Combustion and Emission Behavior of Ethanol Fuelled Homogeneous Charge Compression Ignition (HCCI) Engine

Similar documents
INFLUENCE OF INTAKE AIR TEMPERATURE AND EXHAUST GAS RECIRCULATION ON HCCI COMBUSTION PROCESS USING BIOETHANOL

INFLUENCE OF FUEL TYPE AND INTAKE AIR PROPERTIES ON COMBUSTION CHARACTERISTICS OF HCCI ENGINE

THE INFLUENCE OF THE EGR RATE ON A HCCI ENGINE MODEL CALCULATED WITH THE SINGLE ZONE HCCI METHOD

Potential of Large Output Power, High Thermal Efficiency, Near-zero NOx Emission, Supercharged, Lean-burn, Hydrogen-fuelled, Direct Injection Engines

Module7:Advanced Combustion Systems and Alternative Powerplants Lecture 32:Stratified Charge Engines

Module 3: Influence of Engine Design and Operating Parameters on Emissions Lecture 14:Effect of SI Engine Design and Operating Variables on Emissions

Module 2:Genesis and Mechanism of Formation of Engine Emissions Lecture 3: Introduction to Pollutant Formation POLLUTANT FORMATION

Influence of Fuel Injector Position of Port-fuel Injection Retrofit-kit to the Performances of Small Gasoline Engine

AN EXPERIMENT STUDY OF HOMOGENEOUS CHARGE COMPRESSION IGNITION COMBUSTION AND EMISSION IN A GASOLINE ENGINE

Study of Performance and Emission Characteristics of a Two Stroke Si Engine Operated with Gasoline Manifold Injectionand Carburetion

PERFORMANCE AND EMISSION ANALYSIS OF DIESEL ENGINE BY INJECTING DIETHYL ETHER WITH AND WITHOUT EGR USING DPF

CHAPTER 1 INTRODUCTION

REDUCTION OF EMISSIONS BY ENHANCING AIR SWIRL IN A DIESEL ENGINE WITH GROOVED CYLINDER HEAD

Normal vs Abnormal Combustion in SI engine. SI Combustion. Turbulent Combustion

Gasoline HCCI engine with DME (Di-methyl Ether) as an Ignition Promoter

JJMIE Jordan Journal of Mechanical and Industrial Engineering

4. With a neat sketch explain in detail about the different types of fuel injection system used in SI engines. (May 2016)

Liquefied Petroleum Gas and Dimethyl Ether Compression Ignition Engine

Experimental Investigation of Acceleration Test in Spark Ignition Engine

Homogeneous Charge Compression Ignition combustion and fuel composition

Effects of ethanol unleaded gasoline blends on cyclic variability and emissions in an SI engine

PRELIMINARY INVESTIGATIONS OF THE HCCI COMBUSTION SYSTEM IN A SINGLE CYLINDER RESEARCH ENGINE

Closed-Loop Combustion Control of a Multi Cylinder HCCI Engine using Variable Compression Ratio and Fast Thermal Management

Comparative performance and emissions study of a lean mixed DTS-i spark ignition engine operated on single spark and dual spark

EFFECT OF EGR AND CYCLONIC SEPARATOR ON EMISSIONS IN DI DIESEL ENGINES

STATE OF THE ART OF PLASMATRON FUEL REFORMERS FOR HOMOGENEOUS CHARGE COMPRESSION IGNITION ENGINES

EFFECTS OF INTAKE AIR TEMPERATURE ON HOMOGENOUS CHARGE COMPRESSION IGNITION COMBUSTION AND EMISSIONS WITH GASOLINE AND n-heptane

CONTROLLING COMBUSTION IN HCCI DIESEL ENGINES

TECHNICAL PAPER FOR STUDENTS AND YOUNG ENGINEERS - FISITA WORLD AUTOMOTIVE CONGRESS, BARCELONA

EXPERIMENTAL INVESTIGATION OF THE EFFECT OF HYDROGEN BLENDING ON THE CONCENTRATION OF POLLUTANTS EMITTED FROM A FOUR STROKE DIESEL ENGINE

