FISCHER-TROPSCH SYNTHETIC FUEL EVALUATIONS HMMWV TEST TRACK EVALUATION

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ADA FISCHER-TROPSCH SYNTHETIC FUEL EVALUATIONS HMMWV TEST TRACK EVALUATION INTERIM REPORT TFLRF No. 4 by Gregory Hansen Edwin A. Frame U.S. Army TARDEC Fuels and Lubricants Research Facility Southwest Research Institute (SwRI ) San Antonio, TX by Eric Sattler for U.S. Army RDECOM - TARDEC Force Projection Technologies Warren, Michigan Contract No. DAAE-7-99-C-L53 (WD23) Approved for public release: distribution unlimited September 29

Disclaimers The findings in this report are not to be construed as an official Department of the Army position unless so designated by other authorized documents. Trade names cited in this report do not constitute an official endorsement or approval of the use of such commercial hardware or software. DTIC Availability Notice Qualified requestors may obtain copies of this report from the Defense Technical Information Center, Attn: DTIC-OCC, 8725 John J. Kingman Road, Suite 944, Fort Belvoir, Virginia 226-6218. Disposition Instructions Destroy this report when no longer needed. Do not return it to the originator.

FISCHER-TROPSCH SYNTHETIC FUEL EVALUATIONS HMMWV TEST TRACK EVALUATION INTERIM REPORT TFLRF No. 4 By Gregory Hansen Edwin A. Frame U.S. Army TARDEC Fuels and Lubricants Research Facility Southwest Research Institute (SwRI ) San Antonio, TX by Eric Sattler for U.S. Army RDECOM - TARDEC Force Projection Technologies Warren, Michigan Contract No. DAAE-7-99-C-L53 (WD23) SwRI Project No. 8.3227.23.82 Approved for public release: distribution unlimited September 29 Approved by: Steven D. Marty, Director U.S. Army TARDEC Fuels and Lubricants Research Facility (SwRI )

REPORT DOCUMENTATION PAGE Form Approved OMB No. 74-188 Public reporting burden for this collection of information is estimated to average 1 hour per response, including the time for reviewing instructions, searching existing data sources, gathering and maintaining the data needed, and completing and reviewing this collection of information. Send comments regarding this burden estimate or any other aspect of this collection of information, including suggestions for reducing this burden to Department of Defense, Washington Headquarters Services, Directorate for Information Operations and Reports (74-188), 1215 Jefferson Davis Highway, Suite 124, Arlington, VA 2222-432. Respondents should be aware that notwithstanding any other provision of law, no person shall be subject to any penalty for failing to comply with a collection of information if it does not display a currently valid OMB control number. PLEASE DO NOT RETURN YOUR FORM TO THE ABOVE ADDRESS. 1. REPORT DATE (DD-MM-YYYY) 3. DATES COVERED (From - To) 2. REPORT TYPE Final Interim Report 24-9-29 4. TITLE AND SUBTITLE Fischer-Tropsch Synthetic Fuel Evaluations HMMWV Test Track Evaluation January 29 September 29 5a. CONTRACT NUMBER DAAE7-99-C-L53 5b. GRANT NUMBER 5c. PROGRAM ELEMENT NUMBER 6. AUTHOR(S) Hansen, Gregory and Frame, Edwin 5d. PROJECT NUMBER SwRI 8.3227.23.82 5e. TASK NUMBER WD 23, Task XI 5f. WORK UNIT NUMBER 7. PERFORMING ORGANIZATION NAME(S) AND ADDRESS(ES) 8. PERFORMING ORGANIZATION REPORT NUMBER U.S. Army TARDEC Fuels and Lubricants Research Facility (SwRI ) Southwest Research Institute P.O. Drawer 2851 San Antonio, TX 78228-51 TFLRF No. 4 9. SPONSORING / MONITORING AGENCY NAME(S) AND ADDRESS(ES) 1. SPONSOR/MONITOR S ACRONYM(S) U.S. Army RDECOM U.S. Army TARDEC Force Projection Technologies Warren, MI 48397-5 12. DISTRIBUTION / AVAILABILITY STATEMENT Approved for public release; distribution unlimited 13. SUPPLEMENTARY NOTES 11. SPONSOR/MONITOR S REPORT NUMBER(S) 14. ABSTRACT This report compares the results of running a HMMWV on four different fuels. Evaluation criteria includes; fuel economy, emissions, vehicle performance, and engine wear. The fuels involved are ULSD, JP8, Synthetic Fischer-Tropsch S8, and a 5/5 blend of JP8 and the Synthetic Fuel. 15. SUBJECT TERMS Jet Fuel Synthetic Fuel Acceleration Vehicle Performance HMMWV Fischer-Tropsch JP-8 USLD Fuel Economy 16. SECURITY CLASSIFICATION OF: 17. LIMITATION OF ABSTRACT a. REPORT b. ABSTRACT c. THIS PAGE Unclassified Unclassified 18. NUMBER OF PAGES Unclassified Unclassified 58 19a. NAME OF RESPONSIBLE PERSON 19b. TELEPHONE NUMBER (include area code) Standard Form 298 (Rev. 8-98) Prescribed by ANSI Std. Z39.18 iv

EXECUTIVE SUMMARY This test utilizes a HMMWV in comparing four different fuels. Evaluation criteria include fuel economy, emissions, vehicle performance, and engine wear. In general, when the HMMWV was running on DF-2 fuel, performance characteristics were the highest, emissions levels were the highest, and fuel economy was the highest. On the other end of the spectrum was the Fischer- Tropsch S-8 fuel. HMMWV performance with S-8 or the fuel blend was reduced in comparison to DF-2. Fuel economy suffered, largely in part to a decreased volumetric energy density, and different combustion characteristics. However, emissions levels were lower for S-8 fuel than any of the others. Again, speaking generally, the 5/5 blend of JP-8 and S-8 vehicle performance and other characteristics fell in the middle of the JP-8 and S-8 fuels. v

