MATERIAL SAFETY DATA SHEET Product Name CAS # Product use Manufacturer LEGEND HMIS/NFPA Severe Serious 4 3 Moderate 2 Slight 1 Minimal 0 1 Product and Company Identification Marine Gas Oil Mixture Fuel Irving Oil Refining GP Box 1260 Saint John, NB E2L 4H6 CA Phone: (506) 202-2000 Refinery: (506) 202-3000 Emergency Phone: 1-800-424-9300 (CHEMTREC) Health * 1 Flammability 2 Physical Hazard 0 Personal Protection B 2 Hazards Identification 2 1 0 Emergency overview Potential short term health effects Routes of exposure Eyes Skin DANGER COMBUSTIBLE LIQUID AND VAPOR EYE AND SKIN IRRITANT CONTAINS MATERIAL WHICH MAY CAUSE CANCER Contains a potential mutagen Eye, Skin contact, Skin absorption, Inhalation, Ingestion Hydrogen sulphide is very toxic At concentrations as low as 1 to 5 ppm, nausea and severe eye irritation may occur Causes irritation May be absorbed through the skin ACGIH - Threshold Limit Values - Skin Notations Skin - potential significant contribution to overall exposure by the cutaneous route Ultra low sulphur diesel 68476-30-2 Skin - potential significant contribution to overall exposure by the cutaneous route (listed under Diesel fuel) Skin - potential significant contribution to overall exposure by the cutaneous route Inhalation Ingestion Target organs Chronic effects Signs and symptoms Sense of smell may be impaired at concentrations of hydrogen sulphide at approximately 20 ppm, with headache and respiratory tract lung irritation At 250 to 500pm, potentially fatal pulmonary edema may occur Dizziness, sudden (often fatal) collapse, unconsciousness and death occur at higher concentrations Pulmonary edema may be delayed as long as 48 hours after exposure Harmful if swallowed May cause stomach distress, nausea or vomiting Aspiration of material into lungs can cause chemical pneumonitis Ingestion of high levels may produce kidney damage Blood Eyes Kidney Liver Respiratory system Skin Prolonged or repeated exposure can cause drying, defatting and dermatitis Prolonged or repeated exposure can cause kidney damage Symptoms may include redness, edema, drying, defatting and cracking of the skin Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting #19328 Page 1 of 10 Issue date 09-Jul-2009
3 Composition / Information on Ingredients Ingredient(s) CAS # Percent Ultra low sulphur diesel 68476-30-2 7704-34-9 60-100 <1 ppm 116 ppm < 01 < 01 Composition comments *Marine gas oil is a complex mixture of hydrocarbons Its exact composition depends on the source of the crude oil from which it was produced and the refining methods used Marine gas oil contains hundreds of individual organic chemicals This section identifies only some of the well-known chemical constituents First aid procedures Eye contact Skin contact Inhalation Ingestion Notes to physician General advice 4 First Aid Measures Flush with cool water Remove contact lenses, if applicable, and continue flushing Obtain medical attention if irritation persists Flush with cool water Wash with soap and water Obtain medical attention if irritation persists If symptoms develop, move victim to fresh air If symptoms persist, obtain medical attention If breathing has stopped, trained personnel should administer CPR immediately Do not induce vomiting Never give anything by mouth if victim is unconscious, or is convulsing Obtain medical attention Symptoms may be delayed Keep away from sources of ignition No smoking If you feel unwell, seek medical advice (show the label where possible) Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves Show this safety data sheet to the doctor in attendance Avoid contact with eyes and skin Keep out of reach of children 5 Fire Fighting Measures Flammable properties Extinguishing media Suitable extinguishing media Unsuitable extinguishing media Protection of firefighters Specific hazards arising from the chemical Protective equipment for firefighters Hazardous combustion products Explosion data Sensitivity to mechanical