1 of Restricted s List (RSL) for Consumer Goods A Hazardous s 1. Azo Dyes / Cleavable Arylamines 3. Disperse Dyestuffs, Allergenic Limit, EU: 30 mg/kg Limit, DE: 5 mg/l (75 mg/kg) Test Method: Leather: 64 LFGB B 82.02-3 (DIN EN ISO 17234-1); Natural fibers Test Method: DIN 54231 and man made fibers and blends: DIN EN 14362-1; 4-Aminoazobenzene: Leather: DIN EN ISO 17234-2 and Textiles : DIN EN 14362-3 DE Requirement: ProdSG, LFGB 30; Recommendation of BfR No 018/2007 (Federal Institute for Risk Assessment) EU Requirement: Regulation (EC) No 1907/2006 Annex XVII valid for textiles and CAS No. leather with skin contact and toys DE Requirement: Recommendation of BfR XXXVI No 11 (Federal Institute for Risk Assessment): No use for paper with food contact Disperse Blue 1 Disperse Blue 106 Disperse Blue 124 2475-45-8 12223-01-7 61951-51-7 CAS No. Disperse Blue 35 12222-75-2 2,4,5-Trimethylaniline 7-17-7 Disperse Orange 3 730-40-5 2,4-Diaminoanisole 615-05-4 Disperse Orange 37 / 76 301-61-6 2,4-Toluylenediamine 95-80-7 Disperse Red 1 2872-52-8 2-Amino-4-nitrotoluene 99-55-8 Disperse Yellow 3 2832-40-8 2-Naphthylamine 91-59-8 3,3' -Dichlorobenzidine 91-94-1 4. Chromium VI 3,3' -Dimethoxybenzidine 119-90-4 3,3'-Dimethyl-4,4'-diaminodiphenylmethane 838-88-0 Limit, EU: 3 mg/kg 4,4'-Diaminodiphenylmethane 101-77-9 3,3' -Dimethylbenzidine 119-93-7 Test Method: DIN EN ISO 17075; 64 LFGB B 82.02-11 4,4'-Methylene-bis-(2-chloroaniline) 101-14-4 14 4 EU Requirement: Directive 2001/95/EC 4,4'-Oxydianiline 101-80-4 DE Requirement: BedGgstV, valid for leather articles with skin contact 4,4'-Thiodianiline 9-65-1 4-Aminodiphenyl 92-67-1 Chromium VI 4-Chlor-o-toluidine 95-69-2 o-aminoazotoluene 97-56-3 5. Nickel Release from metal parts o-anisidine 90-04-0 o-toluidine 95-53-4 p-chloroaniline 106-47-8 p-cresidine 120-71-8 Benzidine 92-87-5 4-Aminoazobenzene 60-09-3 2. Navy Blue / Blue Colourant Limit, EU: not detectable CAS No. Test Method: Determination of chromium VI: Textiles: ISO 11083 / DIN EN ISO 105-E04; Leather: DIN EN ISO 17075 EU Requirement: Regulation (EC) 1907/2006 Annex XVII DE Requirement: ChemVerbotsV; valid for textile and leather articles; Navy Blue is a mixture of: Di- and Trinatrium-(6-(4-anisidino)-3-sulfonato-2-(3,5-dinitro-2- oxido-phenylazo)-1-naphtholato)(1-(5-chlor-2-oxido-phenylazo)-2- naphtholato)chromate Navy Blue Colour Index-No: 611-070-00-2 Limit, EU (skin contact): 0,5 µg/cm²/week Limit, EU (piercing): 0,2 µg/cm²/week Test Method: DIN EN 1811 EU Requirement: Regulation (EC) No 1907/2006 Annex XVII, Limit (direct skin contact): 0,5 µg/cm²/week; Limit (jewellery parts that are inserted into punctured parts of the body): 0,2 µg/cm²/week; DIN EN 14372: limit for baby crockery and cutlery: 0,5 µg/cm²/week Nickel 7440-02-0 Area of application/ Group: Alba Moda, Baur, baumarkt direkt, bonprix, Frankonia, Heine, Media, mytoys.de, OTTO, OTTO Office, Schwab, SportScheck, Witt-Gruppe Area of application/ Countries: EU-Member states, CH, NO Area of application/ Process: Product definition (Pre-)testing Inspection Previous Document Version 12 Created by: A.Jureviciute Checked by: S.Warnecke Released by: A.Stoll Created on: 28-01-20 Check Date: 15-02-20 Release Date: 08-03-20
2 of Restricted s List (RSL) for Consumer Goods 6. Heavy Metals, Total Content 8. Heavy Metals in Electronic Devices (RoHS) 6.1 Cadmium Limit, EU (electronic devices): see below Limit, EU: 100 mg/kg, see below Test Method: DIN EN ISO 17294-2 / EPA 1620 / DIN EN 1122 Test Method: DIN EN ISO 17294-2 / EPA 1620 / DIN EN 1122 / DIN EN ISO 17075 EU Requirement (Cadmium): Regulation (EC) No 1907/2006 Annex XVII no use RoHS Requirement: 2011/65/EC: Restriction of the use of certain of cadmium in wood preservatives; limit for cadmium in paints and varnishes: hazardous substances in electrical and electronic equipment (RoHS) 0,1%; limit for cadmium in plastics (all commodities) and metal components / CAS No. Limit (jewellery): 100 mg/kg Lead /7439-92-1 0,1% CAS No. 0,01% Cadmium 7440-43-9 Chromium VI 0,1% 0,1% 6.2 Lead New-L 9. Heavy Metals in Packaging Limit, EU: 500 mg/kg, see below 9.1 Sum (Lead, Cadmium, Chromium VI, Mercury) Limit, DK: 100 mg/kg EU Requirement (Lead): Regulation (EC) No 1907/2006 Annex XVII no use of lead carbonates and sulfates; no use of lead in wood preservatives; limit valid Limit, EU: 100 mg/kg per sum Test Method: DIN EN ISO 17294-2 / EPA 1620 / DIN EN 1122 / DIN EN from 9 october 20 for metal components in jewellery articles: 0,05% ISO 17075 DK Requirement (Lead): Statutory Order No. 1082 of September 2007 valid EU Requirement: Directive 94/62/EC for ; limit for lead in plastics: 100 mg/kg CAS No. Lead 7439-92-1 Lead 7439-92-1 Cadmium 7440-43-9 Chromium VI 6.3 Mercury Mercury 7439-97-6 Limit, EU: no use 9.2 Cobalt Dichloride in Silica EU Requirement (Mercury): Regulation (EC) 1907/2006 Annex XVII no use of mercury in wood preservatives, no use of mercury in measuring instruments like Limit, OTTO Group: not detectable Limit, EU: thermometers or barometers; further limits in batteries acc. to Directive Test Method: X-ray fluorescence analysis (RFA) 2006/66/EC EU Requirement: Directive 2001/95/EC Mercury 7439-97-6 Cobalt dichloride 7646-79-9 CAS No. CAS No. CAS No. 10. Heavy Metals, Extractable in Perspiration 6.4 Arsenic 10.1 Heavy Metals, Extractable in Perspiration: Adults Limit, EU: no limit Limit, EU: no use in wood preservatives Limit, SK (articles with skin contact): see below EU Requirement (Arsenic): Regulation (EC) 1907/2006 Annex XVII; no use in Test Method (all metals): DIN EN ISO 17294-2 / DIN EN ISO 105-E04 wood preservatives Test Method (Chromium VI) : ISO 11083 / DIN EN ISO 105-E04 DE Requirements: ChemVerbotsV SK Requirement: Decree 635/2005; limits, see below CAS No. / CAS No. Limit in textiles Arsenic 7440-38-2 Antimony / 7440-36-0 Arsenic / 7440-38-2 30 mg/kg 1 mg/kg 7. Heavy Metals in Batteries Lead / 7439-92-1 1 mg/kg Limit, EU: ban or mandatory labelling, see below 0,1 mg/kg Chromium / 7440-47-3 2 mg/kg Test Method: DIN EN ISO 17294-2 / EPA 1620 / DIN EN 1122 EU Requirement: 2006/66/EC, ban or mandatory labelling Chromium VI Cobalt / 7440-50-8 0,5 mg/kg 4 mg/kg / CAS No. Limit Copper / 7440-50-8 50 mg/kg Lead / 7439-92-1 0,004% Nickel / 7440-02-0 4 mg/kg 0,002% 0,02 mg/kg 0,0005%; button cells: 2% / CAS No. Limit in leather Arsenic / 7440-38-2 Lead / 7439-92-1 0,2 mg/kg 0,1 mg/kg 0,8 mg/kg 0,02 mg/kg