Homogeneous Charge Compression Ignition with Water Injection

Saud Bin Juwair, Taib Iskandar Mohamad, Ahmed Almaleki, Abdullah Alkudsi, Ibrahim Alshunaifi

Experimental Investigation of Performance and Emissions of a Stratified Charge CNG Direct Injection Engine with Turbocharger

A COMPARATIVE EXPERIMENTAL STUDY ON ENGINE OPERATING ON PREMIXED CHARGE COMPRESSION IGNITION AND COMPRESSION IGNITION MODE

Maximizing Engine Efficiency by Controlling Fuel Reactivity Using Conventional and Alternative Fuels. Sage Kokjohn

ACTUAL CYCLE. Actual engine cycle

Thermo-Kinetic Model to Predict Start of Combustion in Homogeneous Charge Compression Ignition Engine

Case Study of Exhaust Gas Recirculation on Engine Performance

NUMERICAL INVESTIGATION OF EFFECT OF EXHAUST GAS RECIRCULATION ON COMPRESSIONIGNITION ENGINE EMISSIONS

Effect of Tangential Grooves on Piston Crown Of D.I. Diesel Engine with Retarded Injection Timing

ANALYSIS OF EXHAUST GAS RECIRCULATION (EGR) SYSTEM

The Effect of Air Preheating on the performance and emission characteristics of a DI Diesel Engine achieving HCCI mode of combustion

An investigation of hydrogen-fuelled HCCI engine performance and operation

Published in: First Biennial Meeting of the Scandinavian-Nordic Section of the Combustion Institute

Homogeneous charge compression ignition versus dual fuelling for utilizing biogas in compression ignition engines

International Journal of Scientific & Engineering Research, Volume 7, Issue 8, August-2016 ISSN

Variations of Exhaust Gas Temperature and Combustion Stability due to Changes in Spark and Exhaust Valve Timings

Control of PCCI Combustion using Physical and Chemical Characteristics of Mixed Fuel

Impact of Cold and Hot Exhaust Gas Recirculation on Diesel Engine

INFLUENCE OF THE NUMBER OF NOZZLE HOLES ON THE UNBURNED FUEL IN DIESEL ENGINE

Effect of Diesel Injection Parameters on Diesel Dual Fuel Engine Operations with Charge Preheating under Part Load Conditions

Conversion of Naturally Aspirated Genset Engine to Meet III A Norms for Tractor Application by Using Turbocharger

Modifications on a Small Two Wheeler Two Stroke SI Engine for Reducing Fuel Consumption and Exhaust Emissions

Which are the four important control loops of an spark ignition (SI) engine?

CHAPTER 3 EXPERIMENTAL SET-UP AND TECHNIQUES

The influence of thermal regime on gasoline direct injection engine performance and emissions

ISSN: ISO 9001:2008 Certified International Journal of Engineering and Innovative Technology (IJEIT) Volume 4, Issue 7, January 2015

Evaluation of Performance and Emission Characteristics of Flax Oil Ethyl Ester with Ignition Improver on Diesel Engine and Comparison With Jatropha

The Effect of Clean and Cold EGR on the Improvement of Low Temperature Combustion Performance in a Single Cylinder Research Diesel Engine

Effect of Dilution in Diesel Percentage on the size Distribution from a Diesel Engine Combustion

CHAPTER 8 EFFECTS OF COMBUSTION CHAMBER GEOMETRIES

AN EXPERIMENTAL STUDY ON THE EFFECTS OF EGR AND EQUIVALENCE RATIO ON CO AND SOOT EMISSIONS OF DUAL FUEL HCCI ENGINE

POLLUTION CONTROL AND INCREASING EFFICIENCY OF DIESEL ENGINE USING BIODIESEL

State of the Art (SOTA) Manual for Internal Combustion Engines

Chapter 6. NOx Formation and Reduction in Reciprocating Internal Combustion Engines (RICE)

Effects of intake air temperature on HCCI combustion and emissions with gasoline and n-heptane

