HEAT EXCHANGER OVERVIEW

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ABSTRACT I. INTRODUCTION III. GEOMETRIC MODELING II. LITERATURE REVIW

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HEAT EXCHANGERS 1

PURPOSE A heat exchanger is an apparatus performing heat exchange between two or several fluids. It can carry out this task by: Segregating the fluids and making them exchange heat through a wall Mixing them finely. This is direct heat exchange as in cooling towers Using principally radiations as heating medium (furnaces) Using an intermediary fluid Heat exchangers are everywhere in our industry: Shell and tube heat exhangers to heat up or cool down a feed or a product Fired heaters Air coolers Cooling towers Rotating machines anciliaries include heat exchangers to cool down lubrication oil Pipe tracing Even insulated pipes may be considered as heat exchangers (except one wants to limit heat transfer) JUST BECAUSE PROCESS CONSIST IN EXCHANGING MASS AND ENERGY 2

HEAT EXCHANGER OVERVIEW Heat exchangers can be sorted in four big families: Shell and Tube type more than 90% of all the application Air coolers Fired heaters Special heat exchangers such as: Plate and frame heat exchangers Brazed or welded plate fin heat exchangers Coil wound heat exchanger 3

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COIL WOUND HEAT EXCHANGER 5

CONVENTIONS IN HEAT TRANSFER Upper case terms refer generally to the hot side (the side which cools down) Lower case terms refer generally to the cold side (the side which heats up) Cold stream is generally colored in blue Hot stream is generally colored in red C or c is the thermal capacity (kj/kg or kcal/kg) M or m the mass flow rate (kg/h) A the heat exchange area (m²) U the overall transfer coefficient (W/m². C or kcal/h.m². C) U can be clean or dirty F is the correction factor taking into account the HX technology 6

PHYSICS Heat transfer depends on: The thermal gradient T-t The transfer coefficients hot fluid side and cold fluid side (film coefficients) The wall material conductivity Film coefficients are themselves dependant on: Fluid turbulence (Reynolds number) Thermal physical properties (Prandtl number) 7

PHYSICS 8

PHYSICS In case of cylindrical wall 9

ANALYSIS OF FACTORS INFLUENCING HEAT TRANSFER COEFFICIENTS e/λwall is very small h coeff depends on Physical properties of fluid Flow turbulence Physical phenomena along with the heat transfer (change of state) 10

GENERAL LAW For a counter-current or co-current heat exchange: Q = U A LMTD where Q is the total exchanged heat U is the transfer coefficient A is the heat transfer area LMTD is the Logarithmic Mean Temperature Difference For other types (1-n, cross flow), the formula becomes: Q = F U A LMTD CC 11

Q TOTAL EXCHANGED HEAT Q is the enthalpy difference between outlet and inlet for each side multiplied by the mass flow rate Q is the same for cold side and hot side (basically one does not take into account the heat losses, which are negligible) In case of only sensible heat exchange Q=MC T or Q=mc t In case of latent heat exchange Q=m Hvap or cond Beware in case of a mixture phase change relations are more complex and thermodynamic simulator must be used 12

LMTD Co-current Flow Countercurrent Flow Temperature T Temperature T T H1 LTTD T H1 T H2 T C2 T H2 LTTD T C2 GTTD T C1 T C1 Heat Transferred Q Heat Transferred Q LMTD = ( GTTD) ( LTTD) GTTD Ln LTTD 13

LMTD For non linear curves (condensation, vaporisation), calculating the LMTD with four points may cause a severe error In this case, one should calculate the LMTD with several points For a pure body in phase change 2 points are sufficient For a mixture in phase change more points are needed LMTD = [ Q ( ) ] n LMTD n n Q Total 14

LMTD Beware taking LMTD with four points may lead to consequent errors: Example: Considering a countercurrent natural gas / cooling water cooler and condenser with the following operating conditions: Q T T Total C1 H1 = 2660 = 28 C = 80 C kw T T C 2 H 2 = 38 C = 40 C As the natural gas is condensing in the heat exchanger, the temperature versus duty curve is not linear as shown below: 15