FOREWORD/ACKNOWLEDGMENTS The U.S. Army TARDEC Fuel and Lubricants Research Facility (TFLRF) located at Southwest Research Institute (SwRI), San Antonio, Texas, performed this work during the period of January 29 through September 29 under Contract No. DAAE-7-99-C-L53. The U.S. Army Tank-Automotive RD&E Center, Force Projection Technologies, Warren, Michigan administered the project. Mr. Luis Villahermosa (AMSRD-TAR-D/MS11) served as the TARDEC contracting officer s technical representative. Ms. Pat Muzzell and Mr. Eric Sattler of the U.S. Army National Automotive Center served as project technical monitors. The authors would also like to recognize the contribution of Jeff Sellers for his technical support and dedication. Finally, thanks to the administrative and report-processing support provided by Dianna Barrera. vi

TABLE OF CONTENTS Section Page EXECUTIVE SUMMARY... v FOREWORD/ACKNOWLEDGMENTS... vi LIST OF TABLES... viii LIST OF FIGURES... viii ACRONYMS AND ABBREVIATIONS... IX 1. Background and Objectives... 1 Background... 1 Objectives... 1 Approach... 1 2. Test Evaluation... 1 Fuels... 1 Equipment... 2 Equipment Preparation... 3 Test Procedure... 4 Test Route... 5 3. Discussion of Results and Comparisons... 6 Economy... 6 Acceleration... 9 Emissions and Smoke... 1 Start Times... 13 Oil Analysis... 14 4. Conclusions... 15 5. Recommendations... 15 APPENDIX VIDEO Testing of HMMWV Fuel Comparison Use the following link to access the video: http://www.swri.org/4org/d2/reports/misc/hmmwvfuelcomp.wmv vii

Table LIST OF TABLES Page Table 1. Fuel Properties for ULSD, JP8, 5/5 Blend, and S8... 2 Table 2. Indicated Fuel Economy Data... 7 Table 3. Comparison of Indicated Fuel Economy... 7 Table 4. 1 Mile Engine Operation Summary Data... 8 Table 5. 5 Run Averaged Acceleration Data... 9 Table 6. Comparison of Averaged Acceleration Data... 9 Table 7. 5 Run Averaged Emissions Data... 11 Table 8. Comparison of the 5 Run Averaged Emissions Data... 11 Table 9. 3 Run Averaged Smoke Data... 12 Table 1. Indicated Start Times... 13 Table 11. Results of Oil Analysis... 14 Figure LIST OF FIGURES Page 1. HMMWV Used for Testing... 3 2. Ballast on Front and Rear of the HMMWV... 3 3. Some Instrumentation on the HMMWV... 4 4. Driving Route on SwRI Campus... 5 5. Elevation Change of Driving Route on SwRI Campus... 6 6. Time Resolved Example Data: Showing 1 Miles of Driving on S8 Fuel with the HMMW Ballasted to1,3 Lbs... 8 7. Time Resolved Example Data: Showing the 5 Run Average Acceleration Data from Driving on S8 Fuel with the HMMWV Ballasted to 1,3 Lbs... 1 8. Time Resolved Example Data: Showing the 5 Run Average Emissions Data from Driving on S8 Fuel with the HMMWV Ballasted to 1,3 Lbs... 12 9. Time Resolved Example Data: Showing the Starter Voltage Data from Running on S8 Fuel... 13 viii

ACRONYMS AND ABBREVIATIONS % Percent C Degrees centigrade F Degrees Fahrenheit @ At ASTM American Society for Testing and Materials bhp Brake horsepower BTU British thermal units cc cubic centimeter cm centimeter CO Carbon monoxide cst Centistokes deg degree DOD Department of Defense FBP Final boiling point FTM Federal Test Method FTP Federal Test Procedure g/kw-h Grams per kilowatt-hour g/mi Grams per mile GEP General Engine Products GFM Government furnished equipment GVW Gross Vehicle Weight HC Hydro-Carbon HFRR High-frequency reciprocating rig Hr Hour HMMWV High Mobility Medium Wheeled Vehicle IBP Initial boiling point Kg Kilo-gram L Liter Lbs Pounds Max Maximum mg Milligram mg/l Milligrams per liter mgkoh/g Milligrams potassium hydroxide per gram of sample Min Minimum MJ/Kg Megajoules per kilogram ml Milliliter mm Millimeter mmhg Millimeters of mercury MPG Miles per gallon N No NOx Oxides of nitrogen NR Not required oz Ounce PM Particulate matter ppm Parts per million ix

psi pounds per square inch RPM Revolutions per minute S, sec Seconds SLBOCLE Scuffing load ball on cylinder lubricity evaluator SPK Synthetic Paraffinic Kerosene STDEV Standard deviation SwRI Southwest Research Institute TFLRF U.S. Army TARDEC Fuels and Lubricants Research Facility THC Total hydrocarbons ULSD Ultra-Low Sulfur Diesel um micrometer V Voltage WOT Wide open throttle Wt. Weight Y Yes x

