SOFC Development for Aircraft Application

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SOFC Development for Aircraft Application G. Schiller German Aerospace Center (DLR) Institute of Technical Thermodynamics Pfaffenwaldring 38-40, D-70569 Stuttgart, Germany 1 st International Workshop on SOFCs: How to Bridge the Gap from R & D to Market? Québec City Convention Centre, Québec, May 15 th, 2005

Outline Introduction Operational Requirement of Aircraft Power Sources Aircraft Fuel Cell System Concepts Fuel Cell Development at Airbus Fuel Cell Development at Boeing Conclusion

Fuel Cells for Aircraft Application In principle, there are 2 options for fuel cell application in airplanes: fuel cells for propulsion fuel cells as electrical energy generator In both cases of application: The industrialization of fuel cell systems and its integration is in the very beginning.

Fuel Cells for Propulsion Development of an unmanned aircraft vehicle (Pathfinder Plus) by NASA for observation missions Operation with solar-generated hydrogen to be used in a regenerative propulsion system Combination of a solar array for electricity generation with an electrolyzer and a fuel cell for a continuous operation of the electric motor of the propulsion system Development of a fuel cell powered piloted electric airplane by Boeing Integration of a PEM fuel cell system in an electric demonstrator airplane (motor glider) Flight tests of the fuel cell-powered motor glider On commercial transports fuel cells and electric motor will not replace jet engines. Fuel cells can replace gas turbine APU while on ground and for back up use in flight

Future Power Optimised Aircraft Configuration The aircraft industry has to accomplish the continuously growing requirements of low emissions and low operating costs One approach is a more electric aircraft configuration in a new system architecture Kerosene supplied fuel cell systems are a promising alternative as secondary/primary power source in a more electric aircraft configuration In order to achieve the challenging aims the aircraft development has to investigate and to apply technologies such as: - further replacement of pneumatic and hydraulic routings by electric wires - increase of electrical power as primary source - new electrical system components, e. g. electrical powered air conditioning - electric wing anti ice - application of fuel cell systems as a power source - main engines optimised for propulsion generation only

Possible Aircraft Fuel Cell System Concepts Main characteristics: Operating Temperature Efficiency Fuel Fuel Processing Carbon monoxide Sulfur Power density Maturity level PEM approx 60 80 C up to 40 % kerosene no residual contamination CO must be removed sulfur must be removed < 1 kg/kw pending on system concept SOFC approx. 800 1000 C up to 60 % kerosene residual contamination tolerable less susceptible to CO less susceptible to sulfur < 1 kg/kw improvement necessary

Aircraft Power Sources: Conventional Aircraft Power Architecture - Bleed Air power (e.g. for cabin air conditioning, main engine start) - Electrical power (e.g. for lights, cabin entertainment) - Hydraulic Power (e.g. flight controls) Auxiliary Power Unit (APU) Ram Air Turbine (RAT) Bleed air and / or electrical power (AC) AIRBUS DEUTSCHLAND GmbH. All rights reserved. Confidential and proprietary document. Emergency hydraulic and electrical power (AC) Main Engines Hydraulic, bleed air and electrical power (AC) Aircraft Batteries Electrical power (DC) Electrical, Hydraulic and Main Engines APU RAT Battery Bleed Air Power (kw) 1000 550 (ground) 25 3

Conventional Aircraft Power Architecture Aircraft Main Power Consumers (peak values): Cabin Systems Ice and Rain Protection AIRBUS DEUTSCHLAND GmbH. All rights reserved. Confidential and proprietary document. Flight Controls Landing Gear Air Conditioning Engine Starting Max. Power Consumption (kw) Air Conditioning Ice and Rain Protection Cabin Systems Engine Starting Landing Gear Flight Controls 500 250 100 300 50 150

Future Power Optimized Aircraft Configuration New technologies opportunities: Fuel Cell System AIRBUS DEUTSCHLAND GmbH. All rights reserved. Confidential and proprietary document. Electrical Powered Air Conditioning Advanced Main Engines Electrical Actuators

