Carmeuse Biodiesel Experience

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Carmeuse Biodiesel Experience MSHA/NIOSH Diesel Technology Workshop - January 23, 2019 1

AGENDA 1. Carmeuse Usage 2. The Good 3. The Bad 4. The Ugly 5. Close Out

Carmeuse Background Carmeuse Lime and Stone, Inc. (Carmeuse North America) operates five underground limestone mines Black River Operation Butler, KY Cisco Operation Cisco, GA Ellijay Operation Ellijay, GA Luttrell Operation Luttrell, TN Maysville Operation Maysville, KY Carmeuse--Black River and Carmeuse--Maysville are the largest of the UG operations, with all mining operations carried out completely UG The other operations utilize truck haulage to surface All of the mines are solely dependent on diesel mobile equipment to meet the stone production needs of their plants 3

Maysville and Black River Background Both mines use a staggered room and pillar mining configuration, with headings and benches mined Two to three mining fronts/panels are simultaneously advanced Multiple pieces of mining equipment are simultaneously used in the advancing panels, and split between heading or benching operations Diesel equipment utilized: Cat 988 wheel loaders Cat 772 haul trucks Fletcher diesel face drills Cat track-mounted bench drills Oldenburg powder rigs Cat excavator-type scalers Fletcher roof bolters Various diesel powered support equipment Water and service trucks, manlifts, personnel carriers 4

KY (MY and BR) Background During initial DPM rulemaking, the mines were found to need to make DPM changes like numerous other mines at the time Carmeuse formed a DPM Compliance team prior to the initial rules enactment date, and compliance options were evaluated: Additional ventilation (shafts and fans) DPM exhaust filters Alternative fuels Engine upgrades Enclosed cabs 5

Initial Compliance Background Low-sulfur diesel (mandatory) Relatively easy change over (purchasing and communication) Additional ventilation (shafts and fans) Large capital costs for shafts and fans Significant electrical operating costs for additional fan horsepower DPM exhaust filters Large capital cost if used on all pieces of equipment Operating and maintenance issues and costs associated with using and regenerating Engine upgrades Cost prohibitive based on cost and equipment ages at the time Would be done with new machine purchases Enclosed cabs Similar implementation reasoning as engine upgrades 6

Alternative fuels Initial Compliance Background Relatively easy implementation (purchasing/scheduling/communication) Very minimal capital costs (if any) Possible performance issues to overcome Increase in operating/fuel cost Decreases emissions at the source - engine 7

Initial Capital Estimates Yr. 2000 Dollars Capital Cost $1,400,000 $1,200,000 $1,000,000 $800,000 $600,000 $400,000 Comply w / 160 limit Comply w / 400 limit & possibly 160 limit Comply w / 400 limit; not 160 limit Comply w / 400 limit & possibly 160 limit Comply w / 400 limit & possibly 160 limit $200,000 $0 $1,166,000 $266,000 $0 $0 $0 Imp. Vent-Shaft and Fans Imp. Vent-Fans B35 Biodiesel B50 Biodiesel Lubrizol PuriNOx Control Options 8

Initial Operating Cost Estimates Yr. 2000 Dollars Annual Costs $350,000 $300,000 $250,000 Comply w / 160 limit Comply w / 400 limit & possibly 160 limit Comply w / 400 limit; not 160 limit Comply w / 400 limit & possibly 160 limit Comply w / 400 limit & possibly 160 limit $200,000 $150,000 $100,000 $50,000 $0 $243,586 $110,430 $217,262 $313,278 $97,152 Imp. Vent-Shaft and Fans Imp. Vent-Fans B35 Biodiesel B50 Biodiesel Lubrizol PuriNOx Control Options 9