1. BACKGROUND AND OBJECTIVES BACKGROUND Fischer-Tropsch (F-T) process synthetic fuels, first produced in 1927, were used by WWII Germany, and by South Africa during their embargoed period, to overcome petroleum shortages. Synthetic JP-8 is a clean fuel that contains no sulfur or aromatics, but has historically cost too much to compete with petroleum fuel. Since the mid-199s, the world's major energy companies have begun developing updated F-T processes that are less expensive to build and operate. However, synthetic fuel chemistry differs significantly from petroleum fuels since F-T synthetic fuels are free of aromatic and sulfur compounds. The U.S. Military needs to understand the extent and nature of these differences and the implications regarding current and future military use. There will be some subtle and not so subtle changes in fuel compositions and associated physicochemical properties that can impact engine performance and durability. The U.S. Army Synthetic fuels project will involve assessments of the impacts that varying fuel properties may have on current and future military equipment and systems. OBJECTIVES This test will specifically measure the performance, emissions, fuel economy, and compare engine wear for four (4) different fuels. APPROACH A HMMWV will be instrumented and run in field-like conditions. With 2 miles being accumulated on each of the four (4) fuels. The HMMWV will also be evaluated on a test track for repeatable performance data. 2. TEST EVALUATION FUELS The four (4) fuels are: DF-2 ULSD, JP-8, F-T S-8 [SPK], 5/5 (volume) Blend of S-8 and JP-8. The fuel properties are found in Table 1. 1

Table 1. Fuel Properties for ULSD, JP-8, 5/5 Blend, and S-8 Property ASTM D DF 2 JP 8 5/5 Blend S 8 w/ 22.5 ppm w/ 22.5 ppm Description ULSD Age DCI 4a DCI 4a Refining lubricity lubricity enhancer enhancer Density @ 15 C [kg/l].8556.7931.7739.7554 452 API Gravity @ 15 C 34.2 47.4 51.3 55.8 TAN [mg KOH/g] 3242.1.1 <.1 Aromatics [vol %] 1319 28.1 15.2 8.5 Total Sulfur [ppm] see note 8¹ 9² 38² <1³ Distillation [deg C @ vol %] IBP 172 144 149 165 1 215 164 164 173 2 228 17 168 176 5 86 264 192 195 25 9 317 245 249 256 FBP 346 265 271 277 residue 1.1 1.5 1.5 1.6 loss 2.8 1.3 1.1 1.2 Viscosity @ 4 C [cm^2/s] 445 2.6 1.1 1.21 1.35 Net Heat of Combustion [BTU/Lb] 3338 18,425 18,663 18,87 18,975 Hydrogen Content [mass %] 3343 13.37 14.6 14.65 15.37 Cetane Number 613 47.5 46. 53. 62.7 Calculated Cetane Index 4737 46.1 45. 55.3 64.4 BOCLE [mm] 51.67.48.5.56 HFRR [um] 679 61 72 723 819 ¹ ASTM D5453 ² ASTM D2622 ³ ASTM D3227 EQUIPMENT Test vehicle: GFE HMMWV (See Figure 1) S/N: 1829 Year: 1998 Engine: GEP 6.5L V8 Diesel, naturally aspirated Driveline: 4-speed transmission, 2-speed transfer case 2

Measurement Devices: AVL smoke meter Cambell Data Acquisition for engine operating conditions Daytron Data Aacquision for vehicle dynamics Sensors Inc. Portable Emissions Monitoring System Figure 1. HMMWV Used for Testing EQUIPMENT PREPARATION Figure 2. Ballast on Front and Rear of the HMMWV 3

The HMMWV was modified to accept the PEMS unit on the exhaust. A rack was installed in the bed of the HMMWV to accept concrete ballast. To maintain even weight distribution a rack for additional weights was installed on the front bumper; see Figure 2. The remaining data acquisition systems were installed as appropriate; see Figure 3. Not all of the measurement systems were on the vehicle during each phase of the test. The vehicle s power system and available space were constraints that limited the use of the measurement systems. Figure 3. Some Instrumentation on the HMMWV TEST PROCEDURE The test plan followed this generalized format: Fill with test fuel Drive 1 miles unballasted Measure fuel consumed Perform acceleration tests with emissions unballasted Ballast to 1,3 Lbs 4

Perform acceleration tests with emissions Perform engine start tests [beginning of day for consistency] Refill with test fuel Drive 1 miles ballasted Measure fuel consumed Perform smoke tests Take oil samples Repeat TEST ROUTE The test route is shown in red [with number markers] on Figure 4. The vehicle starts the 1 mile segment from the fleet lab. The vehicle drives to the test track [marker 2] and performs 8 laps. The vehicle then follows the route [numbers 4 through 8] in order. The route continues from marker 8 to marker 1 and on until the 1 miles is completed. Figure 4. Driving Route on SwRI Campus 5

84 Elevation of Route 82 Elevation [feet] 8 78 76 74 72 1 2 3 4 5 6 7 8 Distance [miles] Figure 5. Elevation Change of Driving Route on SwRI Campus Marker 2 on the aerial map [mile 2 on Figure 4] indicates the test track. During actual testing the vehicle performed eight laps on the test track every time around the course. The elevation change was as large as possible while still staying on SwRI campus, see Figure 5 above. 3. DISCUSSION OF RESULTS AND COMPARISONS The first S-8 run will not be included because the data is not consistent. There was a learning curve in operating this test. The average MPH was a little low, so the driver was instructed to increase speed around the paved test track (from 4 to 45 MPH). This caused a change in the fuel economy. The video and photography also interfered with the fuel economy as the vehicle was idling and/or off for some time during the scheduled 1 mile accumulation periods. Furthermore, the test was initiated before the reconditioning of the procured smoke meter was finished. This precluded gathering smoke samples from the first S-8 testing period. ECONOMY The fuel density was measured according to ASTM D452. 6