Future Power Optimized Aircraft Configuration Expected benefits of fuel cell system application: Low Emissions High Efficiency - significant NOx reduction on ground and in flight - Efficiency increase due to applied technologies AIRBUS DEUTSCHLAND GmbH. All rights reserved. Confidential and proprietary document. Fuel Economy - up to 75 % Fuel Reduction on ground - 30 % Fuel Reduction in flight Noise Reduction - excellent potential for a significant on ground noise reduction

Fuel Saving Opportunity On ground: Typical turbine powered APU Future 2015 SOFC APU (Boeing) 15 % efficient 60 % efficient over average operating cycle at std. sea-level conditions 75 % less fuel used In-Flight: Typical turbine-powered APU Future 2015 SOFC APU (Boeing) 40-45 % efficient ~ 75 % efficient Jet-A to electrical during cruise overall system at cruise 40 % less fuel used Source: Boeing

APU Configurations In principle, fuel cells can replace the existing emergency generation and batteries, the existing APU and the generators. Aircraft batteries provide: - Start up power - fill-in power for short-term interruptions - electrical noise filtering - emergency power Evaluation of fuel cells for this application by Boeing and Cessna Aircraft Company (Design study) Cessna Citation X: 10-passenger business jet Boeing 737: 108-passenger airliner

Operational Requirements of a Battery Performance characteristics for steady-state, short circuit and fault clearing conditions Ambient Temperature range: -40 C +70 C (start up) -55 C +40 C (operation) Altitude: 1.000 ft 51.000 ft Tolerance of humidity, vibration and contamination Emergency power for 30 60 minutes Power: 2.4 kw 85 A at 28 VDC

Main Characteristics of Emergency Generation and Batteries o electrical power: about 50 kw o minimum current: > 1 ma o time to start in flight: immediately when needed in emergency case o time to start on ground: no more than 1 min o overload capability: 2 In/5s or 1.5 In/5 mn o stand alone running time in flight: 30 min o stand alone running time on ground: 1 hour o environmental condition: -55 C/+85 C

Main Characteristics of APU system o start time: less than 120 seconds o electrical output: 115 kva, 110 kva in 41.000 ft altitude o electrical overload capability: 155 kva for 5 minutes 218 kva for 5 seconds up to 35.000 ft altitude o the system is self-controlled by its own electronic controller o the system has to be started from a/c electrical system (batteries included) o the system shall be capable to deliver the required performance after a deterioration time of 10.000 hours o the APU is installed in a fire proofed compartment (withstand ca. 1.100 C for 15 min) o specific fuel consumption is below 0.4 kg fuel/kwh

Possible Aircraft Fuel Cell System Concepts Aircraft specific features have to be considered for a fuel cell system integration: On board fuel processing including desulphurisation and kerosene reforming Aeronautical requirements and standards - low installation weight/high power density - system monitoring and controlling - high reliability and system robustness Environmental operating conditions - Varying outside pressures and temperature, e. g. at 41.000 ft 0.18 bar, -57 C - aircraft manoeuvre loads Turbo-machinery is an optimum supplement at high altitude ambient conditions for fuel cell systems Fuel cell hybrid systems are smaller, lighter and have a better dynamic response compared to non-hybrid fuel cell systems Fuel cell hybrid systems have a high power density and offer a better fuel efficiency than non-pressurized fuel cell systems

Operating Conditions Change of the ambient state during the mission Ambient pressure and temperature reduction is a function of the flight altitude Flight altitude of 36.000 ft 0.2 bar ambient pressure 70 K temperature reduction Decrease of Nernst voltage from 0.79 V to 0.74 V during atmospheric operation from 0.86 V to 0.82 V during pressurised operation Decrease of efficiency of 5 6 % Increased air flow required to obtain the same amount of oxygen which is needed at sealevel

Performance Requirements for Aircraft Application Requirements by the aircraft application (SECA program) Attributes Total power Current capability -5 kw (planar) > 100 kw (tubular) > 1 MW (planned) Goal 5 kw for early aviation demo 145 kw for 100 passenger 450 kw for 305 passenger 3-10 kw (SECA transportation) Specific power for entire SOFC system incl. BOP Area specific power density Fuel reformation Sulfur tolerance 0.02 0.04 kw/kg 0.5-1 W/cm² cell 0.4 W/cm² stack Mature at the industrial scale Limited exp. with logistic fuels 0.5 kw/kg (NASA/DOD) 0.1 kw/kg (DOE-SECA) 2 W/cm² cell > 1 W/cm² stack Compact, lightweight system with high conversion efficiency 300 700 ppm current jet fuel sulfur level Aircraft life 40,000 hrs