EFFECT OF H 2 + O 2 GAS MIXTURE ADDITION ON EMISSONS AND PERFORMANCE OF AN SI ENGINE

Chapter 4 ANALYTICAL WORK: COMBUSTION MODELING

Experimental Investigation of Performance and Exhaust Emission Characteristics of Diesel Engine by Changing Piston Geometry

Investigations on performance and emissions of a two-stroke SI engine fitted with a manifold injection system

VISUALIZATION OF AUTO-IGNITION OF END GAS REGION WITHOUT KNOCK IN A SPARK-IGNITION NATURAL GAS ENGINE

Direct Injection Ethanol Boosted Gasoline Engines: Biofuel Leveraging For Cost Effective Reduction of Oil Dependence and CO 2 Emissions

Experimental investigation on influence of EGR on combustion performance in SI Engine

COMBUSTION in SI ENGINES

Analysis of Emission characteristics on Compression Ignition Engine using Dual Fuel Mode for Variable Speed

Principles of Engine Operation. Information

Homogeneous Charge Compression Ignition (HCCI) Engines

EFFECT OF INJECTION ORIENTATION ON EXHAUST EMISSIONS IN A DI DIESEL ENGINE: THROUGH CFD SIMULATION

Theoretical Study of the effects of Ignition Delay on the Performance of DI Diesel Engine

8 th International Symposium TCDE Choongsik Bae and Sangwook Han. 9 May 2011 KAIST Engine Laboratory

Improving The Emission Characteristics of Diesel Engine by Using EGR at Different Cooling Rates

Hongming Xu (Jaguar Cars) Miroslaw Wyszynski (University of Birmingham) Stan Golunski (Johnson Matthey)

Influence of ANSYS FLUENT on Gas Engine Modeling

VALVE TIMING DIAGRAM FOR SI ENGINE VALVE TIMING DIAGRAM FOR CI ENGINE

Foundations of Thermodynamics and Chemistry. 1 Introduction Preface Model-Building Simulation... 5 References...

Studying Turbocharging Effects on Engine Performance and Emissions by Various Compression Ratios

EXPERIMENTAL ANALYSIS OF A DIESEL CYCLE ENGINE USING GASOLINE AS FUEL: HCCI TECHNOLOGY

EMISSION AND COMBUSTION CHARACTERISTICS OF DIFFERENT FUELS IN A HCCI ENGINE. Maduravoyal, Chennai, India

A REVIEW OF SCAVENGING PROCESS OF TWO STROKE ENGINE

Experimental Study on the Use of EGR in a Hydrogen-Fueled SI Engine. P. Tamilarasan, M. Loganathan

Chapter 6 NOx Formation and Reduction in Reciprocating Internal Combustion Engines (RICE)

Internal Combustion Optical Sensor (ICOS)

Experimental Investigation on Diesel Engines by Swirl Induction with Different Manifolds

CHAPTER 7 CYCLIC VARIATIONS

The effect of compression ratio on exhaust emissions from a PCCI Diesel engine

THE STUDY OF EGR EFFECT ON DIESEL ENGINE PERFORMANCE AND EMISSION - A REVIEW Srinath Pai 1, Amriya Tasneem H.R. 2, Shivaraju N 3 & Dr.

EXPERIMENTAL INVESTIGATION OF THERMAL PERFORMANCE OF PETROL ENGINE USING FUEL CATALYST

An Investigation of Compressed Natural Gas Engine for Nitrogen Oxides Reduction

INVESTIGATIONS OF EFFECTS OF PILOT INJECTION WITH CHANGE IN LEVEL OF COMPRESSION RATIO IN A COMMON RAIL DIESEL ENGINE

Combustion and emission characteristics of a dual injection system applied to a DISI engine

Transcription:

8-8-6 Combustion and Emission Behavior of Ethanol Fuelled Homogeneous Charge Compression Ignition (HCCI) Engine Copyright 8 SAE International Rakesh Kumar Maurya, Avinash Kumar Agarwal Engine Research laboratory, Department of Mechanical Engineering Indian Institute of Technology Kanpur Kanpur 86, India Corresponding author s email: akag@iitk.ac.in ABSTRACT The Homogeneous charge compression ignition (HCCI) is the third alternative for the combustion in the reciprocating engine. HCCI a hybrid of well-known spark ignition (SI) and compression ignition (CI) engine concepts and has potential of combining the best features of both. A two cylinder, four stroke, direct injection diesel engine was modified to operate one cylinder on the compression ignition by detonation of homogeneous mixture of ethanol and air. The homogeneous mixture of the charge is prepared by port injection of ethanol in the preheated Intake air. This study presents results of experimental investigations of HCCI combustion of ethanol at intake air temperature of C and at different air-fuel ratios. In this paper, the combustion parameters, pressure time history, rate of pressure rise, rate of heat release, mean temperature history in the combustion chamber is analyzed and discussed. The HCCI operating region criteria is defined based on the cycle-to-cycle variation of indicated mean effective pressure (IMEP) and rate of pressure rise. The results presented in this study for air fuel ratio, which satisfies the HCCI operating region criteria. The results show that controlled HCCI combustion is possible with extremely low emission and high efficiency. INTRODUCTION Petroleum fuel supply concerns and increasingly stringent exhaust emission regulations require development of new propulsion systems that provide high performance, excellent fuel economy, as well as reduced exhaust gas emissions. Homogeneous charge compression ignition (HCCI) is new combustion concept that may be developed as an alternative to compression ignition with higher efficiency, lower NOx and particulate emissions. HCCI means that the fuel and air should be mixed homogeneously before combustion starts and the mixture is auto-ignited due to increase in temperature at the end of the compression stroke. Thus HCCI is similar to SI in the sense that both engines use a premixed charge and HCCI is similar to CI as both rely on autoignition for combustion initiation. However, the combustion process is totally different for the three types. The principle of HCCI combustion consists of (a) Preparing a highly diluted air/fuel mixture by burnt gases recirculation to give reasonable burn rate. (b) The temperature after compression stroke should equal the auto-ignition temperature of the fuel/air mixture to promote simultaneous ignition in the whole combustion chamber. (c) Controlling precisely the combustion heat release to achieve the best compromise in terms of efficiency and pollutant emissions. The earliest experience with HCCI is a report by Onishi et al. [] on a unique combustion behavior intermediate between SI and CI. It was called Active Thermo Atmosphere Combustion (ATAC). The HCCI combustion process has been studied with certain success in two stroke [-] and four stroke engines [-9], and with liquid [-7] and gaseous [8-9] fuels. The HCCI family can be distinguished according to the fuel introduction strategy employed []. This distinction include port injection [-], early in- cylinder injection [6, -], and late in-cylinder injection [], dual fuel introduction (both in-cylinder and port injection) []. The main problem with the HCCI is that the ignition is completely controlled by chemical kinetics, and is therefore affected by the fuel composition, equivalence ratio, and thermodynamic state of the mixture []. There is no external control such as the fuel injection or spark timing that are used on diesel or SI engines. Achieving the required level of control during transient engine operation is even more challenging since charge temperatures has to be correctly matched to the operating condition during rapid transients with a high repeatability as the speed and load is changing. Another problem with HCCI is the low BMEP. The relatively high intake air temperature and very lean air to fuel (A/F) ratios reduce the output compared with the conventional engines. However considering the advantage of HCCI and emission legislation limits, HCCI combustion attracts the attention of researchers globally.