Table 2. Indicated Fuel Economy Data Fuel Type Ballasted to GVW (Y/N) Miles Weight Consumed lbs Fuel Density kg/l MPG S8* N 1 51.3.7554 12.29 S8 Y 1 64.3.7554 9.8 DF2 N 1 57.5.8556 12.42 DF2 Y 1 64..8556 11.16 JP8 N 1 55.8.7931 11.86 JP8 Y 1 67.6.7931 9.79 5/5 N 1 55.5.7739 11.64 5/5 Y 1 6.8.7739 1.62 S8 N 1 58.71.7554 1.74 S8 Y 1 61.9.7554 1.18 * track speed limit 5 mph less than all other tests The fuel economy results seen in Table 2, show decreased values starting with DF2 and ending with S-8. This correlates well with expected results based on fuel energy density, cetane number, and viscosity differences among the fuel types. For comparison it is useful to look at the percent difference between the average MPG and other engine operating parameters for each 1 mile segment, as shown in Table 3 and 4. Table 3. Comparison of Indicated Fuel Economy Ballasted to Fuel Type GVW (Y/N) MPG % Change with JP8 as a Baseline % Change with DF2 as Baseline Average MPH DF2 N 12.42 4.5% n/a 27.73 DF2 Y 11.16 13.9% n/a 26.12 JP8 N 11.86 n/a 4.5% 27.52 JP8 Y 9.79 n/a 12.2% 25.13 5/5 N 11.64 1.9% 6.3% 26.27 5/5 Y 1.62 8.5% 4.8% 26.44 S8 N 1.74 9.5% 13.5% 26.28 S8 Y 1.18 4.% 8.7% 26.87 If JP-8 is a baseline fuel for comparison, the S-8 lost up to 9.5% fuel economy. 7

Table 4. 1 Mile Engine Operation Summary Data Averages Ballasted Oil Sump Coolant Out Ambient Fuel Type (Y/N) Miles Temp F Temp F Temp F RPM DF2 N 1 184. 2. 77.3 1487 DF2 Y 1 176.5 199.9 73.7 1446 JP8 N 1 175. 197.9 68. 1452 JP8 Y 1 171.4 198. 68.8 1431 5/5 N 1 177.6 197.7 71.7 1397 5/5 Y 1 186. 2.8 93.2 1443 S8 N 1 18.2 199.2 73.3 148 S8 Y 1 178.6 199.9 8.1 1479 There is, however, no single measured variable responsible for the observed fuel economy differences 22 S8 Ballasted Engine Data 1 miles 38 2 18 16 14 33 28 23 Oil Sump Temp F Coolant Out Temp F Ambient Temp F MPH RPM MPH, deg F 12 1 Break for Lunch 18 RPM 8 13 6 8 4 2 3 2 8:5 AM 8:22 AM 8:39 AM 8:57 AM 9:14 AM 9:31 AM 9:48 AM 1:6 AM 1:23 AM 1:4 AM 1:58 AM 11:15 AM 11:32 AM 11:49 AM 12:7 PM 12:24 PM 12:41 PM 12:59 PM 1:16 PM Figure 6. Time Resolved Example Data: Showing 1 Miles of Driving on S8 Fuel with the HMMWV Ballasted to 1,3 Lbs Figure 6 shows vehicle operating conditions for one day, or 1 miles of testing. The data presented is for the S-8 fuel with the vehicle ballasted. 8

ACCELERATION The ½ mile test track has an approximate 1 percent slope from beginning to end. This accounts for the uphill/downhill distinction seen in the reported performance and emissions. Table 5 consists of 5 runs in each direction and the averages of each run, from to 5 MPH, are presented. Table 5. 5 Run Averaged Acceleration Data Acceleration to 5 MPH DF2 JP8 5/5 S8 Uphill 22.1 28.5 3.9 33.8 Ballasted Downhill 2.3 23.8 28.9 29.4 Uphill 15.1 16.1 18.5 18.1 Empty Downhill 13.6 14.7 17. 16.7 Uphill 157 1388 1515 1671 Ballasted Downhill 988 1153 1438 1469 Uphill 78 756 887 845 Empty Downhill 645 687 814 791 Uphill 3.31 2.57 2.37 2.17 Ballasted Downhill 3.62 3.8 2.54 2.49 Uphill 4.37 3.93 3.67 3.51 Empty Downhill 4.64 4.32 3.71 3.79 Average Time [seconds] Average Distance [feet] Average Acceleration [ft/s^2] The data may also be seen in Table 6, with JP-8 as a baseline for easy comparison. A positive percentage value means: a faster time, a shorter distance, and a larger acceleration. Table 6. Comparison of Averaged Acceleration Data Acceleration to 5 MPH DF2 JP8 5/5 S8 Uphill 22.3%.% 8.4% 18.4% Ballasted Downhill 15.%.% 21.4% 23.6% Average Time Uphill 6.6%.% 14.5% 12.3% Empty Downhill 7.8%.% 15.9% 13.9% Uphill 23.8%.% 9.1% 2.3% Ballasted Average Downhill 14.3%.% 24.7% 27.4% Distance Uphill 6.4%.% 17.3% 11.8% Empty Downhill 6.1%.% 18.4% 15.1% Uphill 28.6%.% 7.8% 15.5% Ballasted Average Downhill 17.4%.% 17.7% 19.1% Acceleration Uphill 11.2%.% 6.6% 1.6% Empty Downhill 7.4%.% 14.% 12.3% 9

Consistent trends come from the HMMWV configuration running uphill and ballasted. With JP-8 as the baseline for this configuration, vehicle performance was degraded up to 9% running on the 5/5 blend and up to 2% running the full S-8. The most telling data of all is the 58% increase in distance traveled from to 5 MPH if the vehicle is ballasted, running uphill, and the fuels compared are DF2 and S-8. 55 S8 Ballasted to 5 MPH 18 5 16 MPH and acceleration [ft/s^2] 45 4 35 3 25 2 15 1 5 MPH up MPH down Accel up Accel down Dist up Dist down 14 12 1 8 6 4 2 distance [feet] 2 4 6 8 1 12 14 16 18 2 22 24 26 28 3 32 34 time [sec] Figure 7. Time Resolved Example Data: Showing the 5 Run Average Acceleration Data from Driving on S8 Fuel with the HMMWV Ballasted to 1,3 Lbs Figure 7 shows the time resolved vehicle dynamics from two 5 run averages accelerating from to 5 MPH. The vehicle configuration is ballasted and running S-8 fuel. EMISSIONS AND SMOKE Emissions data are presented from the acceleration runs of to 5 MPH in Table 7. 1

