patient is lying down, turn body and head to side to prevent aspiration and monitor for breathing difficulty. Get immediate medical attention. Most important signs and symptoms, both short-term and delayed with overexposure Adverse Effects: May cause sensitization by skin contact. Symptoms may include redness, itching, and inflammation. Aspiration hazard. May cause coughing, chest pains, shortness of breath, pulmonary edema and/or chemical pneumonitis. Repeated or prolonged skin contact may cause drying, reddening, itching and cracking. Preexisting skin conditions and/or respiratory disorders may be aggravated by exposure to this product. Indication of any immediate medical attention and special treatment needed Notes To Physician: INGESTION: Do not induce vomiting. Low viscosity product can be sucked into the lungs and cause damage after swallowing or vomiting. The metabolism of fatty acid methyl ester may release free methanol in the body that could induce metabolic acidosis with delayed effects. If a large amount of product is ingested, i.e. several ounces, consider the use of ethanol or fomepizole (Antizol) and hemodialysis. Consult standard literature or contact a poison control center for treatment details. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media For small fires, Class B fire extinguishing media such as CO2, dry chemical, foam or water spray can be used. For large fires, water spray, fog or foam can be used. Firefighting should be attempted only by those who are adequately trained and equipped with proper protective equipment. Unsuitable extinguishing media Do not use straight water streams to avoid spreading fire. Specific hazards arising from the chemical This product is not a flammable liquid per the OSHA Hazard Communication Standard, but may ignite and/or burn at temperatures exceeding the flash point. Spontaneous combustion may occur under high temperature, closed conditions if material is absorbed in various fiber matrices and oxygen is present (e.g. oily rags). Hazardous combustion products Smoke, carbon monoxide, and other products of incomplete combustion. Explosion data Sensitivity to Mechanical Impact No. Sensitivity to Static Discharge No. Special protective equipment and precautions for firefighters Firefighters should wear full protective clothing and positive-pressure self-contained breathing apparatus (SCBA) with a full face-piece, as appropriate. Avoid using straight water streams. Water spray and foam (AFFF/ATC) must be applied carefully to avoid frothing and from as far a distance as possible. Avoid excessive water spray application. Keep surrounding area cool with water spray from a distance and prevent further ignition of combustible material. Keep run-off water out of sewers and water sources. Additional firefighting tactics NFPA Health 2 Flammability 1 Instability 0 Special Hazard - SDS ID NO.: 0346MAR019 Product name: Marathon Petroleum Biodiesel B99 Page 3 of 12
6. ACCIDENTAL RELEASE MEASURES Personal precautions: Keep public away. Isolate and evacuate area. Shut off source if safe to do so. Eliminate all ignition sources. All contaminated surfaces will be slippery. Protective equipment: Use personal protection measures as recommended in Section 8. Emergency procedures: Environmental precautions: Methods and materials for containment: Advise authorities and National Response Center (800-424-8802) if the product has entered a water course or sewer. Notify local health and pollution control agencies, if appropriate. Avoid release to the environment. Avoid subsoil penetration. Contain liquid with sand or soil. Prevent spilled material from entering storm drains, sewers, and open waterways. Methods and materials for cleaning up: Use suitable absorbent materials such as vermiculite, sand, or clay to clean up residual liquids. Recover and return free product to proper containers. Clean contaminated surface thoroughly. 