Constant Known Conductivity Fuel Systems. & how they assist fuel conductivity management

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Constant Known Conductivity Fuel Systems & how they assist fuel conductivity management Background JF-1A in-line conductivity sensor is designed to provide high-accuracy, continuous measurement of conductivity levels of distillate fuels in flowing and non-flowing applications. The unique sensor offers fuel producers and distributors a comprehensive means of evaluating conductivity levels on a 24/7 real-time basis. Conductivity measurements can be independently displayed or linked to existing DCS- Scada systems. The sensor fully conforms to the requirements of ASTM D2624. Sensor Measurement Principle JF-1A in-line conductivity sensor has an integral probe consisting of two concentric electrodes. When the probe is immersed in fuel, a very low frequency AC voltage is applied to the electrodes. Conduction through the fuel results in an AC electrical current that is amplified, detected and output as either direct serial ASCII data or as a standard 4-20 ma industrial current loop. The use of a precision AC voltage overcomes problems associated with electrode polarization, impedance, and residual DC charges thereby allowing the sensor to accurately measure conductivity in flowing fuel. ASTM method development testing (round-robin) has demonstrated that the sensor provides accurate, highly stable conductivity measurement in fuels flowing up to 30 ft/sec. Applications In-line conductivity measurement assists with the correct additisation of fuel throughout the distribution line. In spite of existing conductivity controls, it is not uncommon for the installation of in-line measurement to report high or variable conductivity levels, this information provides fuel producers and distributors with the capability of optimizing dosing systems and integrating operational safeguards to assist in the prevention of costly instances of off spec fuel. Is the conductivity reading accurate? Yes! Provided the sensor has been correctly installed it will report results to within +/-2 ps/m. Safety The JF-1A in-line sensor is rated and approved for use in ATEX Zone1 and FM;FMc certified for class 1, Division II environments. Some considerations about in-line conductivity measurements Traditional dip tests - provide at best a random conductivity test result at one location and at one point of time during fuel distribution. Such tests are subject to operator input and the only alternative approved test instrument operates using a dc voltage sensor which has significant limitations. Dc voltage measurement requires the sample to be absolutely still with no movement, is highly dependent on temperature and needs time to stabilise before a reading can be taken. These factors give potential for significant measurement errors, poor precision and repeatability. In addition dc sensors cannot be used for conductivity measurement of in-line flowing fuel so can only provide manually recorded data. Note: Seta-D2 uses Alternating Current (AC) based sensor technology making in-line measurement possible as well as offering other significant user benefits (refer to sales literature).

Dosing ATF by VOLUME - fuel management based on dosing ATF by VOLUME might provide operational compliance but has potential for costly overdosing to occur. This procedure assumes that the correct volume of SDA is added to the given volume of fuel but makes no allowance for the actual conductivity of a particular fuel before it is additised ie: a low conductivity fuel does not require the same volume of SDA as a higher conductivity fuel. Over dosing - in the event that ATF is over dosed the potential cost is very high as the fuel must be clay treated to remove the excess additive and depending on where the fuel is located in the distribution line, there may not be facilities for such treatment, so it is downgraded or returned to the refinery for re-processing. In addition the fuel has already been dosed with unnecessary levels of costly additive. Equally there is potential for under dosing which incurs additional additising costs and delays. Operational Safety - the objective of SDA is to safeguard storage, distribution and loading/unloading facilities from a potential electrical discharge incident. However when fuel is dosed by volume it is possible that this has not safeguarded the entire fuel supply but just that portion of fuel that is directly dosed with a concentration of SDA; for example it has been shown that SDA will not always diffuse out into a standing storage tank. So protection of the entire fuel loading process is best achieved by real time continuous monitoring and additive injection. Additive characteristics - the surface active nature of SDA and its reaction to certain conditions to which it may be exposed during distribution (eg: corroded pipeline surfaces) can create a situation where SDA is initially dosed at the correct level and then drops off significantly downstream. Such instances may be discovered when checking conductivity levels at airport fuel storage depots or at loading/unloading terminals, placing further emphasis on the benefits offered by secure conductivity testing throughout the distribution line. Operational Costs - each off-spec incident has SIGNIFICANT COST IMPLICATION, typically requiring management review while the fuel is held pending a decision about remedial action. Investment in an in-line system will greatly assist to reduce incidents of off-spec conductivity readings taken manually from hand held instruments and provide secure 24/7 data via a local management system. Note: There are reported instances of over dosing which have necessitated the removal of fuel from the distribution line, downgrade of product, transport etc costing suppliers more than US$ 200K. In summary, a fully automated system with continuous conductivity monitoring using Seta-D2 technology connected into the Distribution Control System allows a Supplier to issue Bills of Lading or other Audit Certificates certified to ASTM D2624 with greater robustness and based on in-line conductivity measurements taken for each fuel batch at time of delivery.