Table 7. 5 Run Averaged Emissions Data Emissions to 5 MPH DF2 JP8 5/5 S8 Uphill 166.2 146. 133. 121.6 Ballasted Downhill 175.2 145. 134. 124.9 Uphill 193.5 85.5 147.8 165.5 Empty Downhill 189.5 131.8 153.5 167.1 Uphill 449.3 446.8 328.1 296.2 Ballasted Downhill 454.2 443.4 329.4 294.6 Uphill 453.6 456.5 324.1 297.6 Empty Downhill 46. 459.7 318.3 296.6 Uphill 6.2 8.1 16.6 12.2 Ballasted Downhill 9.2 9.5 14.5 11.4 Uphill 11.3 17.9 25.1 18.4 Empty Downhill 1.4 13.6 23.8 12.7 Average CO [ppm] Average NOx [ppm] Average HC [ppm] Emissions quality generally improves when moving to the S-8 fuel. Again it is useful to look at the data on an improvement basis with JP-8 as a baseline, as shown in Table 8. A positive percentage indicates a lower emissions level. Table 8. Comparison of the 5 Run Averaged Emissions Data Emissions to 5 MPH DF2 JP8 5/5 S8 Average CO Uphill 13.8%.% 8.9% 16.7% Ballasted Downhill 2.8%.% 7.6% 13.8% Uphill 126.5%.% 72.9% 93.7% Empty Downhill 43.8%.% 16.5% 26.8% Average NOx Uphill.6%.% 26.6% 33.7% Ballasted Downhill 2.4%.% 25.7% 33.6% Uphill.7%.% 29.% 34.8% Empty Downhill.1%.% 3.8% 35.5% Average HC Uphill 23.4%.% 16.4% 51.7% Ballasted Downhill 2.7%.% 53.1% 19.7% Uphill 36.6%.% 4.5% 2.8% Empty Downhill 23.5%.% 75.1% 6.7% 11

CO, NOx [ppm] 425 4 375 35 325 3 275 25 225 2 S8 Ballasted Emissions CO Up CO Down NOx Up NOx Down HC Up HC Down 4 35 3 25 2 15 HC [ppm] 175 15 1 125 1 5 75 2 4 6 8 1 12 14 16 18 2 22 24 26 28 3 32 34 time [sec] Figure 8. Time Resolved Example Data: Showing the 5 Run Average Emissions Data from Driving on S8 Fuel with the HMMWV Ballasted to 1,3 Lbs Figure 8 shows the time resolved emissions from two 5 run averages accelerating from to 5 MPH. The vehicle configuration is ballasted and running S-8 fuel. The smoke data is presented, in Table 9, on a volumetric basis for ease of comparison. The measurements were made by the AVL smoke meter by sampling the exhaust gas for a specific length of time and then reading the sample according to the Bosch smoke procedure. The values presented represent the average of 3 runs at each condition. For the first condition, the HMMWV engine was on and the transmission was in neutral. For the second condition, the HMMWV was traveling at a constant 3 MPH in high gear. For the third condition, the smoke sample was taken while the vehicle was accelerating under WOT from to 5 MPH. The fourth condition shows the bias with the engine off. Table 9. 3 Run Averaged Smoke Data Average Smoke [mg/m^3] Ballasted DF2 JP8 5/5 S8 Idle.54 1.29.85.74 3 MPH 2.25 2.83 2.44 2.26 WOT to 5 35.91 9.7 9.48 6.85 Off.14.8.1.6 12

Overall the S-8 showed slightly less smoke than the JP8, while the DF2 showed a high volume of smoke. START TIMES The cold start times are one measurement, not an average. They were performed at the beginning of the day to ensure consistency, as shown in Table 1. The hot start times were performed after the engine oil was brought up to operating temperature. Table 1. Indicated Start Times Start Time [seconds] Hot Cold DF2 JP8 5/5 S8.4.4.6.5.65.8.8 1. Generally the S-8 showed longer start times than the JP-8 or DF2. 24 S8 Engine Crank Test Starter Voltage [V] 2 16 12 8 Engine Hot Engine Cold 4.5 1 1.5 2 2.5 3 3.5 4 4.5 5 Time [sec] Figure 9. Time Resolved Example Data: Showing the Starter Voltage Data from Running on S8 Fuel Figure 9 shows the time resolved starter voltage for the hot and cold engine conditions. The vehicle is running S-8 fuel. 13