7. HANDLING AND STORAGE Safe Handling Precautions: Storage Conditions: Incompatible Materials NEVER SIPHON THIS PRODUCT BY MOUTH. Do not expose to heat, open flames, strong oxidizers or other sources of ignition. Avoid repeated and prolonged skin contact. Exercise good personal hygiene including removal of soiled clothing and prompt washing with soap and water. Do not cut, drill, grind or weld on empty containers since explosive residues may remain. Refer to applicable EPA, OSHA, NFPA and consistent state and local requirements. Store in properly closed containers that are appropriately labeled and in a cool, well-ventilated area. Store wiping rags in metal cans with tightly fitting lids. Corrosion and microbial growth are promoted by the presence of water. Avoid contamination by storing in water-free tanks with scheduled water drainage. Contact with copper/alloys, lead, tin and zinc may result in increased sediment and deposits that can plug filters. Degradation can be avoided by preventing temperature extremes and the presence of air during storage. Strong oxidizing agents. 8. EXPOSURE CONTROLS/PERSOL PROTECTION Name ACGIH TLV OSHA PELS: OSHA - Vacated PELs NIOSH IDLH 61788-61-2 67784-80-9 73891-99-3 Biodiesel (Fatty Acid, Methyl Ester) 68937-84-8 129828-16-6 68476-34-6 100 mg/m 3 TWA Skin - potential significant contribution to overall exposure by the cutaneous route - - - Notes: The manufacturer has voluntarily elected to provide exposure limits contained in OSHA's 1989 air contaminants standard in its SDSs, even though certain of those exposure limits were vacated in 1992. SDS ID NO.: 0346MAR019 Product name: Marathon Petroleum Biodiesel B99 Page 4 of 12
Engineering measures: Ensure adequate ventilation, especially in confined areas. Local or general exhaust required when using at elevated temperatures that generate vapors or mists. Use mechanical ventilation equipment that is explosion-proof. Personal protective equipment Eye protection: Skin and body protection: Respiratory protection: Hygiene measures: Use goggles or face-shield if the potential for splashing exists. Wear neoprene, nitrile or PVA gloves to prevent skin contact. Glove suitability is based on workplace conditions and usage. Contact the glove manufacturer for specific advice on glove selection and breakthrough times. Breathing apparatus needed when aerosol or mist is formed. Observe respirator assigned protection factors (APFs) criteria cited in federal OSHA 29 CFR 1910.134. Self-contained breathing apparatus should be used for fire fighting. Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes and clothing. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical State Liquid Appearance Yellow Liquid Color Pale yellow Odor Slight Odor Threshold Property Values (Method) Melting Point / Freezing Point Initial Boiling Point / Boiling Range 288-366 C / 550-690 F (ASTM D1160) Flash Point 171-199 C / 340-390 F (ASTM D93) Evaporation Rate Flammability (solid, gas) Flammability Limit in Air (%): Upper Flammability Limit: Lower Flammability Limit: Explosion limits: Vapor Pressure Vapor Density Specific Gravity / Relative Density 0.88 Water Solubility Solubility in other solvents Partition Coefficient Decomposition temperature ph: Not applicable Autoignition Temperature 374-449 C / 705-840 F Kinematic Viscosity 3.90-4.05 cst @ 40 C (ASTM D445) Dynamic Viscosity Explosive Properties VOC Content (%) Density Bulk Density 10. STABILITY AND REACTIVITY Reactivity Chemical stability The product is non-reactive under normal conditions. The material is stable at 70 F (21 C ), 760 mmhg pressure. SDS ID NO.: 0346MAR019 Product name: Marathon Petroleum Biodiesel B99 Page 5 of 12