3 of Restricted s List (RSL) for Consumer Goods 10.2 Heavy Metals, Extractable in Perspiration: Baby Copper / 7440-50-8 622,5 mg/kg Limit, EU: no limit Lead / 7439-92-1,5 mg/kg Limit, CZ, SK: see below Test Method: DIN EN ISO 17294-2 / DIN EN ISO 105-E04 Test Method (Chromium VI) : ISO 11083 / DIN EN ISO 105-E04 CZ Requirement: Act No 84/2001: limits in A are valid for toys and baby products for the materials textile, leather and synthetics. Mark *: limits are not valid for leather in Czech Republic SK Requirement: Decree 635/2005: limits in A are valid for toys and baby products for textiles with skin contact, limits in B are valid for leather with skin Manganese / 7439-95-47 Nickel / 7440-02-0 Selenium / 7782-49-2 Strontium / 7440-24-6 Tin / 7440-31-5 Organic tin Zinc / 7440-66-6 1 200 mg/kg 7,5 mg/kg 75 mg/kg 37,5 mg/kg 4 500 mg/kg 15 000 mg/kg 0,9 mg/kg 3 750 mg/kg contact Limit: in liquid or sticky toy material valid from July 20 / CAS No. Antimony / 7440-36-0 30 mg/kg Aluminium / 7429-90-5 1 406 mg/kg Arsenic / 7440-38-2 0,2 mg/kg Antimony / 7440-36-0 11,3 mg/kg Lead / 7439-92-1 0,2 mg/kg Arsenic / 7440-38-2 0,9 mg/kg 0,1 mg/kg Barium / 7440-39-3 1 125 mg/kg Chromium / 7440-47-3 1 mg/kg * Boron / 7440-42-8 300 mg/kg Chromium VI 0,5 mg/kg * 0,3 mg/kg Cobalt / 7440-50-8 1 mg/kg Chromium (III) 9,4 mg/kg Copper / 7440-50-8 25 mg/kg Chromium (VI) 0,005 mg/kg Nickel / 7440-02-0 1 mg/kg Cobalt / 7440-48-4 2,6 mg/kg 0,02 mg/kg Copper / 7440-50-8 156 mg/kg / CAS No. Limit B Lead / 7439-92-1 3,4 mg/kg Arsenic / 7440-38-2 0,2 mg/kg Manganese / 7439-95-47 300 mg/kg Lead / 7439-92-192 0,1 mg/kg 97 1,9 mg/kg 0,8 mg/kg Nickel / 7440-02-0 18,8 mg/kg 0,02 mg/kg Selenium / 7782-49-2 9,4 mg/kg Strontium / 7440-24-6 1 125 mg/kg 11. Heavy Metals, Extractable in Hydrochloric Acid New-P Tin / 7440-31-5 3 750 mg/kg Limit, EU (toys): see below Organic tin 0,2 mg/kg Limit, EU (articles for infants and small children with food contact): see below Zinc / 7440-66-6 938 mg/kg Test Method: DIN EN 71-3 / DIN EN ISO 17294-2 Limit: in scraped-off toy material valid from July 20 EU Requirement: Directive 88/378/EEC valid until July 20; Directive / CAS No. Limit 2009/48/EC valid from July 20; valid for toys only Aluminium / 7429-90-5 70 000 mg/kg EU Requirement: DIN EN 14372, Baby cutlery and crockery; DIN EN 14350-2, Antimony / 7440-36-0 560 mg/kg babyl drinking equipment Arsenic / 7440-38-2 47 mg/kg / CAS No. Limit Barium / 7440-39-3 56 000 mg/kg Antimony 7440-36-0 60 mg/kg Boron / 7440-42-8 15 000 mg/kg Arsenic 7440-38-2 25 mg/kg 17 mg/kg Barium 7440-39-3 1000 mg/kg Chromium (III) 460 mg/kg Lead 7439-92-1 90 mg/kg Chromium (VI) 0,2 mg/kg Cadmium7440-43-9 75 mg/kg Cobalt / 7440-48-4 0 mg/kg Chromium7440-47-3 60 mg/kg Copper / 7440-50-8 7 700 mg/kg Mercury 7439-97-6 60 mg/kg Lead / 7439-92-1 160 mg/kg Selen 7782-49-2 500 mg/kg Manganese / 7439-95-47 15 000 mg/kg / CAS No. Limit A Limit Limit: in dry, brittle, powder-like or pliable toy material valid from July 20 / CAS No. Aluminium / 7429-90-5 Antimony / 7440-36-0 Arsenic / 7440-38-2 Barium / 7440-39-3 Boron / 7440-42-8 Chromium (III) Chromium (VI) Cobalt / 7440-48-4 94 mg/kg Nickel / 7440-02-0 930 mg/kg Limit Selenium / 7782-49-2 460 mg/kg 5 625 mg/kg Strontium / 7440-24-6 56 000 mg/kg 45 mg/kg Tin / 7440-31-5 180 000 mg/kg 3,8 mg/kg Organic tin 12 mg/kg 4 500 mg/kg Zinc / 7440-66-6 46 000 mg/kg 1 200 mg/kg 1,3 mg/kg 37,5 mg/kg 0,02 mg/kg 10,5 mg/kg
4 of Restricted s List (RSL) for Consumer Goods 12. Lead and Cadmium Release New-L 0,003 mg/l Copper / 7440-50-8 1 mg/l Limit, EU (ceramic, enamel, porcelain): see below Manganese / 7439-96-5 0,5 mg/l Nickel / 7440-02-0 0,02 mg/l Test Method: 64 LFGB B 80.03-1/-2/-3/-4 / DIN EN 88 0,001 mg/l EU Requirement: Directive 84/500/EEC Selen / 7782-49-2 0,01 mg/l DE Requirement: BedGgstV Non-fillable articles: per article surface PL Requirement: PN-B 210 Wyroby szklane i ceramiczne przeznaczone do kontaktu z zywnoscia - Dopuszczalne ilosci uwalnianego olowiu i kadmu Lead / 7439-92-1 Chromium / 7440-47-3 0,01 mg/dm² 0,4 mg/dm² / Cas No Limit EU Limit PL 0,005 mg/dm² Lead / 7439-92-1 Nickel / 7440-02-0 0,1 mg/dm² Lead Release / non-fillable articles 0,8 mg/dm² Lead Release / fillable articles < 3 l 4.0 mg/l 2,0 mg/l 15. Alkylphenols and Alkylphenolethoxylates AP, APEO Lead Release / fillable articles > 3 l 1.5 mg/l 1,0 mg/l Lead release / Rim (DE / PL) 2,0 mg/article Limit, OTTO Group (textiles): AP 50 mg/kg; APEO 500 mg/kg Limit, EU: Cadmium Release / non-fillable articles 0,07 mg/dm² Limit, EU (Nonylphenol and Nonylphenolethoxylates): Cadmium Release / fillable articles < 3 l Cadmium Release / fillable articles > 3 l Cadmium Release / Rim (DE / PL) 0,3 mg/l 0,1 mg/l 0,2 mg/article 0.1% valid for preparations only Test Method: In-house method, Ultrasonic Extraction in methanol (textiles) and methanol/tetrahydrofuran (polymer) for 30 min. at RT, detection by LC- Qtrap. Zinc, Antimony and Barium Release New-P EU Requirement: Regulation (EC) No 1907/2006 Annex XVII valid for preparations only; Limit (Nonylphenol and Nonylphenolethoxylates in Limit, AT (ceramic, enamel, porcelain): see below preparations): 0,1% no legal limit for Octylphenol and Test Method: 64 LFGB B 80.03-1/-2/-3/-403 3/ / DIN EN 88 CAS No. AT Requirement: Keramik-Verordnung Nonylphenol NP 84852-15-3 / CAS No. Limit Nonylphenol ethoxylates NPEO Zinc / 7440-66-6 Octylphenol OP 9002-93-1 Zinc Release / fillable articles < 1 L 3 mg/article Octylphenol ethoxylates OPEO Zinc Release / fillable articles > 1 L 3 mg/l Antimony / 7440-36-0 16. Antioxidants Antimony Release / fillable articles < 1 L 1 mg/article Antimon Release / fillable articles > 1 L 1 mg/l Limit, EU: acc. to DIN EN 14350 (baby drinking equipment), see below Barium / 7440-39-3 Test Method: DIN EN 14350-2 Barium Release / fillable articles < 1 L 1 mg/article EU Requirement: Directive 2001/95/EC, 88/378/EWG valid until Barium Release / fillable