Detailed Mid-FTIR Analysis Of Gasoline, Diesel & Jet Fuel With A Single Portable Analyzer In Seconds

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Detailed Mid-FTIR Analysis Of Gasoline, Diesel & Jet Fuel With A Single Portable Analyzer In Seconds Philipp Jordan eralytics TM GmbH www.eralytics.com

Welcome to a new era of petroleum testing PERFORMANCE YOU CAN RELY ON eralytics TM GmbH www.eralytics.com

Profile Development Production Sales After-Sales Service of innovative, reliable and easy to operate petroleum testing equipment.

Experience you can rely on Eralytics founded in May 2007 by 4 industry insiders Several hundred installations in > 50 countries World-wide sales & service network North America: COMPASS INSTRUMENS

Mission Add value for our customers by enhancing their ability to perform reliable measurements with highest precision maximum speed easiest operation

Quality you can rely on eralytics is ISO 9001:2008 certified since Jan 2008 ISO 9001:2008 certificate from DET NORSKE VERITAS

Product range ERAVAP - vapor pressure tester of gasoline, crude oil & LPG ERASPEC - mid-ftir fuel analyzer for gasoline, diesel, FAME & jet fuel ERACHECK - hydrocarbons in water tester

Tomorrow Papers ERAVAP - vapor pressure tester of gasoline, crude oil & LPG Vapor Pressure Measurement Of Gasoline, Crude Oil & LPG With New ASTM D5191 & D5188 Speed Test Fuel Ratings Symposium / Vine I & II at 10:30 ERACHECK - hydrocarbons in water tester Oil/Grease In (Sea) Water Portable & CFC-Free A New Mid-IR Laser Based Analyzer for Total Petroleum Hydrocarbons in Water Gulf Oil Spill Symposium / Bluebonnet at 10:00

Welcome to a new era of petroleum testing ERASPEC Detailed Mid-FTIR Analysis Of Gasoline, Diesel & Jet Fuel With A Single Portable Analyzer In Seconds eralytics TM GmbH www.eralytics.com

IR Spectrometry Lens (Mirror) Lens (Mirror) IR- Source Dispersive Element Sample Cell IR- Detector

IR Spectrometry Dispersive Element: Separation of different wavelengths of the IR-radiation => Measurement of intensity as a function of wavelength: SPECTRUM In ERASPEC: FTIR Interferometer (FT = Fourier Transformation)

IR Spectrometry Spectrum of gasoline Ig(v); ν = 1/λ 560 Intensity (arb. units) 510 460 410 360 630.0 830.0 1030.0 1230.0 1430.0 1630.0 1830.0 2030.0 Wavenumber (cm-1)

IR Spectrometry Spectra of gasoline, reference: Ig(v), Ir(v) 560 Intensity (arb. units) 510 460 410 360 630.0 830.0 1030.0 1230.0 1430.0 1630.0 1830.0 2030.0 Wavenumber (cm-1)

IR Spectrometry Transmission spectrum T(v)= 100*Ig/Ir 105 100 95 Transmission (%) 90 85 80 75 70 65 630.0 830.0 1030.0 1230.0 1430.0 1630.0 1830.0 2030.0 Wavenumber (cm-1)

IR Spectrometry Absorbance spectrum A(v)= log(ir/ig) 0.35 Absorbance (absorbance units) 0.3 0.25 0.2 0.15 0.1 0.05 0 630.0 830.0 1030.0 1230.0 1430.0 1630.0 1830.0 2030.0 Wavenumber (cm-1)

IR Spectrometry Absorbance spectrum: Absorbance is directly proportional to the concentration of the substance that causes the absorption line 0.2 Absorbance (absorbance units) 0.15 0.1 0.05 0 630.0 730.0 830.0 930.0 1030.0 1130.0 1230.0 Wavenumber (cm-1)

IR Spectrometry Compositional analysis Pure chemicals are measured by analyzing IR peaks associated with each substance The height of or area under a peak is proportional to the concentration of the respective substance

IR Spectrometry Benzene, Ethanol Absorbance (a.u.) 0.1 0.08 0.06 0.04 0.02 0 630 730 830 930 1030 1130 1230 1330 Wavenumber (cm-1)

