INTEGRATION OF REFINERY AND PETROCHEMICALS WITH OVER THE FENCE SUPPLY OF GAS UTILITY MOLECULES

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Block 2: Refining, Transportation and Petrochemistry Forum Title: F08 - Integration of the Refining and Petrochemical Industry INTEGRATION OF REFINERY AND PETROCHEMICALS WITH OVER THE FENCE SUPPLY OF GAS UTILITY MOLECULES Prasad K Panicker Executive Director Bharat Petroleum Corporation Limited-Kochi Refinery, India Chacko M Jose, Bharat Petroleum Corporation Limited, India

BHARAT PETROLEUM CORPORATION LIMITED - KOCHI REFINERY India - 0.23 Billion Crude oil processing capacity and Crude oil import of 70 Billion USD BPCL 13% share in refining capacity of India. Kochi Refinery is one among the four Refineries Refinery is located in Kochi, the port city on the south-west coast of India, also known as Queen of Arabian Sea Refining Capacity of 190,000 BPSD Complexity of 6.3 Crude API of 38.7 & 0.65 wt% Sulfur Fourth Quartile Third Quartile Kochi Refinery today Environment Value Maximization Energy Intensity Index of 105.2 Specific Green house Gas emission of 0.179 Refining Margin of 6.0 $/bbl, against Singapore Cracking margin of 7.5 4.6 $/bbl lower than USGC coking margin Benchmark with World class Performance (Solomon Associate 2014 Analysis) Second Quartile Energy Intensity Index Process Unit Utilization Net Cash Margin Operational Availability Second Quartile Source : PPAC

THE NEED FOR AIMING HIGH.. Oil Consumption Per capita, bbls 22.1 In MMT 5.7% 88 Light Distillates 190 310 7.4 7.5 7.5 7.6 7.7 6.5 6.6 6.5 6.4 6.5 6.2 6.1 5.9 5.7 5.6 FY 15 FY 16 FY 17 FY 18 FY 19 EIU IMF Inflation GDP GDP Indian Economy shifting to a higher growth path 2.7 USA China India World Avg Indian Oil demand to grow more 1 5 65 82 114 22 30 FY15 FY21 Growth of Petroleum products Middle Distillates Heavy Distillates Source : ENI annual World Oil and Gas review, PPAC Present Expanding to Market study suggested 120,000 BPSD capacity expansion

THE TRIGGERS.. Accelerated Global demand for fuels Changes in Marine Fuel sulfur specifications Growing market demand for Petrochemicals in India 90 Percapita Polymer consumption, Kilogram 46 8 35 Indian Petrochemicals demand increased by 7 % CAGR over 2011-16 vis-à-vis GDP of 5.5%. Value of Net import of petrochemicals increased from 1.63 Billion USD in 2007-08 to 8.25 Billion USD in 2015-16. USA China India World Avg Source : MoPNG-working group

WHY KOCHI REFINERY.. Land availability Close to international maritime route and port infrastructure Single Point Mooring facility, which can support up to 15.5 MMTPA Excellent product evacuation facilities Higher demand of products in Southern region of India Natural Gas availability

FINDING A PERFECT CONFIGURATION.. Optimum Hydrogen addition and Carbon rejection technology Making a Product portfolio that meets market demand with maximum value addition Key Areas Conversion of bottom of the barrel to Value added products Flexibility to optimize between Transportation fuels and Petrochemical feedstock Configuration Study Final Selection Secondary Processing Secondary Processing Options Options Residue Upgradation Options Full Conversion Hydrocracker. Once-through Hydrocracker with High Conversion FCCU. Conventional FCCU with downstream treatments. Slurry Hydrocracker. Delayed Coker. Flexi-coking. Solvent De-asphalting. Delayed Coker Unit, ranked second on margins, selected for residue up-gradation. Slurry Hydrocracker was not preferred, i. high capital cost ii. expected difficulties in operation including disposal of pitch Diversification of value added petrochemicals gave edge to Once-through Hydrocracker with High Conversion FCCU.