articles > 1 L 1 mg/l 2011/20; 2009/48/EC valid from 2011/20; valid for toys only / CAS No Limit 14. Metal Release Fillable articles: per simulant food 2,6-Di-tert-butyl-p-cresol (BHT) / Limits refer to metals with food contact 128-37-0 30 µg/100 ml Limit, EU: no limits 6,6'-di-tert-butyl-2,2'-methylen-dip-cresol Limit, CH, DE, IT: see below (Antioxidant 2246) / 119-15 µg/100 ml Test Method (Metal composition/steel key): X-ray fluorescence analysis RFA IEC 47-1 62321 Ed.1 Non-fillable articles: per article surface Test Method (Migration in simulant food): 64 LFGB B 80.30-1/-2/-3 2,6-Di-tert-butyl-p-cresol (BHT) / EU Requirement (Metal Release): Regulation (EC) No 1935/2004 CH Requirement (Aluminum): Switzerland: Directive 817.023.21 128-37-0 6,6'-di-tert-butyl-2,2'-methylen-dip-cresol (Antioxidant 2246) / 119-47-1 60 µg/dm² 30 µg/dm² DE Requirement: LFBG 31; fillable articles: limit values for metal migration acc. to mineral water, MinTafWV; non-fillable articles: Hausch, Deutsche Lebensmittel- Rundschau 03/1996: Metalllässigkeit von Bestecken aus nichtrostenden Stählen 17. Asbestos Fibers IT Requirement (stainless steel): Notification No 2009/202/I, Technical Regulations Information System, TRIS, 7 April 2009: Only specific stainless steel Limit, EU: not detectable is allowed, which is indicated by a special steel key or which is defined by the Test method: Visual identification by microscope composition EU Requirement: Regulation (EC) 1907/2006 Annex XVII / CAS No. Limit CAS No. Fillable articles per simulant food Actinolit 77536-66-4 Aluminium / 7429-90-5 10 mg/l Amosit 12172-73-5 Antimony / 7440-36-0 0,005 mg/l Anthophyllit 77536-67-5 Arsenic / 7440-38-2 0,01 mg/l Chrysotil 12001-29-5 Barium / 7440-39-3 1 mg/l Krokydolith 12001-28-4 Lead / 7439-92-1 0,01 mg/l Tremolit 77536-68-6 Chromium / 7440-47-3 0,05 mg/l
5 of Restricted s List (RSL) for Consumer Goods 18. Aromatic Amines 20. Bisphenol A New-L 18.1 Aromatic Amines, textiles Limit, OTTO Group (textiles): not detectable Limit, EU: not detectable Limit, AT, BE, FR, DK, SE: see below Limit, EU (toys): not detectable Test Method: DIN EN 14372 Limit, CH (p-phenylendiamine in textiles): not detectable EU Requirement: Regulation (EC) No 10/2011: The use of Bisphenol A is Test method: DIN EN 14362-1; Toys: DIN EN 71-9 totally forbidden for baby bottles made of polycarbonate EU Requirement: Directive 2001/95/EC; toys only: Directive 88/378/EEC valid AT Requirement: LMSVG, prohibited in pacifiers and teethers until July 20; Directive 2009/48/EC valid from July 20 CH Requirement: Directive 817.023.41: no use of p-phenylenediamine in textiles CAS No. p-phenylendiamine 106-50-3 2-Naphthylamine 91-59-8 3,3' -Dichlorobenzidine 91-94-1 3,3' -Dimethoxybenzidine 119-90-4 3,3' -Dimethylbenzidine 119-93-7 4,4'-Diaminodiphenylmethane 101-77-9 Benzidine 92-87-5 o-anisidine 90-04-0 DK Requirement: Recommendation of Danish Veterinary and Food Administration: Bisphenol A is prohibited in articles with food contact for children < 3 years o-toluidine 95-53-4 CAS No. p-chloroaniline 106-47-8 Bisphenol A 80-05-7 2,4-Toluylenediamine 95-80-7 21. Chlorinated aliphatic compounds 18.2 Aromatic Amines, plastic, paper, cardboard and board Limit, EU (plastic): 0,01 mg/kg Limit, i Otto Group (paper, cardboard, d board): no use New-P Test method: 64 LFGB L 00.00-6; Technical guideline EUR 24815 EN 2011; DIN EN 14362-1 EU Requirement: Regulation (EU) No. 10/2011; Limit: 0,01 mg/kg sum of released primary aromatic amines, excluded are primary aromatic amines which are regulated in table 1 of annex I regulation (EU) No. 10/2011. DE Requirement: Recommendation of BfR No. XXXVI. Papiere, Kartons und Pappen für den Lebensmittelkontakt", Issue date 01.01.2012 CAS No. Aniline 62-53-3 4,4-Diaminodiphenylether 4,4'-Methylenedianiline m-phenylendiamine 2,4-Toluenediamine 2,6-Toluendiamin 3,3-Dimethylbenzidine 19. Benzene Limit, OTTO Group (general): 5 mg/kg valid for all consumer products Limit, EU: see below Test Method: in-house method, headspace (30 min at 110 C). GC-MS, Semiquantitative determination against d8-toluene EU Requirement: Regulation (EC) 1907/2006 Annex XVII. Limit in toys: 5 mg/kg; limit in preparations: 0,1 % Limit, EU: BE Requirement:. 5-338/8; Bisphenol is prohibited for materials with food contact for children < 3 years FR Requirement: Act 2010-729: Bisphenol A is prohibited in baby bottles, Act 2012-1442: Bisphenol A is prohibited for food contact materials and articles for children < 3 years SE Requirement: SFS 2012:991: Bisphenol A is prohibited for paints and coatings in food packaging intended for children < 3 years; valid from July 20 Test Method: in-house method, headspace (30 min at 110 C). GC-MS, Semi-quantitative determination against d8-toluene EU Requirement: Regulation (EC) 1907/2006 Annex XVII; valid for preparations only; Limit (sum): 0,1 % 21.1 Chloraliphates Congener Group 1 Limit, DE: 0,1% DE Requirement: ChemVerbotsV; Congener group 1 refers to preparations and commodities; Limit (sum): 0,1 % 101-80-4 CAS No. 101-77-9 Tetrachloromethane 56-23-5 108-45-2 1,1,1,2 Tetrachloroethane 630-20-6 95-80-7 1,1,2,2 Tetrachloroethane 79-34-5 823-40-5 Pentachloroethane 76-01-7 119-93-7 21.2 Chloraliphates Congener Group 2 Limit, DE: DE Requirement: ChemVerbotsV; Congener group 2 refers to preparations only; Limit (sum): 0,1 % CAS No. 1,1 Dichloroethene 75-35-4 1,1,1 Trichloroethane 71-55-6 1,1,2-Trichloroethane 79-00-5 CAS No. Trichloromethane 67-66-3 Benzene 71-43-2 21.3 Chloraliphates, further substances Limit,Otto Group: see below Limit, gesetzlich EU: No use in preparations in the production process of non-ferrous metals CAS No. Hexachloroethane 67-72-1