LMTD Temperature = f(heat Transferred) 90 80 T H1 70 Temperature in C 60 50 T H2 40 30 T C1 20 T C2 Cooling Water Condensing Natural Gas Linear behaviour 10 Q 1 Q 2 Q 3 Q 4 0 0 500 1000 1500 2000 2500 3000 Heat Transferred in kw Calculation Method LMTD in C Absolute Error in C Relative Error in % End points calculation (Linear behaviour) 23.8 0 0 Weighed calculation with n = 4 26.0 2.2 9.2 Weighed calculation with n = 14 26.2 2.4 10.1 16

LMTD Note that Process Simulators (Hysys, Pro II) do calculate an integrated LMTD point by point 17

F FACTOR F factor depends on the technology of heat exchanger used F=1 for pure counter-current or pure co-current heat exchangers For other types F is function of: The thermal efficiency e or E = heat exchanged / heat exchanged if the heat transfer area was infinite The thermal capacity ratio r or R = mc/mc 18

1-2n HEAT EXCHANGER 19

DIVIDED FLOW HX 20

DIVIDED FLOW HX 21

SPLIT FLOW HX 22

SPLIT FLOW HX 23

DOUBLE SPLIT FLOW HX 24

CROSS FLOW HX 25

U COEFFICIENT Perry chemical handbook 26

U COEFFICIENT 27

FOULING One has previously seen that U, the overall transfer coeff. is U = 1/R R as written beside does not take into account any dirt that could accumulate on the wall (on both sides) and which could modify the transfer coefficient This R leads to the U clean Fouling is the results of different phenomenon such as precipitation, sedimentation, chemical reactions, corrosion or biological growth. Fouling is complex, dynamic, and in times degrades the performance of the heat exchanger. Consequently, fouling resistances shall be determined depending on the fluid and then specified in the process datasheet to provide overdesign. Indeed, the heat exchanger is generally oversized for clean operation and barely adequate for conditions just before it should be cleaned. 28

FOULING Fouling coefficients must then be added to the overall resistance Typical values are: PROCESS FLUIDS Heavy oil Oil Heavy Gas Oil Light Gas Oil Gasoline LPG (liquid) Natural gas Regeneration gas (dryers) Amine solution Glycol Refrigerant (propane or mixed refrigerant) Oily water UTILITY FLUIDS Sea cooling water River cooling water Fresh (desalinated) cooling water in closed loop Well water Atmospheric air Fuel gas Hot oil Super heated steam Saturated steam / steam condensate Boiler feed water Instrument air, Nitrogen m 2 C / W 0.00050 0.00040 0.00035 0.00030 0.00020 0.00020 0.00015 0.00017 0.00040 0.00040 0.00010 0.00030 m 2 C / W 0.00030 0.00040 0.00020 0.00040 0.00035 0.00017 0.00020 0.00010 0.00017 0.00017 0.00017 Fouling factors Fouling factors h ft 2 / Btu 0.0028 0.0023 0.0020 0.0017 0.0011 0.0011 0.0009 0.0010 0.0023 0.0023 0.0006 0.0017 h ft 2 / Btu 0.0017 0.0023 0.0011 0.0023 0.0020 0.0010 0.0009 0.0006 0.0010 0.0010 0.0010 29

FOULING One should add to the clean heat transfer resistance the following term: Where Rs is the fouling resistance Rsi the tube internal fouling resistance Rse the tube external resistance Ratio de/di (external tube diameter / internal tube diameter) to refer to the external surface 30

HEAT TRANSFER COEFFICIENT To calculate U, one needs to evaluate h tube side and shell side h coefficients are very complex to calculate, especially for the shell side, it depends on: The physical properties of the fluid The flow regime (turbulence) Physical phenomena simultaneous to heat transfer Heat leaks (for the shell side) For the tube side in turbulent flow (Re>10000) and sensible heat exchange: Pr = Cµ/λ 31