HIGHLIGHTS OF THE PROJECT.. Capacity Expansion from 1,90,000 bbl/day to 3,10,000 bbl/day (15.5 MMTPA). Meeting Auto Fuel compliant to 100% BS-IV and part BS-VI grade. Flexibility to process crude oils with 30 38 API. Facility for bottom up gradation and diversification to Petrochemicals. Production of 0.5 MMT of propylene and 1.3 MMT of Petcoke. Hydrogen demand is 16.4 TPH & Syngas requirement for Petrochemical plant is 14 TPH. Capital cost of 3 billion USD for Refinery expansion, 700 million USD for Petrochemical plant & 400 million for Utility gas molecule complex.

PROPYLENE DERIVATIVE PETROCHEMICAL PROJECT (PDPP).. Entry of BPCL into the field of Propylene based Petrochemicals. PDPP taken up as a BPCL Project, a Make in India initiative as envisaged niche petrochemicals are predominantly imported. Production of Niche Petrochemicals utilizing 250 TMT out of 500 TMT of Polymer grade Propylene available post IREP. Acrylic Acid Acrylates : Butyl Acrylate, 2 Ethyl Hexyl Acrylate Oxo Alcohols : Normal Butanol, 2 Ethyl Hexanol, Iso Butanol Total project cost : 700 Million USD.

PDPP - INTEGRATION WITH REFINERY.. Technology selection was done with the objective of maximizing the net present value from the entire life cycle of the unit. Syngas, Hydrogen and Nitrogen to be sourced from Build-Own Operate (BOO) facilities being installed as part of IREP. Sourcing Feedstock & Utilities Loading of products using Refinery facilities For Capex/Opex Advantage Firewater system integration Location Advantage: Nearer to Refinery Refinery Effluent treatment in Refinery facilities

OVER THE FENCE GAS UTILITY SUPPLY.. The operational synergy between IREP & PDPP made sense to outsource Industrial Gases required for both. The selection of Build-Own Demand (BOO) would minimize the capital required for IREP & PDPP. Utility supplier for Future Projects Power required is generated by BOO operator with backup supply from Refinery Highly energy efficient unit design with GT integrated with H 2 Plant BOO at BPCL- Kochi Refinery Buy & Sell or Tolling model pricing philosophy Flexibility to operate on NG or Naphtha Pricing of Hydrogen, Syngas & Steam depends on operating efficiency at varying capacities. Pricing model arrived was each product from BOO shall attract a Fixed monthly charge and Variable Charge based on actual consumption. The Variable Charge calculation was based on 12 windows of operation.

5.0 6.0 TRANSFORMATION TO A WORLD CLASS GREEN REFINERY.. Routine expansion project in a growing economy has been turned into well thought out plan for efficiency improvement, value addition, risk reduction and transformation as a modern industrial complex with World Standards. 11.0 105.2 15.2 EII 90.0 World best Refinery Characteristics (Solomon Associates 2014) Crude Capacity - 380 Kbbl/day Kochi Refinery Post Expansion 310 Complexity 13.3 10.3 9.5 6.0 15.5 Crude oil API 31.9, Sulfur 1.6 wt% Total conversion 52% 30.6, 2.6 48

HIGHLIGHTS OF THE PROJECT UNIT CAPACITIES & PRODUCT PATTERN.. Process Units Present Capacity, MMTPA Additional Capacity, MMTPA CDU/VDU 5 + 4.5 10.5 DHDT 2.54 4.3 VGO HDT 1.7 3.0 FCCU 1.45 2.2 NHT/Isom (Revamp) 0.37 DCU 3.8 HGU 18,000 TPA 130,000 TPA SRU 3 X 72 TPD 2 X 340 TPD Product Pre-expansion, TMT/Anm Post expansion, TMT/Anm Propylene 50 540 Gasoline 480 1109 LPG 1115 2209 SKO 360 240 HSD 4384 8112 ATF 400 600 Naphtha 392 451 Bitumen 250 250 FO/ LSHS 1400 0 Sulphur 33 303 Petcoke 0 1337

HIGHLIGHTS OF THE PROJECT PROJECT ENORMITY.. Item Description Piling Structural Erection Above ground Piping Work Equipment erection Electrical/Instrument cable laying Quantity 21,000 Numbers 60,000 MT 7,300,000 Inch Meter 2062 Numbers / 41,000 MT (250+ Over Dimensional Consignments) 7,000 Km