6 of Restricted s List (RSL) for Consumer Goods 22. Cyclohexane 25. Chlorinated Paraffins C10-C New-L Limit, OTTO Group: 0,1% Limit, EU: Limit, EU: not detectable Limit, EU (preparations): 1 % Test Method: in-house method, headspace (30 min at 110 C). GC-MS, Semiquantitative determination against d8-toluene Test Method: in-house method, Ultrasonic extraction in dichlormethane for 30 min at RT, detection of short chained paraffins via LC-TOF EU Requirement: Regulation (EC) 1907/2006 Annex XVII; 0,1 % in contact adhesives on neoprene basis EU Requirement: Regulation (EC) 850/2004 Annex I, limit 1% valid for CAS No. substances and preparations. SCCPs containing items are prohibited. Cyclohexane 110-82-7 DE Requirement: ChemVerbotsV; valid for preparations; Limit: 1 % CAS No. 23. Chlorinated Benzenes Chlorinated Paraffins C10-C 85535-84-8 Limit, EU: 26. Dimethylfumarate Test Method: DIN 54232 EU Requirement: Regulation (EC) 1907/2006 Annex XVII limit values refers to Limit, EU: 0,1 mg/kg Trichlorobenzene (1,2,3-Trichlorobenzene, 1,2,4-Trichlorobenzene and 1,3,5- Trichlorobenzene), legal limit refers to preparations: 0,1 % DE Requirement: ChemVerbotsV: refers to 1,2,4-Trichlorbenzene only, legal limit refers to preparations: 0,1 % CAS No. 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,3,5-Trichlorobenzene Pentachlorophenol 2,3,4,5-Tetrachlorophenol 2,3,4,6-Tetrachlorophenol 2,3,5,6-Tetrachlorophenol Test Method: Pretest Headspace GC-MS. Quantitation by ultrasonic extraction with dicloro methane for 30 min at RT and subsequent detection GC-MS. EU Requirement: Regulation (EC) No 1907/2006 Annex XVII; valid for products and components of products 87-61-6 CAS No. 120-82-1 Dimethylfumarate 624-49-7 108-70-3 27. Dioxins and Furanes 24. Chlorinated Phenols New-L Limit, OTTO Group (PCP, TeCP in consumer products): 0,5 mg/kg Limit, OTTO Group: see below Limit, OTTO Group (PCP, TeCP, paper with food contact): 0,15 mg/kg Limit, DE: see below Limit (PCP), AT, CH, DE, DK, NL, NO: 5 mg/kg; SK see below Test Method: DIN EN 194; VDI 3499 Limit (PCP in paper with food contact), legal DE: 0,15 mg/kg DE Requirement: ChemVerbotsV Limit (TeCP) CH: no use Parameter Limit Test Method: EN ISO 17070; EPA 3545A Limit (Dioxins + Furanes Cogeners Group 1): 1 µg/kg EU Requirement: Regulation (EC) No 1907/2006 Annex XVII; PCP limit for Limit (Dioxins + Furanes Cogeners Group 2): 5 µg/kg preparations: 0,1 %; Limit (Dioxins + Furanes Cogeners Group 3): 100 µg/kg AT Requirement: ChemVerbotsV 2003 limit for PCP in preparations: 0,1 %; limit for PCP in : 5 mg/kg 28. Flammable and highly flammable substances CH Requirement: ChemRRV 814.81 no use of PCP and TeCP, Swiss authorities accept articles up to PCP/TeCP-contents of 5 mg/kg Limit, EU (decoration articles): not detectable DE Requirement: ChemVerbotsV limit for PCP in preparations: 0,1 %; limit for PCP in : 5 mg/kg; LFGB, Recommendation of BfR No 018/2007 Test Method: in-house method, headspace (30 min at 110 C). GC-MS, (Federal Institute for Risk Assessment): limit for PCP in paper with food contact: Semi-quantitative determination against d8-toluene 0,15 mg/kg. DK Requirement: BEK nr. 854 of 5 September 2009, Bekendtgørelse om forbud mod import, salg og eksport af varer, der indeholder pentachlorphenol: Limit for PCP and its salts and esters in products: 5 mg/kg NL Requirement: Besluit van 23 september 1997, houdende vaststelling van het Warenwetbesluit Pentachloorfenol; Limit for PCP in : 5 mg/kg NO Requirement: Regulation No. 922 of 1 June 2004, Forskrift om begrensning i bruk av helse- og miljøfarlige kjemikalier og andre produkter (produktforskriften): Limit for PCP and its salts and esters in textile and leather articles: 5 mg/kg SK Requirement: Decree 635/2005 PCP limit in textiles: 0,5 mg/kg; PCP limit in leather: adult 5 mg/kg and baby 0,5 mg/kg CAS No. 87-86-5 EU Requirement: no use of substances, that are marked as flammable and highly flammable acc. to Regulation (EC) No 1272/2008, in decoration articles (e.g. metallic glitter for festivities, artificial snow, evanescent bubbles and flakes, artificial cobwebs, streamers, stink bombs) 29. Flame retardants: Organophosphates Limit, EU (toys): not detectable Test Method: DIN EN 71-9 /-10 /-11 EU Requirement: Directive 88/378/EEC valid until 2011/20; Directive 2009/48/EC valid from 2011/20 DE Requirement: ProdSG, LFGB 30. DIN EN 71-9 is not harmonized within all European countries. Though the German authorities observe the compliance with DIN EN 71-9 4901-51-3 CAS No. 58-90-2 Tri-o-kresyphosphate 78-30-8 935-95-5 Tris(2-chlorethyl)-phosphate) 115-96-8
7 of Restricted s List (RSL) for Consumer Goods 30. Flame Retardants incl. RoHS Limit, EU (PBB, TEPA, TRIS in textiles with skin contact): not detectable EU Requirement: Directive 88/378/EEC valid until July 20; Directive 2009/48/EC valid from July 20; valid for toys only, Limit in toys acc. to DIN EN 71-9: wood: 80 mg/kg; textiles and paper: 30 mg/kg Limit, EU (Octa/Penta-BDPE in and Deca/Octa/Penta- BDPE/PBB in electronic articles): 1000 mg/kg Test Method: in-house method, Ultrasonic extraction in dichloro methane for 30 min at RT, detection with GC-MS or LC-TOF EU Requirement (TRIS, TEPA, PBB): Regulation (EC) No 1907/2006 Annex XVII no use of TRIS, TEPA, PBB in textiles with skin contact EU Requirement (Octa-, Pentabromodiphenylether): Regulation (EC) No 1907/2006 Annex XVII; limit for Octa-, Pentabromodiphenylether: 0,1% in incl. Electronic devices RoHS Requirement (Octa-, Penta-, Decabromdiphenylether, Polybrominated Biphenyls PBB): 2011/65/EC: Restriction of the use of certain hazardous substances in electrical and electronic equipment (RoHS) CAS No. Tris-(azoridinyl)-phosphinoxid TEPA 545-55-1 Tri-(2,3-dibromopropyl)-phosphate TRIS 126-72-7 Polybrominated Biphenyls PBB 59536-65-1 Octabromodiphenylether 32536-52-0 Pentabromodiphenylether 32534-81-9 Decabromobiphenylether 1163-19-5 31. Fluorinated Greenhouse Gases Limit, EU: not detectable Test Method: in-house method, headspace (15 min at 70 C). GC-MS, Semiquantitative determination against d8-toluene EU Requirement: Regulation (EC) 842/2006; Limit: not detectable EU Requirement: DIN EN 14372: Limit formaldehyde baby cutlery and crockery: 15 mg/kg EU Requirement: Regulation (EU) No. 284/2011; valid for melamin kitchenware from china only, Limit: 15 mg/kg DE Requirement: XXXVI. Papiere, Kartons und Pappen für den Lebensmittelkontakt; valid for paper, carton and cardboard, Limit: 1 mg/dm² AT Requirement: PSG 2004; BGBI. No 194/1990; mandatory labelling of formaldehyde in textiles with skin contact at a content > 1500 mg/kg CZ Requirement: Act No 84/2001: Formaldehyde in toys and baby products: 30 mg/kg DE Requirement: BedGgstV 10 Anl. 9,2: mandatory labelling of formaldehyde in textiles with skin contact at a content > 1500 mg/kg; ChemVerbotsV: limit value for derived timber products: 0,1 ppm; test method 717/1 FI Requirement: Decree 210/1988; Limit in textiles with skin contact: 100 mg/kg FR Requirement: Notification 97/01431/F; Limit in articles with skin contact: 100 mg/kg NL Requirement: Legislative Decree formaldehyde in textiles, Decision of 22. March 2001; Limit in articles with skin contact: 120 mg/kg NO-Anforderung: Forskrift om begrensning i bruk av helse- og miljøfarlige kjemikalier og andre produkter (produktforskriften): textiles for babys < 3 years: 30 mg/kg, textiles with skin contact: 100 mg/kg CAS No. CAS No. Perfluorinated Hydrocarbons (PFC) Formaldehyde 50-00-0 Partially Fluorinated Hydrocarbons Sulfurhexafluoride SF6 2551-62-4 34. N-Nitrosoamines 32. Fluorochlorohydrocarbons (CFC) and halons (HC) Limit, EU: not detectable Test Method: in-house method, headspace (30 min at 110 C). GC-MS, Semiquantitative determination against d8-toluene EU Requirement: Regulation (EC) No 2037/2000; refers to e.g. fridges, blowing gases in spray cans DE Requirement: ChemOzonschichtV; refers to e.g. fridges, blowing gases in spray cans Parameter CFC compounds Halons 33. Formaldehyde New-L Limit, OTTO-Group (textiles with skin contact adult / baby): 75 mg/kg / 20 mg/kg Limit, OTTO-Group (leather with skin contact): 150 mg/kg Limit, EU: Limit only for toys acc. DIN EN 71-9 Limit, EU: Limit for baby cutlery and crockery: 15 mg/kg Limit, AT, CZ, DE, FI, FR, NL, NO, SK: see below Test Method: DIN EN ISO 14184-1/ ISO 17226-2 Test Method (Toys): different test methods acc. to DIN EN 71-9; wood: EN 717-3; textiles: DIN EN ISO 14184; paper: EN 645 and DIN EN 1541 Test method (baby cutlery and crockery): DIN EN 14372 SK Requirement: Decree 635/2005: Adults: Formaldehyde in leather: 150 mg/kg, in textile: 75 mg/kg; babies: Formaldehyde in leather: 50 mg/kg, in textile: 20 mg/kg Limit, EU (children articles): see below Test Method: EN 12868; EN 1400-3 EU Requirement: Directive 93/11/EEC; Limit (nitrosoamines in rubber teats, soothers and baby articles that can be taken into the mouth): 0,01 mg/kg; limit (nitrosatable substances in rubber teats, soothers and baby articles that can be taken into the mouth): 0,1 mg/kg EU Requirement: DIN EN 14350-2; Limit (baby drinking equipment) nitrosamines: 0,01 mg/kg; nitrosable substances: 0,1 mg/kg DE Requirement: BedGgstV; Limit (toys for children < 3 years) nitrosoamines: 0,01 mg/kg; nitrosatable substances: 0,1 mg/kg; Limit (balloons) nitrosoamines: 0,05 mg/kg; nitrosatable substances: 1 mg/kg CAS No. N-Nitrosamines 35. Mercaptobenzothiazol MBT Limit, EU (baby articles with food contact): 8 mg/kg in aqueous migration solution Test Method: DIN EN 14350-2 EU Requirement: 2001/95/EC, 88/378/EWG valid until 2011/20; 2009/48/EC valid from 2011/20; valid for toys only CAS No. Mercaptobenzothiazol MBT 149-30-4 New-L EU Requirement: Directive 2009/48/EG (valid from July 20); Limit (toys from natural- and synthetic rubber for children < 3 years) Nitrosamines: 0,05 mg/kg; limit (toys for children < 3 years) nitrosoamines: 0,1 mg/kg
8 of Restricted s List (RSL) for Consumer Goods 36. Methylene diphenyl diisocyanate (MDI) Monomethyltetrachlorodiphenylm Limit, EU: 0,1%in preparation, otherwise use of protection gloves and marking ethane (Ugilec 141) 76253-60-6 as sensitizing substance are mandatory EU Requirement: Regulation (EC) No 1907/2006 Annex XVII. Limit: 0,1% in 40. Perfluorinated Tensides preparations. Limit, OTTO Group (PFOS, PFOA in textiles): see below CAS No. Limit, EU (PFOS in textiles): see below Methylene diphenyl diisocyanate (MDI) 26447-40-5 Limit, NO (PFOA): see below 4,4'- Diphenylmathane diisocyanate 101-68-8 2,4'-Diphenylmethane diisocyante 5873-54-1 2,2'-methylenediphenyl diisocyanate 2536-05-2 37. Organotin Compounds Limit, OTTO Group (toys): no use Limit, OTTO Group (further ): 0,1% Limit, EU: 0,1% see below Limit, DE (toys for babies < 3 years): no use Test Method: DIN EN ISO 17353 / EN 71-3 EU Requirement (DBT): Regulation (EC) 1907/2006 Annex XVII; Limit: 0,1 % valid for mixture and EU Requirement (DOT): Regulation (EC) 1907/2006 Annex XVII; Limit: 0,1 % valid for textile artciles with skin contact, gloves, shoes, wall and floor covering, Test Method: in-house method, Ultrasonic extraction with dichloro methane for 30 min at RT. Analytical determination is performed via LC-Qtrap EU Requirement: Regulation (EC) No 850/2004; legal limit for products: 0,1%, for preparations: and for coated textiles: 1 µg/m²; EU intends to find a limit for PFOA too NO Requirement valid from 1 January 20: Regulation 1. June 2004 No.922 (Product Regulation); legal limit PFOA and individual salts and individual esters: for sell consumer textiles, floor carpeting and other coated consumer products: 1 µg/m²; for other consumer products: 0,0001% / CAS No. Limit (textiles) Perfluorooctane Sulfonate PFOS / 2795-39-3 1 µg/m 2 baby articles, women care articles, nappies Perfluoroctansäure PFOA / 335- EU Requirement (TBT, TPhT): Regulation (EC) 1907/2006 Annex XVII; limit: 0,1 67-1, 3825-26-1, 335-95-5, 2395- % valid for 00-8, 2395-00-8, 335-93-3, 335-1 µg/m 2 EU Requirement (toy, migration of organotin): Directive 2009/48/EC, valid from 66-0, 376-27-2, 3108-24-5 July 20 DE Requirement: Recommendation of BfR No XLVII: No use for toys for children 41. Polycyclic Aromatic Hydrocarbons PAH < 3 years (Federal Institute for Risk Assessment) Limit, OTTO Group: see below CAS No. Limit, EU: no limits for consumer gods Dibutyltin (DBT) Limit, DE (GS Certification): see below Tributyltin (TBT) Test Method: ZEK 01.4-08 Triphenyltin (TPhT) Dioctyltin (DOT) 38. Pesticide (DDT) Limit, OTTO Group: not detectable Limit, DE, CH: not detectable Test Method: EPA M 8270C; 3545; ISO 159 CH Requirement: ChemRRV 814.81; Consumer products that contain DDT are not marketable. DE Requirement: ChemVerbotsV; Consumer products that contain DDT are not marketable. CAS No. 1,1,1-Trichlor-2,2-bis-(4-chlorophenyl)ethan 50-29-3 DDT and