EXPERIMENTAL SETUP A two cylinder, four stroke, air cooled, naturally aspirated, bowl shaped combustion chamber; direct injection diesel engine was modified for the experiment. The engine specification was given in table. One of the two cylinders of the engine is modified to operate in HCCI mode, while the other cylinder is operated like an ordinary diesel engine, thus motoring the first cylinder for achieving HCCI. A schematic diagram of the experimental setup is shown in Figure. Table : Detailed Engine specification Engine characteristics Specification Model Indec PH Diesel Engine Injection Type Direct Injection Number of Cylinders Two Bore / Stroke 87. / mm Power per Cylinder.85 kw @ 5 rpm Compression Ratio 6.5 Displacement 8 cc Fuel Injection Timing before TDC Fuel Injection Pressure kg/cm @5 rpm 5 6 8 7 : Intake Air, : Air Box, : Heater, : Injection Timing Circuit, 5: Electronic fuel Injector, 6: Piezo-electric Pressure Transducer, 7: Charge Amplifier, 8: Shaft Encoder, 9: Dynamometer, : Emission Analyzer, : Combustion Analyzer Figure : Schematic diagram of experimental setup. Test fuel used for this investigation is ethanol. A premixed fuel system was installed in the intake manifold. This system consists of electronic injector and an injection timing and injection duration controlling electronic circuit. Fresh air entering the engine is heated by an air pre-heater positioned upstream of the intake manifold. The intake air heater is operated by a closed loop controller, which maintains the intake air temperature at C. The in-cylinder pressure was measured using a water-cooled piezo-electric pressure transducer (Make: Kistler, Switzerland; Model: 66B) which is mounted flush in the cylinder head. The pressure transducer minimizes thermal shock error by using a double walled diaphragm and integral water cooling system. To measure the a precision shaft encoder (Make: Encoders India, Model: ENC58/6-7ABZ/5-V) is coupled with the crank shaft using a helical coupling. 9 The cylinder pressure history data acquisition and combustion analysis is done using a program based on LabVIEW, developed at Engine Research Laboratory IIT Kanpur. The raw exhaust gas analysis for NO x, CO and THC were carried out using Exhaust gas emission analyzer (Make: AVL, India; Model: DiGAS ). Experiments were conducted on the modified engine at constant speed of 5 rpm and intake air temperature of C. RESULT AND DISCUSSION In this section the experimental results at different engine load at constant engine speed are presented with ethanol as fuel at intake air temperature of the C. RELATIVE AIR/FUEL RATIO () is the ratio of the actual air/fuel ratio to the stoichiometric air/ fuel ratio. The results in this investigation are presented with respect to different relative air/fuel ratios (), which are present in the HCCI operating region. OPERATING REGION To study the HCCI combustion criteria as to what constitutes HCCI combustion must be defined. The HCCI operation region is limited by the misfire and knocking. The operation boundaries are associated with these factors (misfire and knock). The first boundary defines the lower limit for the HCCI combustion. At low loads, fuel flow rate decreases hence the net heat release also decreases. It is believed that the resulting gradual reduction of average combustion temperature results in more unburned charge that is characterized by high CO and THC emissions and by increase in cycle-tocycle variation. Cycle-to-cycle variation of the combustion process in an engine can be monitored by cylinder pressure transducer. Fluctuation of both maximum cylinder pressure and the indicated mean effective pressure (IMEP) were used as a measure of cycle-to-cycle variations and were expressed as COV pmax and COV IMEP. The Coefficient of Variation (COV) of IMEP and COV of maximum cylinder pressure (Pmax) was used in this investigation and COV is calculated for consecutive engine cycles was calculated as standard deviation ( ) divided by mean value (IMEP) as a percentage [5]. COV IMEP IMEP % IMEP IMEP Since the drivability problems in automobiles normally arise when COV IMEP exceeds percent [5], this study used this value for the misfire boundary. When the fuelling rates is increased (lower ), the HCCI combustion rates also increase and intensify, and gradually cause unacceptable noise and may