0.06 0.05 0.04 0.03 0.02 0.01 0 IR Spectrometry Mixture of Benzene and Ethanol Absorbance (a.u.) 630 730 830 930 1030 1130 1230 1330 Wavenumber (cm-1)

ERASPEC Excellent precision for gasoline composition Total Oxygen, Oxygenates, Aromatics, Olefins, Saturates, Di-Olefins 16 Aromatics incl. Benzene (ASTM D 6277, EN 238), Toluene, o-, p- & m- Xylene, Ethylbenzene, etc.

ERASPEC Excellent precision for gasoline composition 9 Oxygenates (ASTM D 5845) Alcohols (Methanol, Ethanol, Iso- Propanol, etc.) Ethers (MTBE, ETBE, TAME, DIPE) N-Methylanilin, MMT, CMT

ERASPEC Excellent precision for Diesel composition Total Aromatics PNA FAME (Biodiesel) (EN 14078) Cetane Improver (2-EHN)

ERASPEC ES01-JET for Jet fuel parameters in 1 minute

ERASPEC Excellent precision for important fuel properties RON, MON & AKI Cetane Number Cetane Index Distillation points (IBP, T10, T50, T90, T95, FBP) Evaporation points (E70, E100, E150, E250, E350) RVP 10 freely programmable parameters

ERASPEC ES01-JET for Jet fuel parameters in 1 minute

ERASPEC Excellent precision for important fuel properties Density: direct measurement with built-in Anton Paar density meter Accuracy: 0.0005 g/cm 3

ERASPEC Measuring principle to determine fuel properties Calculation methods: Cluster Analysis Maximum Accuracy Calibration data base with similar samples required Multi Linear Regression (MLR) Method if Cluster Analysis is not applicable The applied calculation method is shown with the result

ERASPEC Calculation of fuel properties (RON, MON, Cetane number & Index, Distillation etc): Data base (library) containing fuels with known properties, easy to upgrade Factory calibration data base of a matrix of several hundred international fuels Spectral regions that correlate with fuel properties

ERASPEC performance you can rely on Latest technology for reliable operation: Industrial PC Linux system Universal input power supply (85-264V) => No influence of voltage fluctuations

ERASPEC Multiple connections for easy data management USB, Ethernet and RS232 connection for printer, computer, barcode reader, mouse, keyboard, LAN, and LIMS

ERASPEC Latest Technology High-Speed Testing Warm-up time: 30 seconds Measuring time: 60 seconds No sample preparation, automatic sample introduction, automatic cleaning!

ERASPEC Easiest Operation Fully automated measurement Detailed results in only 1 minute Results can be analyzed, printed, saved to USB-stick, transferred to LIMS

ERASPEC Analysis of Fuel Spectra Fuel Spectra as Grafic Chart on Display View Spectra Compare Spectra Analyze Spectra No PC needed! No external software!

ERASPEC Portable & Rugged Small footprint Light weight (7 kg) Metal Housing The perfect solution for mobile testing!

ERASPEC Latest Technology Auto Sampler 10 positions Directly attached Tubes or syringes ERASPEC remains fully portable!

ERASPEC ERASOFT RCS PC software - Remote control (several analyzers) - Data transfer - Result view, print, storage

ERASPEC Free Software upgrade: simply with USB stick or Erasoft RCS

ERASPEC Applications Production / blending control in refineries Product monitoring at pipeline terminals Blending of bio fuels Product specification testing in fuel distribution like storage tanks, trucks, ships, etc. Quality control of Jet fuel at airports

ERASPEC Applications Mobile testing to fight fuel adulteration, smuggling and dilution R&D at car manufacturers Universities Product specification control in motor racing Several hundred international installations: EPA, Shell, Sinopec, Petrochina, Intertek, OMV, SGS, Teppco, NIOC, OilLybia, MOL, Caltex,.

Welcome to a new era of petroleum testing THANK YOU FOR YOUR ATTENTION! eralytics TM GmbH www.eralytics.com Performance you can rely on.