What if conductivity readings fluctuate? In some installations it will be found that the conductivity value reported by the sensor is variable or fluctuates. This situation typically indicates the need to investigate local operational factors and to take mitigating steps to provide stable readings for conductivity measurement and additive injection control. Some potential causes for variation in measured conductivity levels. Since the JF-1 measures the actual conductivity of flowing fuel readings will show any fluctuation in conductivity of the fuel as it passes the sensor. Poor mixing Perhaps the greatest potential problem is due to fuel that has not been well blended with conductivity enhancer additives. While additives (such as Stadis 450) tend to mix quite quickly into fuels, there needs to be sufficient residence time and mixing phenomena (elbows, static mixers, valves, etc.) to allow the additive to reach a uniform concentration within the fuel. Since the conductivity enhancer or static dissipation additive (SDA) tends to be highly concentrated (typical dose rate is 1 ppm), fuel that is not uniformly mixed with additive can exhibit considerable variations in conductivity value. Slow Pulse Injection Rates (the Slug Effect ) In a typical high-flow scenario, a 12 diameter pipeline flowing at 5,000 bph (220 lit/sec) gives a line velocity of around 10 ft/sec (~3 m/sec). To control conductivity at around 100 CU (ps/m) using a 1 ppm dose rate means the required injection rate of SDA is 0.22 ml/sec. However most commercial injection systems have a minimum injection rate of several ml which is well above the rate needed above, so at (say) a 4 ml injection pulse, the injection rate will be set at 1 pulse/20 sec (assuming undiluted additive is used). The result being that approximately 19 seconds of untreated fuel would pass the sensor between each slug of highly dosed fuel. Average conductivity levels It might be assumed that over a period of time the average reading would provide a relatively accurate conductivity value but this may not actually be the case. Typically when a 4ml slug of SDA is injected into the flow it will dissipate over some length of pipe. In the 12 diameter example above, the instantaneous volume of fuel being dosed with the slug would be 0.78 cf (22 lit) and if the conductivity value is linearly proportional to SDA concentration then the approximate conductivity of this slug would be 2,000 CU or 20 times the average conductivity requirement. Another and most important consideration is that in short pipe runs the SDA never truly dissipates completely through the fuel and there may be periods of a delivery where fuel is below the minimum specification for conductivity, creating a potential safety hazard. Also if the sensor is set to output conductivity value over a nominal range of 0-500 CU (the typical configuration) the high-conductivity slugs simply appear as over-scale readings and are clipped at the full scale value rather than at the true, much higher conductivity level. Therefore the calculated average can be biased accordingly. Note that the JF-1A sensor features internal averaging over a much broader CU range than the upper limit of the 4-20 ma output (typically 0-1,500 CU) so it is important to average internally to the sensor rather than externally (using the 4-20 ma signal) to minimize this biasing effect.