impact Sensitivity to static discharge Combustible by WHMIS/OSHA criteria Vapors may travel to a source of ignition and flash back Containers may explode when heated Carbon dioxide Dry chemical Foam Container may explode in heat of fire Vapors are heavier than air and may travel along the ground to some distant source of ignition and flash back Cool containers with flooding quantities of water until well after fire is out Firefighters should wear full protective clothing including self contained breathing apparatus Cool containers with flooding quantities of water until well after fire is out May include and are not limited to: Oxides of carbon Oxides of nitrogen Polycyclic aromatic hydrocarbons (PAHs) Aromatic hydrocarbons Hydrogen sulphide Oxides of sulphur Not expected to be sensitive to mechanical impact Vapor: Yes 6 Accidental Release Measures Personal precautions Keep unnecessary personnel away Do not touch or walk through spilled material Do not touch damaged containers or spilled material unless wearing appropriate protective clothing Keep people away from and upwind of spill/leak #19328 Page 2 of 10 Issue date 09-Jul-2009
Methods for containment Methods for cleaning up Other information Handling Storage Exposure limits Ingredient(s) Ultra low sulphur diesel Stop leak if you can do so without risk Prevent entry into waterways, sewers, basements or confined areas This material is a water pollutant and should be prevented from contaminating soil or from entering sewage and drainage systems and bodies of water Before attempting clean up, refer to hazard data given above Small spills may be absorbed with non-reactive absorbent and placed in suitable, covered, labelled containers Prevent large spills from entering sewers or waterways Contact emergency services and supplier for advice Never return spills in original containers for re-use Keep unnecessary personnel away 7 Handling and Storage Use good industrial hygiene practices in handling this material Non-sparking equipment Explosion-proof ventilation Intrinsically safe electrical equipment Ground and bond containers when transferring material Keep out of reach of children Containers should be vented and equipped with a flame arrester May be stored at ambient temperatures Keep away from heat, open flames or other sources of ignition 8 Exposure Controls / Personal Protection Exposure Limits ACGIH-TLV TWA: 05 ppm STEL: 25 ppm OSHA-PEL TWA: 1 ppm STEL: 5 ppm Ceiling: 25 ppm ACGIH-TLV TWA: 100 mg/m3 OSHA-PEL Not established ACGIH-TLV TWA: 10 ppm STEL: 15 ppm OSHA-PEL Ceiling: 20 ppm ACGIH-TLV TWA: 10 ppm STEL: 15 ppm OSHA-PEL TWA: 10 ppm Engineering controls Personal protective equipment Eye / face protection Hand protection Skin and body protection ACGIH-TLV TWA: 10 mg/m3 OSHA-PEL Not established Mechanical ventilation should be used when handling this product in enclosed s Local exhaust ventilation may be necessary Face shield or chemical goggles Eye wash fountain is recommended Tychem BR/LV or Tychem TK Use of protective coveralls and long sleeves is recommended If clothing or footwear becomes contaminated with the product, remove it immediately and completely decontaminate it before re-use, or discard it #19328 Page 3 of 10 Issue date 09-Jul-2009
Respiratory protection Do not attempt rescue of an hydrogen sulphide knockdown victim without the use of proper respiratory protective equipment For confined s, wear a NIOSH-approved (or equivalent) full-facepiece airline respirator in the positive pressure mode with emergency escape provisions Respirator should be selected by and used under the direction of a trained health and safety professional following requirements found in OSHA's respirator standard (29 CFR 1910134) and ANSI's standard for respiratory protection (Z882) General hygiene considerations Handle in accordance with good industrial hygiene and safety practice When using do not eat or drink Wash hands before breaks and immediately after