OIL ANALYSIS The oil analysis, as seen in Table 11 shows essentially no differences in engine wear or oil degradation. There was no measurable fuel dilution, or soot dilution. The key wear metals showed no more than a single digit increase. Finally, the oil s acid number showed no increase. Table 11. Results of Oil Analysis New Oil DF-2 JP-8 5/5 S-8 ASTM D3524M Fuel Dilution Diesel (wt.%) NA <.3 <.3 <.3 <.3 ASTM D445 Viscosity @ 1 C (cst) 14.62 14.5 14.38 14.39 14.4 ASTM D445 Viscosity @ 4 C (cst) 11.3 19.2 18.34 18.5 18.28 ASTM D4739 Total Base Number Inflection Point (mg KOH/g) 8.36 7.85 8.17 8.43 8.64 ASTM D4739 Total Base Number Buffer Point (mg KOH/g) 8.31 7.78 7.88 8.17 9.2 ASTM D5185 Elemental Analysis (ppm) Aluminum (Al) <1 1 1 1 1 Antimony (Sb) <1 <1 <1 <1 <1 Barium (Ba) <1 <1 <1 <1 <1 Boron (B) 5 3 4 3 4 Calcium (Ca) 2595 2659 2719 2689 268 Chromium (Cr) <1 <1 <1 <1 <1 Copper (Cu) <1 <1 <1 <1 <1 Iron (Fe) 2 6 6 4 4 Lead (Pb) <1 <1 <1 <1 <1 Magnesium (Mg) 12 8 14 1 12 Manganese (Mn) <1 <1 <1 <1 <1 Molybdenum (Mo) 2 2 3 2 2 Nickel (Ni) <1 <1 <1 <1 <1 Phosphorus (P) 154 149 156 142 136 Silicon (Si) 4 2 5 3 3 Silver (Ag) <1 <1 <1 <1 <1 Sodium (Na) 6 5 5 5 5 Tin (Sn) <1 <1 <1 <1 <1 Zinc (Zn) 1191 1212 1225 126 123 Potassium (K) 6 5 7 6 6 Strontium (Sr) <1 <1 <1 <1 <1 Vanadium (V) <1 <1 <1 <1 <1 Titanium (Ti) <1 <1 <1 <1 <1 Cadmium (Cd) <1 <1 <1 <1 <1 ASTM D664 Total Acid Number Buffer Point (mg KOH/g) 2.2 1.99 2.14 2.16 2.19 TGA Soot (wt.%).125.136.19.19.159 14

4. CONCLUSIONS When JP-8 is used as a baseline for comparison, the S-8 fuel performed worse in vehicle dynamics, but performed better in emissions. The results of the 5/5 blend of JP8 and S-8 fell right in between the results of the 2 constituent fuels. The engine oil tests showed no significant wear during the 2+ miles of testing. In total the HMMWV accumulated 1652 miles. Only 1 of those miles are accounted for by the fuel economy testing. The remaining 652 miles largely consisted of the acceleration tests which may be characterized by WOT engine operation and hard braking. The fuel pump was analyzed by a local calibration facility. As a result of the testing, the pump showed very little wear. This is the reason the calibration tables were not included in the body of the report. The pump calibration tables are found in the appendix. 5. RECOMMENDATIONS TLFRF staff is very confident in the vehicle performance and emissions data. The cold start and hot start data cannot be interpreted with a high level of confidence, since there is only one data point per fuel used. If a more confident data set is required a specialized set of cold start tests is recommended. Similarly, the fuel economy can only be viewed as an indication of results. Repeatability is required for fuel economy comparison, and the scope of this test did not include repeated 1 mile fuel economy segments. Longer term effects of S-8 fuel use should be investigated. 15

APPENDIX A Fischer Tropsch Synthetic Fuels Evaluations HMMV Test Track Evaluation Work Directive No. 23, Task XI 1 Mile Data Plots Conducted for U.S. Army TARDEC Force Projection Technologies Warren, Michigan 48397 5

22 DF2 Ballasted Engine Data 1 miles 34 2 32 3 18 28 MPH, deg F 16 14 12 1 8 Oil Sump Temp F Coolant Out Temp F Ambient Temp F MPH RPM 26 24 22 2 18 16 14 12 6 4 1 8 6 2 4 2 8:42:43 AM 9:: AM 9:17:17 AM 9:34:34 AM 9:51:5 AM 1:9:7 AM 1:26:24 AM 1:43:41 AM 11::58 AM 11:18:14 AM 11:35:31 AM 11:52:48 AM 12:1:5 PM 12:27:22 PM 12:44:38 PM 1:1:55 PM 1:19:12 PM 1:36:29 PM 1:53:46 PM 2:11:2 PM RPM A-1

MPH, deg F 22 2 18 16 14 12 1 8 6 4 2 DF2 Un Ballasted Engine Data 1 miles Oil Sump Temp F Coolant Out Temp F Ambient Temp F MPH RPM 34 32 3 28 26 24 22 2 18 16 14 12 1 8 6 4 2 12:43:12 PM 1::29 PM 1:17:46 PM 1:35:2 PM 1:52:19 PM 2:9:36 PM 2:26:53 PM 2:44:1 PM 3:1:26 PM 3:18:43 PM 3:36: PM 3:53:17 PM RPM 4:1:34 PM 4:27:5 PM A-2

MPH, deg F 22 2 18 16 14 12 1 8 6 4 2 JP8 Ballasted Engine Data 1 miles Oil Sump Temp F Coolant Out Temp F Ambient Temp F MPH RPM 34 32 3 28 26 24 22 2 18 16 14 12 1 8 6 4 2 7:4 AM 7:58 AM 8:15 AM 8:32 AM 8:49 AM 9:7 AM 9:24 AM 9:41 AM 9:59 AM 1:16 AM 1:33 AM 1:5 AM 11:8 AM 11:25 AM 11:42 AM 12: PM 12:17 PM 12:34 PM 12:51 PM 1:9 PM RPM 1:26 PM 1:43 PM A-3

JP8 Un Ballasted Engine Data 1 miles 22 34 2 32 3 18 28 16 Oil Sump Temp F Coolant Out Temp F 26 24 14 12 1 22 2 18 16 14 8 12 6 1 8 4 6 2 4 2 8:9 AM 8:26 AM 8:44 AM 9:1 AM 9:18 AM 9:36 AM 9:53 AM 1:1 AM 1:27 AM 1:45 AM 11:2 AM 11:19 AM 11:36 AM 11:54 AM 12:11 PM 12:28 PM 12:46 PM 1:3 PM 1:2 PM 1:37 PM MPH, deg F Ambient Temp F MPH RPM RPM A-4