potentially cause engine damage, and eventually leads to unacceptably high level of NO x emissions. Therefore knocking combustion can be defined as being at the upper limit of HCCI combustion. In this investigation, the upper limit of HCCI combustion was defined as being when the rate of pressure rise in a cylinder exceed. Mpa pre crank angle degree ( ) (dp/dθ max =. Mpa / ) for each individual cycle. The recorded pressure in the cylinder determined the values of COV IMEP, COV Pmax and dp/dθ max. Therefore, the HCCI operation region is the area in which the values of COV IMEP and COV Pmax are less than percent and values of dp/dθ max are less than. Mpa/. This definition is applied for present investigation and HCCI operating region was found for of,.5, and.5. The variation of the COV IMEP, COV Pmax and rate of pressure rise at shown in the Figure and Figure at different relative air fuel ratio () in HCCI operating range. COV IMEP COV Pmax Maximum Pressure (bar) Rate of Pressure rise (bar/) Pressure (bar) IMEP (bar) down the speed of the chemical reactions sufficiently so that engine is not damaged and this leads to slow combustion. With lean operation, this will significantly reduces the output for a given air flow through the engine. The rich side limit for IMEP is limited by the rate of combustion and hence that of rate of pressure rises. The maximum IMEP encountered in this investigation is. bars. The Variation of IMEP at different relative air fuel ratios () in HCCI mode is shown in Figure. 5.5.5 8 6.5.5.5.5 Figure : COV IMEP and COV Pmax for successful HCCI operating region 8 6 - - = =.5 = =.5-5 - - - - 5 Figure: Rate of rate of pressure rise variation for successful HCCI operating region ENGINE LOAD, IMEP One major limitation of HCCI combustion is the requirement of a highly diluted mixture in order to slow Figure : IMEP for HCCI operating region. CYLINDER PRESSURE The cylinder pressure was measured for all operating conditions. The cylinder pressure was recorded for cycles, with a resolution of.5 crank angle degrees. Figure 5 shows the pressure trace for different relative air fuel ratio (). For all plots, the trace with the highest maximum pressure corresponds to the operating condition with the richest mixture, as given by figure 6, and the lowest maximum pressure corresponds to the leanest mixture. 7 6 5 = =.5 = =.5-5 - - - - 5 Figure 5: P-θ diagram at different relative air fuel ratios () 8 6.5.5 Relative Air/Fuel ratio ( ) Figure 6: Maximum cylinder pressure for HCCI mode at different relative air fuel ratios (). RATE OF COMBUSTION / HEAT RELEASE

Indicated Thermal efficiency Temperature (K) Max Rate of Heat Release (J/) Rate of Heat Release (J/) The cylinder pressure was analyzed using a single zone heat release model, which gives the rate of heat release. Details concerning the model can be found in research by brunt et. Al. [6]. Figure 7 shows the rate of heat release. It can be noticed that the start of combustion is sensitive to the temperature history during the compression stroke. The mean temperature history in the combustion chamber is shown in Figure 8. It can be noticed from the Figure that the maximum temperature in the combustion chamber is for the richest mixture, which also demonstrated the highest rate of heat release. For all plots, the trace with the highest maximum rate of heat release corresponds to the operating condition with the richest mixture, as given by Figure 9, and the lowest rate of heat release corresponds to the leanest mixture (=.5). 6 8 6 - = =.5 = =.5-5 - - - - 5 Figure 7: Rate of heat release for different relative airfuel ratio mixtures combusting in HCCI mode 8 6 8 6 = =.5 = =.5-5 - - - - 5 Figure 9: Mean temperature history in the combustion chamber for different relative air-fuel ratio mixtures combusting in HCCI mode INDICATED THERMAL EFFICIENCY As the experiments were carried out with a twocylinder engine, which was converted to operate in HCCI mode on one cylinder only, brake thermal efficiencies can be measured with relatively lower confidence. The engine friction of the first cylinder working in HCCI mode becomes high compared to power produced from the same cylinder. Therefore only indicated efficiency calculations are reported in the present research. Gross Indicated thermal efficiency is defined as the ratio between the work on the piston during the compression and expansion stroke (W i,g ) to the input fuel energy. W ig, mq f ig, LHV Where m f is fuel mass per cycle and q LHV is the lower heating value of the fuel. Net Indicated Thermal Efficiency is the gross indicated efficiency adjusted for pumping work. It is the ratio between the work on the piston for all the four strokes, W i,n, to the input fuel energy. W in, mq f in, LHV Figure shows the measured Gross and net Indicated thermal efficiency. It shows that the indicated thermal efficiency decreases with increasingly rich mixture. In present study the maximum indicated thermal efficiency is achieved for =.5, for HCCI combustion mode. 6 8 6.5.5 Figure 9: Maximum rate of heat release for different relative air-fuel ratio mixtures combusting in HCCI mode 7 8 5 Gross Net.5.5 Figure: Measured indicated thermal efficiency for different relative air-fuel ratio mixtures Indicated specific fuel consumption (ISFC) is the ratio of fuel consumed and the indicated power. The indicated power is calculated from the pressure volume curve. The measured ISFC is shown in Figure. The figure shows that the minimum fuel consumption is for =.5. This observation is justified as the maximum