handling the product 9 Physical and Chemical Properties Appearance Color Form Odor Odor threshold Physical state ph Melting point Freezing point Boiling point Flash point Pour point Clear Clear to Golden Liquid Petroleum Liquid Not applicable 130-400 C (26600-75200 F) (Typically) > 60 C (> 14000 F) Closed Cup -12 - -21 C (1040 - -580 F) Evaporation rate Flammability limits in air, lower, % 06-13 by volume Flammability limits in air, upper, % 6-75 by volume Vapor pressure 21-26 mmhg @ 21 C Vapor density Specific gravity 085 @ 15 C Octanol/water coefficient Solubility (H2O) Auto-ignition temperature 227 C (44060 F) VOC (Weight %) Viscosity 17-36 cps @ 40 C Percent volatile 10 Stability and Reactivity Chemical stability Conditions to avoid Stable under recommended storage conditions Heat, open flames, static discharge, sparks and other ignition sources Do not mix with other chemicals Incompatible materials Acids Oxidizers Hazardous decomposition products May include and are not limited to: Oxides of carbon Oxides of nitrogen Aromatic hydrocarbons Hydrogen sulphide Oxides of sulphur Possibility of hazardous reactions Hazardous polymerization does not occur #19328 Page 4 of 10 Issue date 09-Jul-2009
Component analysis - LC50 Ingredient(s) Ultra low sulphur diesel Component analysis - Oral LD50 Ingredient(s) 11 Toxicological Information LC50 13050 ppm rat; 13700 mg/l/4h rat 46 mg/l/4h rat 1 mg/l/4h rat > 623 mg/l/4h rat LD50 Ultra low sulphur diesel Effects of acute exposure Eye Skin 690 mg/kg rat; 4700 mg/kg mouse 12000 mg/kg rat 490 mg/kg rat; 533 mg/kg mouse; 1200 mg/day guinea pig > 5000 mg/kg human; > 3000 mg/kg rat Hydrogen sulphide is very toxic At concentrations as low as 1 to 5 ppm, nausea and severe eye irritation may occur Causes irritation May be absorbed through the skin ACGIH - Threshold Limit Values - Skin Notations Skin - potential significant contribution to overall exposure by the cutaneous route Ultra low sulphur diesel 68476-30-2 Skin - potential significant contribution to overall exposure by the cutaneous route (listed under Diesel fuel) Skin - potential significant contribution to overall exposure by the cutaneous route Inhalation Ingestion Sensitization Chronic effects Carcinogenicity Sense of smell may be impaired at concentrations of hydrogen sulphide at approximately 20 ppm, with headache and respiratory tract lung irritation At 250 to 500pm, potentially fatal pulmonary edema may occur Dizziness, sudden (often fatal) collapse, unconsciousness and death occur at higher concentrations Pulmonary edema may be delayed as long as 48 hours after exposure Harmful if swallowed May cause stomach distress, nausea or vomiting Aspiration of material into lungs can cause chemical pneumonitis Ingestion of high levels may produce kidney damage Non-hazardous by WHMIS/OSHA criteria Prolonged or repeated exposure can cause kidney damage Contains potential carcinogens, naphthalene and certain polycyclic aromatic hydrocarbons (PAHs) are known carcinogens ACGIH - Threshold Limit Values - Carcinogens A1 - Confirmed Human Carcinogen Ultra low sulphur diesel 68476-30-2 A3 - Confirmed Animal Carcinogen with Unknown Relevance to Humans (listed under Diesel Fuel) A4 - Not Classifiable as a Human Carcinogen IARC - Group 1 (Carcinogenic to Humans) Supplement 7 [1987], Monograph 29 [1982] IARC - Group 2B (Possibly Carcinogenic to Humans) Monograph 82 [2002] NTP (National Toxicology Program) - Report on Carcinogens - Known Human Carcinogens Known Human Carcinogen NTP (National Toxicology Program) - Report on Carcinogens - Reasonably Anticipated to be Human Carcinogens Suspect Carcinogen Reasonably Anticipated To Be A Human Carcinogen US - California - Proposition 65 - Carcinogens List carcinogen, initial date 2/27/87 carcinogen, initial date 4/19/02 Mutagenicity Contains a potential mutagen Reproductive effects Teratogenicity Non-hazardous by WHMIS/OSHA criteria Non-hazardous by WHMIS/OSHA criteria #19328 Page 5 of 10 Issue date 09-Jul-2009