5/5 Blend Ballasted Engine Data 1 miles 22 34 2 32 3 MPH, deg F 18 16 14 12 1 8 Oil Sump Temp F Coolant Out Temp F Ambient Temp F MPH RPM 28 26 24 22 2 18 16 14 12 6 1 8 4 6 2 4 2 12:43 PM 1: PM 1:17 PM 1:35 PM 1:52 PM 2:9 PM 2:26 PM 2:44 PM 3:1 PM 3:18 PM 3:36 PM 3:53 PM 4:1 PM 4:27 PM 4:45 PM RPM A-5

5/5 Blend Un Ballasted Engine Data 1 miles 22 34 2 32 3 18 28 16 14 12 1 8 26 24 22 2 18 16 14 12 6 4 1 8 6 2 4 2 8:31 AM 8:48 AM 9:5 AM 9:23 AM 9:4 AM 9:57 AM 1:14 AM 1:32 AM 1:49 AM 11:6 AM 11:24 AM 11:41 AM 11:58 AM 12:15 PM 12:33 PM 12:5 PM 1:7 PM MPH, deg F 1:24 PM 1:42 PM Oil Sump Temp F Coolant Out Temp F Ambient Temp F MPH RPM RPM A-6

22 S8 Ballasted Engine Data 1 miles 34 2 32 3 18 28 16 26 24 14 12 1 8 22 2 18 16 14 12 6 1 8 4 6 2 4 2 8:5 AM 8:22 AM 8:39 AM 8:57 AM 9:14 AM 9:31 AM 9:48 AM 1:6 AM 1:23 AM 1:4 AM 1:58 AM 11:15 AM 11:32 AM 11:49 AM 12:7 PM 12:24 PM 12:41 PM MPH, deg F 12:59 PM 1:16 PM Oil Sump Temp F Coolant Out Temp F Ambient Temp F MPH RPM RPM A-7

S8 Un Ballasted Engine Data 1 miles 22 34 2 32 3 18 28 16 26 24 14 22 12 1 8 2 18 16 14 12 6 1 8 4 6 2 4 2 9:5 AM 1:7 AM 1:24 AM 1:42 AM 1:59 AM 11:16 AM 11:34 AM 11:51 AM 12:8 PM 12:25 PM 12:43 PM 1: PM 1:17 PM 1:35 PM 1:52 PM 2:9 PM MPH, deg F 2:26 PM 2:44 PM Oil Sump Temp F Coolant Out Temp F Ambient Temp F MPH RPM RPM A-8

APPENDIX B Fischer Tropsch Synthetic Fuels Evaluations HMMV Test Track Evaluation Work Directive No. 23, Task XI Emissions Conducted for U.S. Army TARDEC Force Projection Technologies Warren, Michigan 48397 5

DF2 Ballasted Emissions 775 725 675 625 575 525 CO Up CO Down NOx Up NOx Down HC Up HC Down 45 4 35 3 CO, NOx [ppm] 475 425 375 325 275 225 175 125 75 25 25 2 15 1 5 2 4 6 8 1 12 14 16 18 2 22 24 26 28 3 32 34 time [sec] HC [ppm] B-1

DF2 Un Ballasted Emissions 775 725 675 625 575 525 CO Up CO Down NOx Up NOx Down HC Up HC Down 45 4 35 3 CO, NOx [ppm] 475 425 375 325 275 225 175 125 75 25 25 2 15 1 5 2 4 6 8 1 12 14 16 18 2 22 24 26 28 3 32 34 time [sec] HC [ppm] B-2

JP8 Ballasted Emissions 775 725 675 625 575 525 CO Up CO Down NOx Up NOx Down HC Up HC Down 45 4 35 3 CO, NOx [ppm] 475 425 375 325 275 225 175 125 75 25 25 2 15 1 5 2 4 6 8 1 12 14 16 18 2 22 24 26 28 3 32 34 time [sec] HC [ppm] B-3

JP8 Un Ballasted Emissions 775 725 675 625 575 525 CO Up CO Down NOx Up NOx Down HC Up HC Down 45 4 35 3 CO, NOx [ppm] 475 425 375 325 275 225 175 125 75 25 25 2 15 1 5 2 4 6 8 1 12 14 16 18 2 22 24 26 28 3 32 34 time [sec] HC [ppm] B-4

5/5 Blend Ballasted Emissions 775 725 675 625 575 525 CO Up CO Down NOx Up NOx Down HC Up HC Down 45 4 35 3 CO, NOx [ppm] 475 425 375 325 275 225 175 125 75 25 25 2 15 1 5 2 4 6 8 1 12 14 16 18 2 22 24 26 28 3 32 34 time [ppm] HC [ppm] B-5

5/5 Blend Un Ballasted Emissions 775 725 675 625 575 525 CO up CO down Nox up Nox down HC up HC down 45 4 35 3 CO, NOx [ppm] 475 425 375 325 275 225 175 125 75 25 25 2 15 1 5 2 4 6 8 1 12 14 16 18 2 22 24 26 28 3 32 34 time [ppm] HC [ppm] B-6

775 725 675 625 575 525 S8 Ballasted Emissions CO Up CO Down NOx Up NOx Down HC Up HC Down 45 4 35 3 CO, NOx [ppm] 475 425 375 325 275 225 175 125 75 25 25 2 15 1 5 2 4 6 8 1 12 14 16 18 2 22 24 26 28 3 32 34 time [sec] HC [ppm] B-7

775 725 675 625 575 525 S8 Un Ballasted Emissions CO Up CO Down NOx Up NOx Down HC Up HC Down 45 4 35 3 CO, NOx [ppm] 475 425 375 325 275 225 175 125 75 25 25 2 15 1 5 2 4 6 8 1 12 14 16 18 2 22 24 26 28 3 32 34 time [sec] HC [ppm] B-8

APPENDIX C Fischer Tropsch Synthetic Fuels Evaluations HMMV Test Track Evaluation Work Directive No. 23, Task XI Acceleration Conducted for U.S. Army TARDEC Force Projection Technologies Warren, Michigan 48397 5