CO (g/kwhr) NOx (g/kwhr) HC (g/kwhr) ISFC (g/kwhr) indicated thermal efficiency is at the same air fuel equivalence ratio in the HCCI operating region. 5.5.5 Figure : Measured Indicated specific fuel consumption for ethanol fuel in HCCI mode EXHAUST GAS EMISSIONS Nitric oxide (NO) and nitrogen dioxide (NO ) are usually grouped together as NOx emissions. Nitric oxide is the predominant oxide of nitrogen produced inside the engine cylinder. The principal source of NO is the oxidation of atmospheric (molecular) nitrogen. The critical equivalence ratio for NO formation in high temperature, high pressure burned gases (typical of engines) is close to stoichiometric. Oxides of nitrogen are formed during combustion when localized temperatures in the combustion chamber exceed the critical temperature and molecules of oxygen and nitrogen combine. With the homogeneous combustion of a premixed charge, the temperature is expected to be same throughout the combustion chamber, except near the walls. This in combination with very lean mixtures gives a low maximum temperature during the cycle. NOx formation is very sensitive to the temperature history during the cycle. At temperatures over 8 K, the NOx formation rate increases rapidly with increased temperature. The NO formation rate is governed by Zeldovich mechanism [5]. Figure shows the NO x emission in the HCCI operating region. The trend shows that the NO x emissions decrease as the mixture become leaner. This is due to the lowering of the combustion chamber temperature which is also explained by mean gas temperature (Fig.8). It is also observed that the NO x emission over entire HCCI combustion region is extremely low (. g/kwhr)) as compared to the CI or SI engines. Unburnt hydrocarbons form as a consequence of incomplete combustion of the hydrocarbon fuel. The level of unburned hydrocarbons in the exhaust gas is specified in terms of the total hydrocarbon concentration expressed in PPM. Total hydrocarbon emission is a useful measure of the combustion inefficiency; it is not necessarily a significant index of pollutant emissions. Engine exhaust gases contain a wide variety of hydrocarbon compounds. Lower combustion chamber temperature prevents NOx formation, but at times, this becomes too low to fully oxidize the fuel, resulting in high-unburned hydrocarbons emission. Even if the mixture is well prepared and close to homogeneous, the combustion rate near the walls will probably be slower, due to higher heat loss from the walls. If we assume that the combustion rate is slower near the walls, much fuel in this region will not be able to burn completely, as the overall temperature decreases due to the volume increase during the expansion stroke. Large part of the HC emissions will probably originate from the wall regions [7]. Figure shows the HC emissions from the engine operating in HCCI mode. The trend shows that HC emissions increase when the mixture becomes leaner. Leaner mixture lowers the temperature of the combustion chamber, thus emitting higher hydrocarbons..5.... NOx HC.5.5 Figure : Indicated specific NO x and HC emissions for different relative air-fuel ratio mixtures in HCCI mode Carbon monoxide emissions from internal combustion engines are controlled primarily by the fuelair equivalence ratio. 8 6.5.5.5.5.5 Figure : Indicated specific CO Emission for different relative air-fuel ratio mixtures combusting in HCCI mode In HCCI mode, CO emission depends on relative air fuel ratio () and preheating of the intake charge. Close to the rich limit for HCCI and with early combustion phasing, very little CO is generated. However closer to the lean limit, higher CO is generated. With increased relative air-fuel ratio, CO increases drastically, as can be seen in figure. This depends mainly on the lower combustion temperature and the later combustion phasing. At the end of combustion, the temperature becomes too low for complete oxidation and high amount of CO is generated. CONCLUSIONS