Possibility of hazardous reactions Hazardous polymerization Conditions to avoid Incompatible Materials Hazardous decomposition products None under normal processing. Will not occur. Excessive heat, sources of ignition, open flame. Water contamination during storage. Strong oxidizing agents. None known under normal conditions of use. Potential short-term adverse effects from overexposures 11. TOXICOLOGICAL INFORMATION Inhalation Eye contact Skin contact Ingestion Excessive inhalation of mist may result in respiratory irritation. Overheating may produce vapors which may cause respiratory irritation, dizziness and nausea. Produces little or no irritation on direct contact with the eye. May cause sensitization by skin contact. Prolonged and repeated contact may cause defatting and drying of the skin and may lead to irritation and/or dermatitis. Ingestion of large amounts may cause gastrointestinal disturbances. Aspiration into lungs may cause chemical pneumonia and lung damage. Acute toxicological data Name Oral LD50 Dermal LD50 Inhalation LC50 - - - 61788-61-2 > 5000 mg/kg (Rat) > 5000 mg/kg (Rabbit) - 67784-80-9 - - - 73891-99-3 Biodiesel (Fatty Acid, Methyl Ester) > 2000 mg/kg (Rat) - - 68937-84-8 - - - 129828-16-6 68476-34-6 > 5000 mg/kg (Rat) > 2000 mg/kg (Rabbit) >1 - <5 mg/l (Rat) 4 h Delayed and immediate effects as well as chronic effects from short and long-term exposure BIODIESEL (SOYBEAN DERIVED): Dermal sensitization study (Guinea Pigs) repeat insult patch procedure with induction and challenge patches indicated a positive sensitization response. PETROLEUM MIDDLE DISTILLATES: May cause damage to organs after repeated and prolonged dermal overexposure. Repeated dermal application for 13 weeks has produced decreased liver, thymus, and spleen weights. Microscopic alterations included liver enlargement and damage. Petroleum middle distillates have produced skin tumors in mice after repeated and prolonged skin contact and have tested positive with in vitro genotoxicity tests. Additional studies indicated prolonged skin irritation contributes to tumor development. Repeated dermal exposures to high concentrations of petroleum middle distillates in test animals resulted in reduced litter size and litter weight, and increased fetal resorptions at maternally toxic doses. Dermal exposure to high concentrations resulted in severe skin irritation with weight loss and some mortality. Adverse effects related to the physical, chemical and toxicological characteristics Signs and Symptoms May cause allergic skin reaction. Symptoms may include redness, itching, and inflammation. Aspiration hazard. May cause coughing, chest pains, shortness of breath, SDS ID NO.: 0346MAR019 Product name: Marathon Petroleum Biodiesel B99 Page 6 of 12
pulmonary edema and/or chemical pneumonitis. Repeated or prolonged skin contact may cause drying, reddening, itching and cracking. Preexisting skin conditions and/or respiratory disorders may be aggravated by exposure to this product. Sensitization Mutagenic effects Carcinogenicity Name 61788-61-2 67784-80-9 Biodiesel (Rapeseed derived) 73891-99-3 Biodiesel (Fatty Acid, Methyl Ester) 68937-84-8 129828-16-6 68476-34-6 Reproductive toxicity May cause sensitization by skin contact. Not expected to be a respiratory sensitizer. None known. Suspected of causing cancer. Cancer designations are listed in the table below ACGIH IARC NTP OSHA (Class) (Class) Confirmed animal carcinogen (A3) None known. Not Classifiable (3) Specific Target Organ Toxicity (STOT) - single exposure Specific Target Organ Toxicity (STOT) - repeated exposure Aspiration hazard Not classified. Not classified. May be fatal if swallowed or vomited and enters airways. 12. ECOLOGICAL INFORMATION Ecotoxicity The 24-hour LC50 for biodiesel is 4.65 mg/l in Daphnia magna (water flea) juveniles (J. Air &WasteManage.Assoc.57:286 296).Thisproductshouldbeconsideredtoxictoaquatic organisms. Name Algae/aquatic plants Fish Toxicity to Crustacea Microorganisms 61788-61-2 67784-80-9 Biodiesel (Rapeseed derived) 73891-99-3 Biodiesel (Fatty Acid, Methyl Ester) 68937-84-8 129828-16-6 68476-34-6-96-hr LC50 = 35 mg/l Fathead minnow (flow-through) - 48-hr EL50 = 6.4 mg/l Daphnia magna Persistence and degradability Expected to be readily biodegradable under aerobic conditions. SDS ID NO.: 0346MAR019 Product name: Marathon Petroleum Biodiesel B99 Page 7 of 12