isomers EU Requirement: Directive 2001/95/EC; no limits are defined for consumer goods EU Requirement: Regulation (EC) No 1907/2006 Annex XVII; Restriction on the marketing and use of extender oils for the production of tyres and parts of them if they exceed the following values: Polycyclic aromatic hydrocarbons PAH - sum: or Benzo(a)pyrene: 1 mg/kg. DE Requirement: ProdSG, LFGB 30, ZEK 01.4-08; limit values refer to products with GS-certification, only (ZEK 01.4-08); no limits are defined for further products yet. Acc. to BfR 025/2009 the PAH content in consumer goods should be as low as possible (Federal Institute of Risk Assessment). Limits for products with GS-certification Polycyclic aromatic hydrocarbons PAH - sum (skin contact < 30 s): 200 mg/kg 39. Polychlorinated Biphenyles PCB, Terphenyles PCT and Benzo(a)pyrene (skin contact < 30 s): 20 mg/kg halogenated Phenylmethanes Polycyclic aromatic hydrocarbons PAH - sum (skin contact > 30 s): 10 mg/kg Limit, OTTO Group: not detectable in Benzo(a)pyrene (skin contact > 30 s): 1 mg/kg Limit, DE: not detectable in Polycyclic aromatic hydrocarbons PAH - per substance (baby articles and Test Method: EPA M 8270C; 3545 articles that can be taken into the mouth): 0,2 mg/kg EU Requirement: Regulation (EC) 1907/2006 Annex XVII; DBBT, Ugilec 121 or OTTO Group Limits: 21, Ugilec 141: not detectable in ; PCT-limit in preparations: 50 Polycyclic aromatic hydrocarbons PAH - sum ( general): mg/kg DE Requirement: ChemVerbotsV; PCB/PCT, DBBT, Ugilec 121 or 21, Ugilec Benzo(a)pyrene ( general): 1 mg/kg 141: not detectable in ; limit in preparations: 50 mg/kg Polycyclic aromatic hydrocarbons PAH - per substance (baby articles, CAS No. articles that can be taken into the mouth and articles with food contact): 0.2 Polychlorinated biphenyles PCB 36-36-3 mg/kg Polychlorinated terphenyles PCT 61788-33-8 CAS No. Monomethyldibromodiphenylmethane Benzo(a)pyrene 50-32-8 99688-47-8 (DBBT) Acenaphthene 83-32-9 Monomethyldichlorodiphenylmethane (Ugilec 121 or 21) Acenaphthylene 208-96-8
9 of Restricted s List (RSL) for Consumer Goods 41. Polycyclic Aromatic Hydrocarbons PAH Tri-p-kresylphosphate 78-32-0 Triphenylphosphate 115-86-6 CAS No. Anthracene 120-12-7 44. Preservatives Benzo(a)anthracene 56-55-3 Benzo(g,h,i)-perylene 191-24-2 Limit, EU (toys): not detectable Benzo(b)fluoranthene 205-99-2 Test Method: DIN EN 71-9 /-10 /-11 Benzo(k)fluoranthene 207-08-9 EU Requirement: Directive 88/378/EEC valid until 2011/20; Directive Chrysene 218-01-9 2009/48/EC valid from 2011/20 Dibenz(a,h)anthracene 53-70-3 DE Requirement: ProdSG, LFGB 30. DIN EN 71-9 is not harmonized Fluoranthene 206-44-0 within all European countries. Though the German authorities observe the Fluorene 86-73-7 compliance with DIN EN 71-9 Indeno(1,2,3-cd)pyrene 193-39-5 44.1 Preservatives in leather, liquids and modelling clay Naphthalene 91-20-3 / CAS No. Limit Phenanthrene 85-01-8 Formaldehyde / 50-00-0 0,05% Pyrene 129-00-0 Phenol / 108-95-2 Benzo(j)fluoranthene 205-82-3 1,2-Benzisothiazol-3-one / 2634-2-Methyl-4-isothiazolin-3-one / Benzo(e)pyrene 42. 192-97-2 Plasticizers: Phthalates 33-5 New-L 2682-20-4 5 mg/kg Limit, EU (DEHP, BBP, DBP, toys in general): 0,1% 5-Chlor-2-methyl-4-isothiazolin-3- one / 26172-55-4 Limit, EU (DNOP, DIDP, DINP, toys that can be taken into the mouth): 0,1% 5-Chlor-2-methyl-4-isothiazolin-3- Limit, EU (DEHP, BBP, DBP, DNOP, DIDP, DINP baby cutlery and crockery): sum 0,1% one + 2-Methyl-4-isothiazolin-3- one 15 mg/kg Limit, DK (DEHP, DIBP, BBP, DBP products for indoor use, products with skin contact or mucous membrane): 0,1% 44.2 Preservatives in wood Test Method: DIN EN 15777; DIN EN 14372; EPA M 1625 / CAS No. Limit EU Requirement: Regulation (EC) No 1907/2006 Annex XVII, valid for toys and Cyfluthrin / 68359-37-5 baby products only; limits: sum (DEHP, BBP, DBP) = 0,1% for all kinds of toys Cypermethrine / 52315-07-8 and baby products, sum (DNOP, DIDP, DINP) = 0,1% refers to parts that can be Deltamethrine / 52918-63-5 taken into the mouth. Lindan / 58-89-9 2 mg/kg EU Requirement: DIN EN 14372, Baby cutlery and crockery Pentachlorophenol / 87-86-5 2 mg/kg DK Requirement: Statutory Order no. 786 of 11 July 2006, valid for toys and Permethrin / 52645-53-1 childcare products only; limits: sum (DEHP, BBP, DBP) = 0,1% for all kinds of toys and childcare products, sum (DNOP, DIDP, DINP) = 0,1% refers to parts that 45. Solvents, migration can be taken into the mouth. Moreover: 0,05% of other phthalates, valid for toys and childcare products for babies < 3 years Limit, EU (toys): not detectable DK Requirement: BEK nr 11 af 26/11/2012, valid for products for indoor use, material with skin contact or mucous membrane, limit (DEHP, BBP, DBP, DIBP): Test Method: DIN EN 71-9/-10/-11 0,1%, valid from 1 Dezember 20 EU Requirement: Directive 88/378/EEC valid until July 20; Directive CAS No. 2009/48/EC valid from July 20; valid for toys only Butylbenzyl phthalate / BBP 85-68-7 DE Requirement: ProdSG, LFGB 30. DIN EN 71-9 is not harmonized Dibutyl phthalate / DBP 84-74-2 within all European countries. Though the German authorities observe the Di-(2-ethylhexyl)-phthalate / DEHP 117-81-7 compliance with DIN EN 71-9 Di-iso-butylphthalate / DIBP 84-69-5 / CAS No. Limit Di-iso-decylphthalate / DIDP 26761-40-0 Nitrobenzene / 98-95-3 0,02 mg/l Di-iso-nonylphthalate / DINP 28553-12-0 Bis (2-methoxyethyl)ether / 111- Di-n-octylphthalate / DNOP 117-84-0 96-6 0,5 mg/l Cyclohexanone / 108-94-1 46 mg/l 43. Plasticizers, migration: Organophosphates Dichloromethane / 75-09-2 0,06 mg/l Ethylbenzene / 100-41-4 1 mg/l Limit, EU (toys): not detectable Methanol / 67-56-1 5 mg/l Test Method: DIN EN 71-9 /-10 /-11 Toluene / 108-88-3 2 mg/l EU Requirement: Directive 88/378/EEC valid until July 20; Directive Trichloroethene / 79-01-6 0,02 mg/l 2009/48/EC valid from 2011/20 2-Methoxyethyl acetate / 110-49-6 0,5 mg/l DE Requirement: ProdSG, LFGB 30. DIN EN 71-9 is not harmonized within all 2-Ethoxyethanol / 110-80-5 0,5 mg/l European countries. Though the German authorities observe the compliance with 2-Ethoxyethyl Acetate / 111-15-9 0,5 mg/l DIN EN 71-9 2-Methoxypropyl acetate / 70657- CAS No. 70-4 0,5 mg/l Tri-m-kresylphosphate 563-04-2 Tri-o-kresylphosphate 78-30-8 3,5,5-Trimethyl-2-cyclohexene-1- one / 78-59-1 Xylene (all isomers) 3 mg/l 2 mg/l