HEAT TRANSFER COEFFICIENT SHELL SIDE Transfert coefficient for a monophasic stream flowing transversaly a bundle of tubes is: Nu = a Re 1/3 Pr -1/3 (µ/µ p ) 0.14 Nu gives h e Heat transfer coefficient for shell side is: h c =h e.k CH.k BP.k Re (method Bell) 32

HEAT TRANSFER COEFFICIENT SHELL SIDE Current A is partly useful but less efficient than current A Current B is useful Current C is completely useless Current E is completely useless Current F is completely useless but present only on types E, J, K and X To reduce current A: reduce baffle tube clearance To reduce current C: implement sealing strips To reduce current E: reduce baffle shell clearance To reduce current F only ways are to change shell type (F, G, H) 33

HEAT TRANSFER AREA A is the total heat transfer area A = π d e L (external diameter since U is expressed with regards to external surface) if the tubes are bare One can increase the surface with special tube design (more expensive) Low fin tubes (area increase factor up to 10) One can create nucleation sites to maximise ebullition heat transfer coefficient (Wielland tubes) 34

35

36

SHELL AND TUBE TECHNOLOGY Shell and tube HX is the labour horse of chemical engineering Very robust Common rudimentary design Can be applied for all services Can be cleaned (if designed so as to) There is a lot of manufacturers Completely defined by the TEMA code 37

TEMA HEAT EXCHANGER TEMA (Tubular Exchanger Manufacturer Association) defines shell and tube heat exchanger by a code of three letters (e.g. BEU) First letter is for the front end type Second letter is for the shell type Third letter is for the rear end type 38

39

40

TEMA SHELL AND TUBES 41

TEMA SHELL AND TUBES 42

TEMA SHELL AND TUBES 43

TEMA SHELL AND TUBES 44

TEMA SHELL AND TUBES 45

TEMA SHELL AND TUBES 46

TEMA TYPE CHOICE ADVANTAGES: Easy demantling allows cleaning and inspection without unfastening the tube nozzles DRAWBACKS: Two gaskets are required to ensure tightness Poor resistance to pressure Cost factor higher than B type 47

TEMA TYPE CHOICE ADVANTAGES: Easy demantling allows cleaning and inspection without unfastening the tube nozzles DRAWBACKS: Two gaskets are required to ensure tightness Poor resistance to pressure Cost factor higher than B type APPLICATION: Dirty services with low pressure 48

ADVANTAGES: Cheap Resistance to high pressure due to elliptical design Only one gasket is needed TEMA TYPE CHOICE DRAWBACKS: Access to tube can only be given after complete nozzle dismantling APPLICATION: Clean products, which do not need frequent cleaning Commonly used with U tubes type 49

TEMA TYPE CHOICE ADVANTAGES: No more gasket between the tube sheet and the distribution box DRAWBACKS: Less pressure resistant than bonnet type APPLICATION: Not really used in oil and gas industry 50

TEMA TYPE CHOICE Channel has been made by solid forged work or have been completely welded Can be used as rear end ADVANTAGES: For special closing system Sustains very high pressure DRAWBACKS: Expensive 51

TEMA TYPE CHOICE ADVANTAGES: Cheap DRAWBACKS: Bad distribution Nozzle diameter may be increased Vapour bell may be reuired in case of very high vapour flow rate 52

TEMA TYPE CHOICE ADVANTAGES: No longer F current DRAWBACKS: Limited to low pressure drops Leak do exist between the Longitudinal baffle and the shell 53

TEMA TYPE CHOICE ADVANTAGES: Low shell pressure drop as no baffle Efficiency higher than for 1-n apparatus DRAWBACKS: Tube length limit due to lack of support (in transversal baffle design, baffles support tubes) Hard to avoid poor distribution 54

TEMA TYPE CHOICE ADVANTAGES: Low pressure drop DRAWBACKS: Piping more complex APPLICATION: Used when considerable actual flow change occurs 55