ENERGY EFFICIENCY DRIVERS & ENVIRONMENT FRIENDLY CONCEPTS.. Hot Water Belt(HWB) system at Petro-FCCU. Total heat recovered will be 84.3 MMKCal/hr. Power Recovery Expander (PRE) at Petro-FCCU PRE receives flue gas from Regenerator and produce 11 MW of power. Considering this, PFCCU is a net-exporter of power. Electrostatic Precipitator at Petro-FCCU. Ensures Suspended Particulate Matter in the flue gas is less than 50 mg/nm 3 Back Pressure Turbines with VHP steam. Sulfur Recovery Units with Tail Gas Treaters ensure 99.9% sulfur removal and emissions well below the norms of 1518 Kg/hr. Coke handling system in DCU. Reverse Osmosis based De-mineralized water plant.

PDPP - PROCESS FLOW.. PROPYLENE (113) CRUDE ACRYLIC ACID (160) (160) (50) (110) GLACIAL ACRYLIC ACID (Future) All figures in 000 TPA Sales 47 (250) SAP (Future) 0 SYN GAS HYDROGEN (137) (99.8) (6.5) OXO ALCOHOL (212) N-BUTANOL (150) 2-ETHYL HEXANOL (55) I-BUTANOL (7) (4) (106) (110) (8) BUTYL ACRYLATE 2-ETHYL HEXYL ACRYLATE 7 180 38 10 47

OVER THE FENCE GAS UTILITY SUPPLY - PRICING.. 100% 70% 50% Hydrogen Capacity 35% 12 C1, C2, C3, C4 C1*, C2*, C3*, C4*, C5 11 C1, C2, C3, C4 C1*, C2*, C3*, C4*, C5 10 C1, C2, C3, C4 C1*, C2*, C3*, C4*, C5 1 C1,C2,C3,C4 D1,D2,D3,D4 C1*,C2*,C3*,C4*,C5 D1*,D2*,D3*,D4*,D5 4 C1,C2,C3,C4 D1,D2,D3,D4 C1*,C2*,C3*,C4*,C5 D1*,D2*,D3*,D4*,D5 7 C1,C2,C3,C4 D1,D2,D3,D4 C1*,C2*,C3*,C4*,C5 D1*,D2*,D3*,D4*,D5 2 C1,C2,C3,C4 D1,D2,D3,D4 C1*,C2*,C3*,C4*,C5 D1*,D2*,D3*,D4*,D5 5 C1,C2,C3,C4 D1,D2,D3,D4 C1*,C2*,C3*,C4*,C5 D1*,D2*,D3*,D4*,D5 8 C1,C2,C3,C4 D1,D2,D3,D4 C1*,C2*,C3*,C4*,C5 D1*,D2*,D3*,D4*,D5 3 C1,C2,C3,C4 D1,D2,D3,D4 C1*,C2*,C3*,C4*,C5 D1*,D2*,D3*,D4*,D5 6 C1,C2,C3,C4 D1,D2,D3,D4 C1*,C2*,C3*,C4*,C5 D1*,D2*,D3*,D4*,D5 9 C1,C2,C3,C4 D1,D2,D3,D4 C1*,C2*,C3*,C4*,C5 D1*,D2*,D3*,D4*,D5 Variable charges / Ton of Hydrogen with Natural Gas as Feed/fuel. Scenario 1 :With Power from CPP of BOO Operator C1*NG1+C2*DM1+C3*RW1-(C4*ST1) Scenario 2: With Power from BPCL/Other sources C1 * *NG1+C2 * *DM1+C3 * *RW1-(C4 * *ST1) +C5*P1 For Syngas, all D factors quoted by the BOO Operator as per the table will be used for the above two scenarios. 35% 50% 70% 100% Syn Gas Capacity

TRANSFORMATION OF SOCIETY ALONG WITH REFINERY GROWTH.. Employment Opportunities Workmen from length & breadth of the nation have received employment opportunities. Gain for Cochin Port Increased traffic and revenue for Cochin Port. Further foray into Niche/Specialty Petrochemicals Potential for major Petrochemical plants in the area & resultant employment generation. Petrochemical Park For medium and small scale industries. Community Development Portion of Project expenditure is earmarked for developing nearby community.