10 of Restricted s List (RSL) for Consumer Goods 46. Solvents, inhalation Fig leaf, fresh and preparations 68916-52-9 Limit, EU (toys): not detectable trans-2-heptenal 18829-55-5 trans-2-hexenal diethyl acetal 67746-30-9 Test Method: DIN EN 71-9/-10/-11 trans-2-hexenal dimethyl acetal 18318-83-7 EU Requirement: Directive 88/378/EEC valid until July 20; Directive 2009/48/EC valid from July 20; valid for toys only Hydroabietyl alcohol 4-Ethoxy-phenol 393-93-6 622-62-8 DE Requirement: ProdSG, LFGB 30. DIN EN 71-9 is not harmonized within all 6-lsopropyl-2- European countries. Though the German authorities observe the compliance with decahydronaphthalenol 341-99-2 DIN EN 71-9 7-Methoxycoumarin 531-59-9 / CAS No. Limit 4-Methoxyphenol 150-76-5 Cyclohexanone / 108-94-1 Ethylbenzene / 100-41-4 6 µg/m³ 5000 µg/m³ 4-(p-Methoxyphenyl)-3-butene-2-1-(p-Methoxyphenyl)-1-penten-3- Dichloromethane / 75-09-2 Hexane / 110-54-3 3000 µg/m³ 1800 µg/m³ one one 943-88-4 104-27-8 Nitrobenzene / 98-95-3 1 µg/m³ Methyl trans-2-butenoate 623-43-8 Trichloroethene / 79-01-6 1 µg/m³ 6-Methylcoumarin 92-48-8 Toluene / 108-88-3 260 µg/m³ 7-Methylcoumarin 2445-83-2 Xylene (all isomers) 870 µg/m³ 5-Methyl-2,3-hexanedione 706-86-0 1,3,5-Trimethylbenzene / 108-67-8 2500 µg/m³ Costus root oil (Saussurea lappa 3,5,5-Trimethyl-2-cyclohexene-1-one / 78-59-1 200 µg/m³ Clarke) 8023-88-9 7-Ethoxy-4-methylcoumarin 8023-88-9 47.Allergenic Fragrances New-P Hexahydrocoumarin 87-05-8 Peru balsam, crude (Exudation Limit (toys): see below of Myroxylon pereirae (Royle) 8007-00-9 Test Method: EN 71- ( in development) 2-Pentylidene-cyclohexanone 25677-40-1 EU Requirement: Directive 2009/48/EG (valid from July 20) 3.6,10-Trimethyl-3.5,9- Labelling of 11 Allergenic Fragrances in toys or parts of toys by concentrations undecatrien-2-one 1117-41-5 exceeding 100 mg/kg Verbena oil (Lippia citriodora CAS No. Kunth) 8024-12-2 Anisyl alcohol 105--5 Musk ambrette (4-tert-Butyl-3- Benzyl benzoate 120-51-4 methoxy-2,6-dinitrotoluene) 97-53-0 Benzyl cinnamate 103-41-3 4-Phenyl-3-buten-2-one 106-24-1 Citronellol 106-22-9 Amyl cinnamal 107-75-5 Farnesol 4602-84-0 Amylcinnamyl alcohol 31906-04-4 Hexyl cinnamaldehyde 101-86-0 Benzyl alcohol 97-54-1 Lilial 80-54-6 Benzyl salicylate 90028-68-5 d-limonene 5989-27-5 Cinnamyl alcohol 90028-67-4 Linalool 78-70-6 Cinnamal 105--5 Methyl heptine carbonate 111-12-6 Citral 120-51-4 3-methyl-4-(2.6,6-trimethyl-2-cyclohexen-1- Coumarin 103-41-3 127-51-5 yl)-3-buten-2-one Eugenol 106-22-9 Limit: no use, traces up to 100 mg/kg are permitted Geraniol 4602-84-0 CAS No. Hydroxy-citronellal 101-86-0 Alanroot oil (Inula helenium) 97676-35-2 Hydroxy- Allylisothiocyanate 57-06-7 methylpentylcyclohexene- 80-54-6 Benzyl cyanide 140-29-4 carboxaldehyde 4 tert-butylphenol 98-54-4 Isoeugenol 5989-27-5 Chenopodium oil 8006-99-3 Oakmoss extracts 78-70-6 Cyclamen alcohol 4756-19-8 Treemoss extracts 111-12-6 Diethyl maleate 141-05-9 Dihydrocoumarin 119-84-6 2,4-Dihydroxy-3-methylbenzaldehyde 6248-20-0 3,7-Dimethyl-2-octen-1-ol (6,7- Dihydrogeraniol) 40607-48-5 4,6-Dimethyl-8-tert-butylcoumarin Dimethyl citraconate 7,11-Dimethyl-4.6,10-dodecatrien-3-one 6,10-Dimethyl-3.5,9-undecatrien-2-one Diphenylamine Ethyl acrylate 17874-34-9 617-54-9 26651-96-7 141-10-6 122-39-4 140-88-5
11 of Restricted s List (RSL) for Consumer Goods 48. Colourants Limit, EU (toys): not detectable Test Method: DIN EN 71-9/-10/-11 EU Requirement: Directive 88/378/EEC valid until July 20; Directive 2009/48/EC valid from July 20; valid for toys only DE Requirement: ProdSG, LFGB 30. DIN EN 71-9 is not harmonized within all European countries. Though the German authorities observe the compliance with DIN EN 71-9 CZ Requirement: Act No 84/2001: no use; valid for toys and baby articles Acid Red 26 3761-53-3 Acid Violet 49 1694-09-3 Basic Red 9 569-61-9 Basic Violet 1 8004-87-3 Basic Violet 3 548-62-9 Disperse Blue 1 2475-45-8 Disperse Blue 106 12223-01-7 CAS No. EU Requirement: Regulation (EC) 1907/2006 Annex XVII; valid for adhesives and paints DE Requirement: ChemVerbotsV; valid for adhesives and paints CAS No. Toluene 108-88-3 52. Vinylchloride Limit, OTTO Group (): 1 mg/kg Limit, OTTO Group (articles with food contact): 0,01 mg/kg Limit, DE (commodities and toys): 1 mg/kg Limit, DE (articles with food contact): 0,01 mg/kg Test Method: in-house method, dissolve and suspend the sample in dimethylacetamide determination by means of headspace GC-MS EU Requirement: Regulation (EC) 1907/2006 Annex XVII: Products that contain vinylchloride as aerosol are not marketable DE Requirement: ChemverbotsV: Products that contain vinylchloride as aerosol are not marketable; BedGgstV: Limit (in commodities): 1 mg/kg; Limit (in commodities with food contact): 0,01 mg/kg Disperse Blue 124 61951-51-7 CAS No. Disperse Blue 3 2475-46-9 Vinylchloride 75-01-4 Disperse Orange 3 730-40-5 Disperse Orange 37 / 76 301-61-6 53. Global Migration Disperse Red 1 2872-52-8 Disperse Yellow 3 2832-40-8 Limit, EU: see below Solvent Yellow 1 60-09-3 Solvent Yellow 2 60-11-7 Test Method: 64 LFGB B 80.30-1/-2/-3 Solvent Yellow 3 97-56-3 EU Requirement (Plastic): Regulation (EC) No 10/2011 49. Monomers, migration DE Requirement (Plastic and Rubber): BedGgstV; BfR Recommendation XXI "Bedarfsgegenstände auf Basis von Natur und Synthesekautschuk" Limit, EU (toys): not detectable CH Requirement (Silicon): Switzerland: Directive 817.023.21 Limit Test Method: DIN EN 71-9 /-10 /-11 non-fillable articles 10 mg/dm 2 EU Requirement: Directive 88/378/EEC valid until July 20; Directive fillable articles 60 mg/kg 2009/48/EC valid from 2011/20 DE Requirement: ProdSG, LFGB 30. DIN EN 71-9 is not harmonized within all 54. Triclosan European countries. Though the German authorities observe the compliance with Limit, OTTO Group: not detectable DIN EN 71-9 / CAS No. Limit Limit, DE (articles with food contact): not detectable Acrylamide / 79-06-1 0,02 mg/l Test Method: Housemethod, Ultrasonic extraction with dichloro methane Styrol / 100-42-5 0,75 mg/l