Fuel Selection Alternative fuels selected as primary DPM control methodology based on cost and implementation Biodiesel selected fuel choices available Recycled yellow-grease derived Virgin soybean oil derived Animal fats based And other sources Yellow-grease based biodiesel initially selected Locally available Limited reported power loss issues Some comfort with fuel supplier PuriNOx side note Water-Diesel fuel emulsion blend Deionized water, Lubrizol chemicals, and diesel fuel Water molecules are encapsulated in diesel fuel 10% water winter blend 20% water summer blend Manufacturing phased out at end of 2006 Ran 10 the problematic fuel at various levels from 2004 thru 2006

Fuel Utilization As required, switched to Low-Sulfur Diesel fuel (<0.05% sulfur) Tested number of alternative fuel blends B20 Bio, B50 Bio, B50 Soy, PuriNOx Used B35 Biodiesel for 7 mos. middle to end of 03 Tested and used PuriNOx 10% and 20% emulsion blends Majority of equipment operating on it from Jan 04 to late 05 Select pieces still on it in mid- 06, but product phased out Dec 06 Switched back to biodiesel Selected B99 to meet PuriNOx performance levels Tried a few suppliers and feed stocks Migrated to distillation only processing of soy or yellow grease feed stocks 11

Fuels Performance 12

Carmeuse Biodiesel Experience MSHA/NIOSH Diesel Technology Workshop The Good Biodiesel brought the Carmeuse UG limestone mines into DPM compliance in the early days of the DPM regulations Alternatives and recommendations had been considered, but biodiesel was selected as the best lead option Biodiesel was instrumental in keeping the KY Mines in compliance during the DPM limit changes Other DPM controls were utilized as well, but Bio remained the lead (eliminate the generation of emissions) Biodiesel was a part of keeping the mines in compliance Tier 4 engine technology usage increased, with Biodiesel remaining utilized in the non-tier 4 units Without additional DPM controls development and implementation, unable to remain consistently within compliance limits without Biodiesel Very limited issues with power and performance Significant emissions reductions Another site utilized biodiesel to quickly achieve compliance 13

The Bad Carmeuse Biodiesel Experience MSHA/NIOSH Diesel Technology Workshop Biodiesel has its disadvantages and limitations Nothing is free; all of the DPM controls have costs associated with them Biodiesel Increased fuel costs Price Consumption Storage/handling Increased maintenance costs Filters Injectors Hoses Increased production costs Unplanned downtime (lost production) Non-Bio DPM Controls (Tier 4) Increased new equipment cost (new engine technology) Increased fuel related costs (DEF Fluid) Increased maintenance costs Regen system issues DEF systems DPM filters Increased production costs DEF fluid procuring/handling Regen s Unplanned downtime 14

The Ugly Downed equipment Plugged fuel filters Injector replacements Carmeuse Biodiesel Experience Deteriorated hoses and o-rings MSHA/NIOSH Diesel Technology Workshop Paint removal Varying quality fuel supplies/suppliers Distilled biodiesel production proven to be best Works for Yellow Grease or Soy based bio s Filtration based bio production still leads to filter plugging On-site filtration system additions unsuccessful Blend levels above B20 more susceptible Yellow Grease more susceptible than Soy Increased fuel cost, and lower BTU performance (ton/gal) Limited fuel supplies, and commodity price fluctuations Gelled surface fuel delivery lines Gelling in equip near winter air intake areas 15

Biodiesel Close Out Carmeuse Experiences Within Carmeuse, Maysville is the only UG site still utilizing Biodiesel for DPM compliance With Tier 4 engines (new engine technology) coming in the new equipment replacements, phasing out Bio was one of our recent KY plans Although sticking with less problematic, Tier 3 technology was considered at times as well Black River has reached that point Fuel additive (TPx HD) is in use at BR to enhance fuel burning and emissions Maysville is 23% B99 and 77% ULS Diesel BR had been 15% B99 and 85% ULS Diesel No Biodiesel blends have been utilized in the Tier 4 engines B20 is the known manufacturer limit; B5 can be common level Internally decided no Bio would be used in Tier 4 s due to the unknowns 16