12 Ecological Information Ecotoxicity Components of this product have been identified as having potential environmental concerns Ecotoxicity - Freshwater Algae Data 72 Hr EC50 Selenastrum capricornutum: 29 mg/l 96 Hr EC50 Skeletonema costatum: 04 mg/l Ecotoxicity - Freshwater Fish Species Data 96 Hr LC50 Pimephales promelas: 107-147 mg/l [flow-through]; 96 Hr LC50 Oncorhynchus mykiss:53 mg/l [flow-through]; 96 Hr LC50 Lepomis macrochirus:2249 mg/l [static]; 96 Hr LC50 Poecilia reticulata:286 mg/l [static]; 96 Hr LC50 Pimephales promelas:22330-41160 μg/l [static]; 96 Hr LC50 Lepomis macrochirus:70000-142000 μg/l [static] Ultra low sulphur diesel 68476-30-2 96 Hr LC50 Pimephales promelas: 35 mg/l [flow-through] 96 Hr LC50 Lepomis macrochirus: 00448 mg/l [flow-through]; 96 Hr LC50 Pimephales promelas: 0016 mg/l [flow-through] 96 Hr LC50 Pimephales promelas: 574-644 mg/l [flow-through]; 96 Hr LC50 Oncorhynchus mykiss:16 mg/l [flow-through]; 96 Hr LC50 Oncorhynchus mykiss:091-282 mg/l [static]; 96 Hr LC50 Pimephales promelas:199 mg/l [static]; 96 Hr LC50 Lepomis macrochirus:310265 mg/l [static] 7704-34-9 96 Hr LC50 Brachydanio rerio: 866 mg/l [static]; 96 Hr LC50 Lepomis macrochirus:<14 mg/l [static]; 96 Hr LC50 Oncorhynchus mykiss:>180 mg/l [static] Ecotoxicity - Microtox Data 30 Min EC50 Photobacterium phosphoreum: 093 mg/l; 18 Hr EC50 Pseudomonas putida: >20 mg/l Ecotoxicity - Water Flea Data 48 Hr EC50 water flea: 356 mg/l [Static]; 48 Hr EC50 Daphnia magna: 10 mg/l 96 Hr EC50 Gammarus pseudolimnaeus: 0022 mg/l 48 Hr EC50 water flea: 216 mg/l Environmental effects Aquatic toxicity Persistence / degradability Bioaccumulation / accumulation Partition coefficient Mobility in environmental media Chemical fate information Other adverse effects This product has not been tested 13 Disposal Considerations Waste codes Disposal instructions Waste from residues / unused products Contaminated packaging Review federal, provincial, and local government requirements prior to disposal 14 Transport Information US Department of Transportation (DOT) Basic shipping requirements: Proper shipping name Diesel fuel Hazard class 3 UN number UN1202 Packing group III Additional information: Special provisions 144, B1, IB3, T2, TP1 Packaging exceptions 150 ERG number 128 #19328 Page 6 of 10 Issue date 09-Jul-2009
Transportation of Dangerous Goods (TDG - Canada) Basic shipping requirements: Proper shipping name DIESEL FUEL; FUEL OIL; GAS OIL; or HEATING OIL LIGHT Hazard class 3 UN number UN1202 Packing group III IMDG (Marine Transport) Basic shipping requirements: Proper shipping name Hazard class UN number Packing group GAS OIL or DIESEL FUEL or HEATING OIL, LIGHT 3 UN1202 III 15 Regulatory Information Canadian federal regulations Canada - WHMIS - Ingredient Disclosure List 01 % 1 % 1 % This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations Canada - CEPA - High Priority Chemicals as Identified by DSL Categorization Batch 1, published February 3, 2007 Canada - CEPA - Schedule I - List of Toxic Substances [SOR/2000-109] #19328 Page 7 of 10 Issue date 09-Jul-2009
US Federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 19101200 All components are on the US EPA TSCA Inventory List US - CERCLA/SARA - Hazardous Substances and their Reportable Quantities 10 Lb final RQ (received an adjusted RQ of 10 lbs based on potential carcinogenicity in an August 14, 1989 final rule); 454 kg final RQ (received an adjusted RQ of 10 lbs based on potential carcinogenicity in an August 14, 1989 final rule) 100 Lb final RQ; 454 kg final RQ 100 Lb final RQ; 454 kg final RQ US - CERCLA/SARA - Section 302 Extremely Hazardous Substances EPCRA RQs 100 Lb EPCRA RQ US - CERCLA/SARA - Section 302 Extremely Hazardous Substances TPQs 500 Lb TPQ US - CERCLA/SARA - Section 313 - Emission Reporting 01 % de minimis concentration 01 % de minimis concentration US - CWA (Clean Water Act) - Hazardous Substances US - CWA (Clean Water Act) - Priority Pollutants US - CWA (Clean Water Act) - Toxic Pollutants Occupational Safety and Health Administration (OSHA) 29 CFR 19101200 hazardous Yes chemical CERCLA (Superfund) reportable quantity : 100000 : 1000000 : 1000000 Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Yes Delayed Hazard - Yes Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Section 302 extremely hazardous substance No Section 311 hazardous chemical Yes Clean Air Act (CAA) Clean Water Act (CWA) WHMIS status WHMIS classification WHMIS labeling Controlled Class B - Division 3 - Combustible Liquid, Class D - Division 2A, 2B #19328 Page 8 of 10 Issue date 09-Jul-2009
State regulations WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm US - California - 8 CCR Section 339 - Director's List of Hazardous Substances 7704-34-9 US - Rhode Island - Hazardous Substance List 7704-34-9 7704-34-9 US - California - Proposition 65 - Carcinogens List US - California - Proposition 65 - Developmental Toxicity carcinogen, initial date 2/27/87 carcinogen, initial date 4/19/02 developmental toxicity, initial date 12/26/97 US - California - Proposition 65 - Reproductive Toxicity - Male male reproductive toxicity, initial date 12/26/97 US - Connecticut - Carcinogenic Substances US - Illinois - Toxic Air Contaminant Carcinogens IRIS A Carcinogen; NTP Known Carcinogen; ACGIH A2 Carcinogen; IARC Group 1 Carcinogen US - Illinois - Toxic Air Contaminants US - Louisiana - Reportable Quantity List for Pollutants 10 Lb final RQ (receives an adjustable RQ of 10 lbs based on potential carcinogenicity in August 14, 1989 final rule); 454 kg final RQ (receives an adjustable RQ of 10 lbs based on potential carcinogenicity in August 14, 1989 final rule) 100 Lb final RQ; 454 kg final RQ 100 Lb final RQ; 454 kg final RQ US - Massachusetts - Right To Know List Carcinogen; Extraordinarily hazardous Extraordinarily hazardous 7704-34-9 US - Michigan - Critical Materials List 100 Lb Annual usage threshold US - Minnesota - Hazardous Substance List Carcinogen US - New Jersey - Right to Know Hazardous Substance List sn 0197 sn 1017 sn 1322 7704-34-9 sn 1757 US - New York - Reporting of Releases Part 597 - List of Hazardous Substances US - North Carolina - Control of Toxic Air Pollutants US - Ohio - Extremely Hazardous Substances - Threshold Quantities 10 Lb RQ (air); 1 lb RQ (land/water) 100 Lb RQ (air); 100 lb RQ (land/water) 100 Lb RQ (air); 1lbRQ(land/water) 000012 mg/m3 (carcinogens) 012 mg/m3 (chronic toxicants) 500 Lb TQ US - Pennsylvania - RTK (Right to Know) - Special Hazardous Substances US - Pennsylvania - RTK (Right to Know) List Environmental hazard; Special hazardous substance Environmental hazard Environmental hazard Toxic (skin); Flammable (skin); Carcinogen (skin) Toxic; Flammable Toxic; Flammable Flammable #19328 Page 9 of 10 Issue date 09-Jul-2009
Inventory name Country(s) or region Inventory name On inventory (yes/no)* Canada Domestic Substances List (DSL) Yes Canada Non-Domestic Substances List (NDSL) No United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) Disclaimer Issue date Effective date 16 Other Information Information contained herein was obtained from sources considered technically accurate and reliable While every effort has been made to ensure full disclosure of product hazards, in some cases data is not available and is so stated Since conditions of actual product use are beyond control of the supplier, it is assumed that users of this material have been fully trained according to the requirements of all applicable legislation and regulatory instruments No warranty, expressed or implied, is made and supplier will not be liable for any losses, injuries or consequential damages which may result from the use of or reliance on any information contained in this document 09-Jul-2009 01-Jul-2009 Expiry date 01-Jul-2012 Prepared by Dell Tech Laboratories Ltd (519) 858-5021 #19328 Page 10 of 10 Issue date 09-Jul-2009