MPH and acceleration [ft/s^2] 55 5 45 4 35 3 25 2 15 1 5 DF2 Ballasted to 5 MPH 17 16 15 14 13 12 11 1 9 8 7 MPH up 6 MPH down 5 Accel up 4 Accel down Dist up 3 Dist down 2 1 2 4 6 8 1 12 14 16 18 2 22 24 26 28 3 32 34 time [sec] distance [ft] C-1

DF2 Un Ballasted to 5 MPH 55 17 5 16 15 45 14 MPH and acceleration [ft/s^2] 4 35 3 25 2 15 1 5 MPH up MPH down Accel up Accel down Dist up Dist down 13 12 11 1 9 8 7 6 5 4 3 2 1 distance [ft] 2 4 6 8 1 12 14 16 18 2 22 24 26 28 3 32 34 time [sec] C-2

MPH and acceleration [ft/s^2] 55 5 45 4 35 3 25 2 15 1 5 JP8 Ballasted to 5 MPH 2 4 6 8 1 12 14 16 18 2 22 24 26 28 3 32 34 time [sec] MPH up MPH down Accel up Accel down Dist up Dist down 17 16 15 14 13 12 11 1 9 8 7 6 5 4 3 2 1 distance [ft] C-3

MPH and acceleration [ft/s^2] 55 5 45 4 35 3 25 2 15 1 5 JP8 Un Ballasted to 5 MPH 2 4 6 8 1 12 14 16 18 2 22 24 26 28 3 32 34 time [sec] MPH up MPH down Accel up Accel down Dist up Dist down 17 16 15 14 13 12 11 1 9 8 7 6 5 4 3 2 1 distance [ft] C-4

5/5 Blend Ballasted to 5 MPH 55 17 5 16 15 45 14 MPH and acceleration [ft/s^2] 4 35 3 25 2 15 1 5 MPH up MPH down Accel up Accel down Dist up Dist down 13 12 11 1 9 8 7 6 5 4 3 2 1 distance [ft] 2 4 6 8 1 12 14 16 18 2 22 24 26 28 3 32 34 time [sec] C-5

5/5 Blend Un Ballasted to 5 MPH 55 17 5 16 15 45 14 MPH and acceleration [ft/s^2] 4 35 3 25 2 15 1 5 MPH up MPH down Accel up Accel down Dist up Dist down 13 12 11 1 9 8 7 6 5 4 3 2 1 distance [ft] 2 4 6 8 1 12 14 16 18 2 22 24 26 28 3 32 34 time [sec] C-6

MPH and acceleration [ft/s^2] 55 5 45 4 35 3 25 2 15 1 5 S8 Ballasted to 5 MPH 2 4 6 8 1 12 14 16 18 2 22 24 26 28 3 32 34 time [sec] MPH up MPH down Accel up Accel down Dist up Dist down 17 16 15 14 13 12 11 1 9 8 7 6 5 4 3 2 1 distance [ft] C-7

MPH and acceleration [ft/s^2] 55 5 45 4 35 3 25 2 15 1 5 S8 Un Ballasted to 5 MPH 2 4 6 8 1 12 14 16 18 2 22 24 26 28 3 32 34 time [sec] MPH up MPH down Accel up Accel down Dist up Dist down 17 16 15 14 13 12 11 1 9 8 7 6 5 4 3 2 1 distance [ft] C-8

APPENDIX D Fischer Tropsch Synthetic Fuels Evaluations HMMV Test Track Evaluation Work Directive No. 23, Task XI Stanadyne Pump Calibration / Evaluation Conducted for U.S. Army TARDEC Force Projection Technologies Warren, Michigan 48397 5

Stanadyne Pump Calibration / Evaluation Pump Type : DB2831-5149 (arctic) SN: 1476314 Test condition : HMMWV NATO Testing AL: PUMP RPM Description Spec. Pre Test Post Test Change ReCalibrated 1 Transfer pump psi. 6-62 psi 67 67 62 Return Fuel 225-375 cc 37 422 52 28 Fuel Delivery 56 cc. Max. 55 55 55 35 Low Idle 12-16 cc 13.5 1.5-3 14 Housing psi. 8-12 psi 9.5 9.5 5 Cold Advance Solenoid -1 psi..5 1.5 1 17 Fuel Delivery 49-52 cc 5 51 1 5 Advance 3.5-4.5 deg. 3.75 3.77.2 3.83 175 Fuel Delivery 45 cc. min. 51 51 52 1825 Fuel Delivery 31.5 cc min. 35 21-14 39 16 Face Cam Fuel delivery 21.5-23.5 cc 22 22 22 Advance 4-6 deg. 4.75 4.35 -.4 4.35 75 De-Energize E.S.O. 4 cc max..5.5.5 18 Fuel Delivery Record 41 27-14 47 Transfer pump psi. Record 1 98-2 95 Housing psi. Record 1 8.5-1.5 1 195 2 75 High Idle 15 cc max. 5 1-4 6 Transfer pump psi. 125 psi max. 115 11-5 112 Fuel Delivery 43 cc min. 5 5 48 Shut-Off 4 cc max..5.5.5 Fuel Delivery 28 cc min. 4 44 4 4 Transfer pump psi. 16 psi min. 27 27 29 Air Timing -1 deg. (+/-.5) -1-1 -1 Fluid Temp. Deg. C nr nr nr Date 2/25/29 5/28/29 6/1/29 The shaded boxes show where the pump is operating out of specification. D-1

APPENDIX E Fischer Tropsch Synthetic Fuels Evaluations HMMV Test Track Evaluation Work Directive No. 23, Task XI Elapsed Photos Showing the HMMWV Driving around SwRI Campus and the Test Track Conducted for U.S. Army TARDEC Force Projection Technologies Warren, Michigan 48397 5

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E-3