Bioaccumulation Mobility in soil Other adverse effects Not expected to bioaccumulate in aquatic organisms. Insoluble and floats on water. May partition into air, soil and water. No information available. 13. DISPOSAL CONSIDERATIONS Description of Waste Residues Long-term storage may result in decomposition of the oil and could result in a rancid odor. Safe Handling of Wastes Handle in accordance with applicable local, state, and federal regulations. Use personal protection measures as required. Do not expose to heat, open flames, strong oxidizers or other sources of ignition. Disposal of Wastes / Methods of Disposal The user is responsible for determining if any discarded material is a hazardous waste (40 CFR 262.11). Dispose of in accordance with federal, state and local regulations. Methods of Contaminated Packaging Disposal Empty containers should be completely drained and then discarded or recycled, if possible. Do not cut, drill, grind or weld on empty containers since explosive residues may be present. Dispose of in accordance with federal, state and local regulations. 14. TRANSPORT INFORMATION DOT (49 CFR 172.101): UN Proper Shipping Name: UN/Identification No: Class: Packing Group: TDG (Canada): UN Proper Shipping Name: UN/Identification No: Transport Hazard Class(es): Packing Group: Not Regulated Not applicable Not Regulated US Federal Regulatory Information: 15. REGULATORY INFORMATION US TSCA Chemical Inventory Section 8(b): This product and/or its components are listed on the TSCA Chemical Inventory. EPA Superfund Amendment & Reauthorization Act (SARA): SARA Section 302: This product does not contain any component(s) included on EPA's Extremely Hazardous Substance (EHS) List. Name CERCLA/SARA - Section 302 Extremely Hazardous Substances and TPQs Biodiesel (Fatty Acid, Methyl Ester) SARA Section 304: This product may contain component(s) identified either as an EHS or a CERCLA Hazardous substance which in case of a spill or release may be subject to SARA reporting requirements: SDS ID NO.: 0346MAR019 Product name: Marathon Petroleum Biodiesel B99 Page 8 of 12
Name Biodiesel (Fatty Acid, Methyl Ester) Hazardous Substances RQs SARA Section 311/312: The following EPA hazard categories apply to this product: Acute Health Hazard Chronic Health Hazard SARA Section 313: This product may contain component(s), which if in exceedance of the de minimus threshold, may be subject to the reporting requirements of SARA Title III Section 313 Toxic Release Reporting (Form R). Name CERCLA/SARA 313 Emission reporting: None None None Biodiesel (Fatty Acid, Methyl Ester) None None None State and Community Right-To-Know Regulations: The following component(s) of this material are identified on the regulatory lists below: Louisiana Right-To-Know: California Proposition 65: New Jersey Right-To-Know: Pennsylvania Right-To-Know: Massachusetts Right-To Know: Florida Substance List: Rhode Island Right-To-Know: Michigan Critical Materials Register List: Massachusetts Extraordinarily Hazardous California - Regulated Carcinogens: Pennsylvania RTK - Special Hazardous New Jersey - Special Hazardous New Jersey - Environmental Hazardous Substances List: Illinois - Toxic Air Contaminants: New York - Reporting of Releases Part 597 - List of Hazardous Louisiana Right-To-Know: California Proposition 65: New Jersey Right-To-Know: Pennsylvania Right-To-Know: Massachusetts Right-To Know: Florida Substance List: Rhode Island Right-To-Know: Michigan Critical Materials Register List: Massachusetts Extraordinarily Hazardous California - Regulated Carcinogens: Pennsylvania RTK - Special Hazardous New Jersey - Special Hazardous New Jersey - Environmental Hazardous SDS ID NO.: 0346MAR019 Product name: Marathon Petroleum Biodiesel B99 Page 9 of 12