TEMA TYPE CHOICE ADVANTAGES: Provide a liquid vapor equilibrium High vaporization rate (30 to 40%) DRAWBACKS: Bulky and costly APPLICATION: Column reboiler 56

TEMA TYPE CHOICE ADVANTAGES: Low pressure drop and provides good tube support, which avoids vibrations Efficiency close to that of the counter current DRAWBACKS: Costly distribution device 57

TEMA TYPE CHOICE ADVANTAGES: Good use of the volume in the shell They allow use of double tube sheet They ease the cleaning as far as L and N types are concerned for the front end Less expensive than floating head DRAWBACKS: Can not be used if big temperature difference during the life of the HX Bundle can not be dismantled Shell can not be accessed 58

TEMA TYPE CHOICE ADVANTAGES: Differential expansion are not a problem DRAWBACKS: Bad tightness = safety problem 59

TEMA TYPE CHOICE ADVANTAGES: Sustain big differential expansion Bundle can be dismantled DRAWBACKS: If one pass tube, packing is needed implying risk of leakage It is expensive Leakage is not visble Bundle not really easy to dismantle 60

TEMA TYPE CHOICE ADVANTAGES: With regards to S type, bundle removal is easier DRAWBACKS: Not os many tubes than for tube S 61

TEMA TYPE CHOICE ADVANTAGES: Low price Easy dismantling No gasket Allows high temperature difference DRAWBACKS: Reserved to rather clean products High speed in the coils may produce erosion 62

63

TEMA TYPE CHOICE ADVANTAGES: Leak can be detected DRAWBACKS: Tightness is not perfect 64

PITCH Triangular pitch: More tubes per section Outside wall is hard to clean Square pitch Easily cleanable 65

WHICH FLUID FOR WHICH SIDE Rule of the thumb for the selection: Dirtier fluid rather in tube side If dirty fluid in the shell side, foresee square pitched As much as possible balance the heat transfer coefficient between shell side and tube side Viscous liquid should be placed shell side High pressure fluid should be placed tube side Erosive product should be placed tube side 66

BUNDLE CLEANING 67

COMPACT HEAT EXCHANGER More exchange area per cubic meter. They are: Plate fin heat exchanger Core in kettle Coil wound heat exchanger Plate and frame heat exchanger Spiral heat exchanger 68

PLATE FIN HEAT EXCHANGER Aluminium brazed Reserved for very clean services (not dismantable) 69

70

CORE IN KETTLE 71

COIL WOUND HEAT EXCHANGER 72

PLATE AND FRAME HEAT EXCHANGER Commonly used for CW / SW heat exchanger Cleanable Beware of the shear stress: put off line one cell rather reducing flow rate in each cell 73

PLATE AND FRAME HEAT EXCHANGER 74

PLATE AND FRAME HEAT EXCHANGER 75

PLATE AND FRAME HEAT EXCHANGER 76

PLATE AND FRAME HEAT EXCHANGER 77

WELDED PLATE HEAT EXCHANGER Cross flow (Alfarex or Compabloc) 78

TEMPERATURE AND PRESSURE LIMITATION 79

SPIRAL PLATE HEAT EXCHANGER 80

AIR COOLERS Q = U A LMTD, F close to 1 Can be induced draft or forced draft Induced Less recirculation Bundle protection Good natural convection Forced Easy access for maintenance Lower power consumption No outlet temperature limitation 81

AIR COOLERS 82

AIR COOLERS 83

AIR COOLERS 84

AIR COOLERS 85

86

87

AIR COOLERS 88

AIR COOLERS 89

COOLING TOWER The competitor of SW/CW P&F HX and Air cooler Used to cool down a semi-opened cooling water loop Efficiently used when big difference between dry bulb temperature and wet bulb temperature (not close to the sea) Operate with mass transfer and heat transfer together This imply: Losses of water to compensate constantly Pollution of the cooling water by air dust Saturation of the cooling water in gas (corrosion issues) 90

COOLING TOWER 91

COOLING TOWER 92