for 30 min at RT, detection with GC-MS Bisphenol A / 80-05-7 0,1 mg/l DE Requirement: BedGgstV Formaldehyde / 50-0-0 2,5 mg/l CAS No. Phenol / 108-95-2 15 mg/l Triclosan 3380-34-5 50. Tar oils 55. Volatile s Limit, EU: not detectable Test Method: in-house method, Ultrasonic extraction with toluene for 60 min at 60 Limit, OTTO Group (silicone with food contact): 0,5% Limit, DE (silicone with food contact): 0,5% C. Analytical determination is performed via GC-MS Test Method: Recommendation BfR No XV (Federal Institute of Risk EU Requirement: Regulation (EC) 1907/2006 Annex XVII Assessment) / DIN EN 14350-2 / DIN EN 14372 DE Requirement: Recommendation BfR No XV (Federal Institute of Risk Assessment) 51. Toluene EU-Requirement: EN 14372, Child use and care articles, baby cutlery and Limit, OTTO Group: consumer products Limit, EU: consumer products crockery; EN 14350-2, Child use and care articles, drinking equipment Limit, EU: 0,1% in adhesives and paints Test Method: in-house method, headspace (30 min at 110 C). GC-MS, Semiquantitative determination against d8-toluene
12 of Restricted s List (RSL) for Consumer Goods 56. Formamide New-P 60. Fastness to Saliva and Perspiration Limit, OTTO Group (puzzle mats): 200 mg/kg Limit, FR (puzzle mats): 200 mg/kg Limit, OTTO Group: see D Commentary Limit, CZ, DE (toys and baby products): Grade 5 Test Method: in-house method, Ultrasonic extraction in dichloro methane for 30 min at RT, detection with GC-MS FR Requirement: Order Official Gazette No. 181 (valid from 08.01.2012 until 07.31.20) puzzle mats of foam are not allowed to contain more than 200 mg/kg formamide. CAS No. Formamide 75-12-7 B Further Restricted Parameters For consumer products aside from hazardous substances there are some further legal parameters, which are not mentioned as legal in any further OTTO Group Document. Test Method (textile): DIN EN ISO 3071 Test Method (leather): DIN EN ISO 4045 CZ Requirement: Act No 84/2001: ph-value in toys and baby b products: textile 4,0-7,5; leather: 3,5-8,5 DE Requirement: EN 71-9 ph (in liquids for toys): 3,0-10,0 Test Method: DIN 53160; grade 5 = no staining / no colour change, grade 1 = very strong staining / very strong colour change (grey scale acc. to DIN EN 20105-A02; ISO 105-A02) DE Requirement: Recommendation of BfR XLVII (Federal Institute for Risk Assessment), valid for toys SK Requirement: Decree 635/2005 limit is valid for baby textiles with skin contact Grade Fastness to Saliva and Perspiration 61. Odour New-P Limit, OTTO Group (articles with food contact): Grade 2; (other articles): Grade 3 58. ph-value Limit, EU (articles with food contact): Grade 2 Limit, OTTO Group (toys and baby products): ph: 4,0-7,5 Test Method: in general DIN 10955; paper, cardboard: DIN EN 1230-1/-2 Limit, CZ (toys and baby products): ph: 4,0-7,5 Test Method: Acc. to SNV 195 651, testing conditions are chosen Limit, DE (in liquids for toys): 3,0-10,0 depending on the indicated use. 59. Colour fastness: rubbing, perspiration Limit, OTTO Group: see D Commentary Limit, CZ, SK (toys and baby products): see below Test Method: textiles: DIN EN ISO 105 X12, E01, E04; leather: DIN EN ISO 11640, dry: 50 cycles, wet and alcaline: 20 cycles; grade 5 = no staining / no colour change, grade 1 = very strong staining / very strong colour change (grey scale acc. to DIN EN 20105-A02; ISO 105-A02) CZ Requirement: Act No 84/2001: limits are valid for toys and baby products SK Requirement: Decree 635/2005 limits are valid for textiles with skin contact Marks : * valid for textiles and leather, ** valid for textiles only in Czech Republic Parameter CZ: Spielzeug und Kinderprodukte / Note Parameter 4 * rubbing dry 3 * rubbing wet 3-4 ** Parameter SK: Textilien mit Hautkontakt / Note Parameter 3-4 rubbing dry 2-3 rubbing wet 3 EU Requirement: Regulation (EC) No 1935/2004, odour and taste: grade 2 DE Requirement: LFGB 31, odour and taste: grade 2 5 62. Polyvinyl chloride PVC Limit, OTTO Group: no use Limit, EU: consumer products Test Method: Beilstein / FTIR: Chlorinated synthetics on a copper wire show a green light in a flame. For a clear identification, an infrared spectrum (FTIR) is performed.
of Restricted s List (RSL) for Consumer Goods C REACH In case of contents > 0,1% per article weight substances of very high concern (SVHC) from the REACH candidate list, the supplier is legally obligated to transmit the information (Regulation (EC) 1907/2006 Art. 33 and Annex XIV). SVHC-s, see http://echa.europa.eu/chem_data/authorisation_process/candidate_list_t able_en.asp. D Commentary This document lists the legal requirements of the EU regarding chemical substances in as well as those national requirements which are different from the EU. Aside from the 28 EU countries Norway and Switzerland are considered. For some parameters - mainly those that are are not regulated clearly by the EU Law - a specific OTTO Group limit value is defined. E Country Abbreviations This document consideres the following countries: EU-Member States EU-Member AT Austria LT Lithuania BE Belgium LU Luxembourg BG Bulgaria MT Malta CY Cyprus NL Netherlands CZ Czech Rep. PL Poland DK Denmark PT Portugal EE Estonia RO Romania FI Finland SK Slovakia FR France SI Slovenia DE Germany ES Spain GR Greece SE Sweden HR Croatia UK United Kingdom HU Hungary IE Ireland Non-EU-Member IT Italy NO Norway LV Latvia CH Switzerland The OTTO Group limits are definitely obligatory just as the legal limits are. In contrast to the OTTO Group limits the legal requirements referring to are marked with a red line on the left side. s, that were not listed in the last version are marked with New- P (= new parameter) Limits, that were not included in the last version are marked with New-L (= new parameter ) and all other changes with black line on the right side. For certain product groups additional documents are valid in the OTTO Group, which are also to be used in its assessment. Doc. No. 01-20351 Chemical Requirements for Garments, Home Textiles, and Beddings Doc No. 01-20352 Chemical Requirements for Shoes and Bags Doc. No. 01-20353 Chemical Requirements for Jewellery This list is not intended to be exhaustive.