Substances List: Illinois - Toxic Air Contaminants: New York - Reporting of Releases Part 597 - List of Hazardous Louisiana Right-To-Know: California Proposition 65: New Jersey Right-To-Know: Pennsylvania Right-To-Know: Massachusetts Right-To Know: Florida Substance List: Rhode Island Right-To-Know: Michigan Critical Materials Register List: Massachusetts Extraordinarily Hazardous California - Regulated Carcinogens: Pennsylvania RTK - Special Hazardous New Jersey - Special Hazardous New Jersey - Environmental Hazardous Substances List: Illinois - Toxic Air Contaminants: New York - Reporting of Releases Part 597 - List of Hazardous Biodiesel (Fatty Acid, Methyl Ester) Louisiana Right-To-Know: California Proposition 65: New Jersey Right-To-Know: Pennsylvania Right-To-Know: Massachusetts Right-To Know: Florida Substance List: Rhode Island Right-To-Know: Michigan Critical Materials Register List: Massachusetts Extraordinarily Hazardous California - Regulated Carcinogens: Pennsylvania RTK - Special Hazardous New Jersey - Special Hazardous New Jersey - Environmental Hazardous Substances List: Illinois - Toxic Air Contaminants: New York - Reporting of Releases Part 597 - List of Hazardous Louisiana Right-To-Know: California Proposition 65: New Jersey Right-To-Know: Pennsylvania Right-To-Know: Massachusetts Right-To Know: Florida Substance List: Rhode Island Right-To-Know: Michigan Critical Materials Register List: Massachusetts Extraordinarily Hazardous California - Regulated Carcinogens: Pennsylvania RTK - Special Hazardous New Jersey - Special Hazardous New Jersey - Environmental Hazardous Substances List: Illinois - Toxic Air Contaminants: New York - Reporting of Releases Part 597 - List of Hazardous SDS ID NO.: 0346MAR019 Product name: Marathon Petroleum Biodiesel B99 Page 10 of 12
Louisiana Right-To-Know: California Proposition 65: New Jersey Right-To-Know: SN 2444 Pennsylvania Right-To-Know: Massachusetts Right-To Know: Florida Substance List: Rhode Island Right-To-Know: Michigan Critical Materials Register List: Massachusetts Extraordinarily Hazardous California - Regulated Carcinogens: Pennsylvania RTK - Special Hazardous New Jersey - Special Hazardous New Jersey - Environmental Hazardous Substances List: SN 2444 TPQ: 10000 lb (Under N.J.A.C. 7:1G, environmental hazardous substances in mixtures such as gasoline or new and used petroleum oil may be reported under these categories) Illinois - Toxic Air Contaminants: New York - Reporting of Releases Part 597 - List of Hazardous Canada DSL/NDSL Inventory: Canadian Regulatory Information: This product and/or its components are listed either on the Domestic Substances List (DSL) or are exempt. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the SDS contains all of the information required by those regulations. Name Canada - WHMIS: Classifications of Canada - WHMIS: Ingredient Disclosure: Uncontrolled product according to - WHMIS classification criteria D2B 1% Uncontrolled product according to - WHMIS classification criteria Biodiesel (Fatty Acid, Methyl Ester) Uncontrolled product according to - WHMIS classification criteria Uncontrolled product according to - WHMIS classification criteria B3,D2A,D2B 0.1% Note: 16. OTHER INFORMATION Prepared By Toxicology and Product Safety Revision Notes Revision Date 03/16/2016 Revised Sections The following sections ( ) have been updated: 2. HAZARD IDENTIFICATION 4. FIRST AID MEASURES 6. ACCIDENTAL RELEASE MEASURES 7. HANDLING AND STORAGE 9. PHYSICAL AND CHEMICAL PROPERTIES 11. TOXICOLOGICAL INFORMATION 12. ECOLOGICAL INFORMATION SDS ID NO.: 0346MAR019 Product name: Marathon Petroleum Biodiesel B99 Page 11 of 12
Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is intended as guidance for safe handling, use, processing, storage, transportation, accidental release, clean-up and disposal and is not considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. SDS ID NO.: 0346MAR019 Product name: Marathon Petroleum Biodiesel B99 Page 12 of 12