Sensor Figure 1: The Slug Effect Created by Slow- Pulse SDA Injection So what can be done to improve measurement and control stability? Increased Injection Rate One solution may be to increase the additive injection rate to a uniform dosing level, typically 0.5 to 2 Hz. This can be done by choosing injection pumps with smaller volumes that are designed for continuous injection, or by diluting the SDA so injection of larger volumes may allow more continuous dosing. In the example given above, a pre-injection dilution ratio of 20:1 (fuel:additive) would allow an injection rate of 1 Hz. However, it now becomes extremely important to assure that dilution is consistent, performed properly and that pre-mixed additive/fuel remains stable. So smaller injection volumes and additive dilution are two methods that allow more rapid SDA injection rates and therefore more uniform conductivity values. Sensor Figure 2: More Uniform Conductivity with More Continuous Injection Lower Flows Achieving uniform conductivity levels becomes more difficult to solve as flow rates reduce. In the example given above, the flowrate was a relatively high 5,000 bph. In a typical truck loading terminal flow rates for a 6 inch line may not exceed 500 gpm (31 lit/sec) and may actually be as low as 50 gpm (3.1 lit/sec) during load-start conditions. In this example, the line velocity would range from about 0.6 to 6 ft/sec. Even with a 40:1 dilution ratio, the injection rate for a 4 ml injection pulse would be only 1 pulse/3.2 sec at the high flows, and 1 pulse/30 sec at the low flows. One solution for these lower flows is to increase the dilution ratio to something like 100:1. This will improve the high flow measurement stability, but the slug problem described above will still exist at the lower flows. The best option to handle the low-flow scenario is to have a much smaller injection volume or to provide a blending solution. Average conductivity values If small-volume rapid injection or precision blending is not possible with the injection system selected for a particular application, the other two options for low-flow start-up scenarios would be to set a fixed injection rate and just ignore fluctuations in conductivity reading, or to increase the internal averaging constant in the JF-1A conductivity sensor.

The JF-1A has the ability to output average conductivity value rather than the instantaneous value, this operating mode can be selected using the sensor s RS232 set-up menu. The sensor can average values over its entire measurement range (typically 0-1,500 CU) rather than its 4-20 ma output range (typically 0-500 CU), which helps eliminate bias errors due to clipping when measuring high-conductivity slugs. However care should be taken when adjusting the averaging rate to assure that the averaging period is not so great as to render the sensor slow to respond to true changes in fuel conductivity. Sensor Location and effects of Axial Mixing Continuous injection helps eliminate the time-related aspect of mixing or slug-effect but it is important to ensure that the additive or additive mix is thoroughly blended with the fuel prior to measurement. Where a steady stream of additive is injected near the pipe wall typical laminar flow means that little mixing occurs. In such instances fuel near the pipe wall may have very high conductivity and the conductivity value will decrease moving across the pipe. In reality it has been found that flow tends to be highly turbulent and that the SDA tends to dissipate quickly within the fuel. However it does take some time for this mixing to occur and the elapse time (or distance downstream) for complete mixing to occur will be a function of the Reynolds number and the specific piping configuration. In some cases it may be many pipe diameters downstream before complete mixing occurs. Since the JF-1A Sensor measures the actual conductivity of the fuel passing the sensor tip it will of course record any fluctuations in conductivity resulting from poor mixing, so sensor location is an important factor. Sensor Figure 3: Poor Axial Mixing To assure uniform conductivity measurement, the sensor should therefore be placed well downstream of the additive injection point and if located (say) 100D+ downstream of the injection point, in most cases uniform mixing can be assumed. For automated injection systems it is usually desirable to minimize the lag time between additive injection and conductivity measurement so placing the sensor well downstream of the injection point, where it may take many seconds to see changes in conductivity, is not always desirable. To overcome this, the distance between injection and measurement points can be reduced by the addition of elbows, valves, strainers or in-line static mixers. If a static mixer is chosen, it is important to review the design of the mixer to assure that it mixes effectively across the entire pipe and does not leave unmixed void areas.

Sensor Static Mixer Figure 4: Improved Axial Mixing with In-line Static Mixer Sensor Installation Actual selection of a suitable measurement point may be a process of trial and error. In some systems 10D downstream of the injection point may be sufficient and in others a location as much as 50D may be required. As a general rule, with highly turbulent flow in pipes where there are at least two 90 deg elbows between the injection and measurement points, a separation of 20D is typically sufficient. In each application, regardless of the brand or type of injection system, on-site tuning of the system will allow the sensor to perform properly across all operating ranges. When planning system installation it will be important to take into account the time needed to manage injection systems across the entire operational range so that averaging constants, injection rates, and PID parameters may be selected that cover all possible local operating scenarios. Summary The JF-1A Sensor offers the ability to measure true fuel conductivity in-line, in real time. It is a highly accurate and stable instrument that can be used for quality management, alarm capability and as a feedback sensor for automated SDA injection. It is important to understand that since the JF-1A is a realtime, in-line sensor it will measure the ACTUAL conductivity as the fuel comes in contact with the sensor. If the fuel conductivity is not consistent and uniform the sensor will detect these changes in conductivity and it can therefore also be installed as a very useful failsafe alert. We would be very pleased to offer our advice and experience on optimizing fuel conductivity management.