Airbus General Approach Airbus energy source approach is a step by step approach for Fuel Cell System Application: Ram air turbine (RAT) substitution for early application AIRBUS DEUTSCHLAND GmbH. All rights reserved. Confidential and proprietary document. Kerosene supplied fuel cell system to replace the APU Primary power source towards more electric aircraft Hydrogen based future aircraft

Airbus General Approach Primary Power Supply Fuel Cell System? APU Replacement RAT Replacement Time 2010 2013/15 20xx 20yy Hydrogen Kerosene AIRBUS DEUTSCHLAND GMBH. All rights reserved. Confidential and proprietary document. H2 Bottle H2 Tank Step by Step approach Under Study

SOFC Spray Concept of DLR Plasma Deposition Technology Thin-Film Cells Ferritic Substrates and Interconnects Compact Design with Thin Metal Sheet Substrates Brazing, Welding and Glass Seal as Joining and Sealing Technology air channel fuel channel oxygen/air not used air Bipolar plate protective coating contact layer cathode current collector cathode active layer electrolyte anode porous metallic substrate Bipolar plate fuel brazing not used fuel + H O 2 (not in scale) Schematic of DLR-SOFC Design with Metallic Substrate Objective of DLR Development: Light-weight stack of 5 kw power with high performance, rapid heat-up and good thermal cycling properties Institute for Technical Thermodynamics

Institute for Technical Thermodynamics Cell Design for APU Application

SOFC APU Challenges at Boeing o Technology ready by 2010 (enables a 2015 entry into service) o High system power density (0.5 kw/kg system goal) o Ability to reform Jet-A fuel (1000 ppm fuel sulfur level tolerance goal) o 40.000 hour life in airplane environment

Source: Boeing

Study of a Hybrid SOFC for APU Replacement Design of a hybrid SOFC system that incorporates jet fuel reformers Pure enough source of H 2 for PEM fuel cell is impractical because of the complex nature of jet fuel Airplane platform: 777-200 ER-sized aircraft 440 kw of electrical power in flight as well as on the ground SOFCo design: 440 kw hybrid APU using: - a planar SOFC - single stage turbo-compressor - autothermal reformer (ATR) SOFCo hybrid fuel cell APU concept Source: SOFCo

Study of a Hybrid SOFC for APU Replacement Cruise Ground Total Power, kw 440.4 432.1 Fuel Cell DC Power, kw 404.9 347.0 Turbine AC Power, kw 35.5 84.2 SOFC fuel cell APU estimated performances Source: SOFCo

Study of a Hybrid SOFC for APU Replacement Fuel cell APU concept in aft end of study aircraft Source: Boeing

APU Application Replacement of APU by fuel cells is still in the stage of system studies 1:1 replacement is not feasible completely new aircraft architecture is required More electric aircraft (MEA): electricity instead of pneumatic energy ( environmental control) System studies are performed to determine concept feasibility, assess system-level benefits and identify technology gaps Study of fuel processing alternatives, fuel desulphurisation, water recovery system ( gray water ) Evaluation of best system configuration in terms of overall system performance, weight and size

Aircraft Specific Tasks o o o o o o o Development of kerosene reformer and means to prevent detrimental Sulphur effects Development of reformer and cells with higher impurity tolerance Study of low temperature and cold-start influence on fuel cells Study of influence of oxygen pressure reduction Study of product water quality Design, tests and optimization of the system with the components Reformer, Fuel Cell, Micro gas turbine and Air compression Study of influence of mechanical stress due to vibrations and shocks

Synergy Effects with Automotive / Maritime Technologies 2000 200 Aircraft Stationary / Maritime synergy effects decrease cost Production MW / year 200 000 AIRBUS DEUTSCHLAND GmbH. All rights reserved. Confidential and proprietary document.