The combustion and emission characteristic of HCCI engine were investigated on a modified two cylinder engine. The inlet air was supplied at º C temperature and the engine was operated at a constant engine speed of 5 rpm, fuelled with ethanol. Successful HCCI combustion is obtained for (-.5) range. HCCI mode operation of the engine is within a narrow load range of the engine. The maximum IMEP obtained during the experiment was. bar. Knocking starts in the engine for the charge richer than relative air fuel ratio and this is the upper combustion limit for HCCI mode. The coefficient of variation of IMEP is lower for richer mixture of air and fuel. The rate of heat release is high and hence combustion duration is shorter (less than ) for all the conditions of engine running in HCCI mode. The maximum Indicated thermal efficiency was found at relative air fuel ratio of.5. Extremely low NO x (almost negligible) was emitted from the engine during HCCI mode operation. The HC and CO emission is however higher. HC emissions decrease and CO emissions increase with increase in relative air-fuel ratio. REFERENCES. Onishi S., Jo S.H., Shoda K., Jo D.P., Kato S., Active Thermo-Atmosphere Combustion (ATAC) A New Combustion Process for Internal Combustion Engines, SAE Paper No. 795, 979.. Ishibashi Y., Asai M., Improving the Exhaust Emissions of Two-Stroke Engines by Applying the Activated Radical Combustion, SAE Paper No. 967, 996.. Najt P.M., Foster D.E., Compression-Ignited Homogeneous Charge Combustion, SAE, Paper No.86, 98.. Thring R.H., Homogeneous-Charge Compression- Ignition (HCCI) Engine, SAE Paper No.8968, 989. 5. Aoyama T., Hattori Y., Mizuta J., Sato Y., An Experimental Study on Premixed-Charge Compression Ignition Gasoline Engine, SAE Paper No. 968, 996 6. Yanagihara H.A., A Simultaneous Reduction of NOx and Soot in Diesel Engines under a New Combustion System (uniform bulky combustion system UNIBUS), 7th. Int. Motor Symposium, Vienna, 996. 7. Yokota H., Kudo Y., Nakajima H., Kakegawa T. Susuki T., A New Concept for Low Emission Diesel Combustion, SAE Paper No. 9789, 997 8. Christensen M., Johansson B., Einewall P., Homogeneous Charge Compression Ignition (HCCI) Using Isooctane, Ethanol and Natural Gas A Comparison with Spark-Ignition Operation, SAE Paper No. 9787, 997. 9. Christensen M., Johansson B., Amnjus P., Mauss F., Supercharged Homogeneous Charge Compression Ignition, SAE Paper No. 98787, 998. Walter B., Gatellier B., Near Zero NOx Emissions and High Fuel Efficiency Diesel Engine: the NADITM Concept Using Dual Mode Combustion, Oil & Gas Science and Technology, Rev. IFP, Vol. 58, No., pp. -,.. Takeda Y., Keiichi Na., Keiichi Ni., Emission Characteristics of Premixed Lean Diesel Combustion with Extremely Early Staged Fuel Injection, SAE Paper No. 966, 996.. Iwabuchi Y., Kawai K., Shoji T. Takeda Y., Trial of New Concept Diesel Combustion System-Premixed Compression-Ignited Combustion, SAE Paper No.999--85, 999.. Kimura S., Aoki O., Ogawa H., Muranaka S. Enomoto Y., New Combustion Concept for Ultra- Clean and High-Efficiency Small DI Diesel Engines, SAE Paper No. 999--68, 999.. Kelly-Zion, Peter L., Dec John E., A computational Study of the effect of the Fuel-Type on the Ignition Time in HCCI Engines, Proceedings of Combustion Institute. 8,. 5. Heywood J.B., Internal Combustion engine fundamentals, McGraw-Hill Book Company, NewYork, 988. 6. Brunt M.F.J., Rai H., Emtage, A.L., The Calculation of Heat Release Energy from Engine Cylinder Pressure Data, SAE Paper No. 985, 998. 7. Christensen M., Johansson B., Homogenous Charge Compression Ignition with Water Injection." SAE Paper No.999--8, 999. CONTACT Dr. Avinash Kumar Agarwal is currently working as Assistant Professor of Mechanical Engineering at Indian Institute of Technology, Kanpur since March. He is a 99 Mechanical Engineering graduate from MREC Jaipur. His area of doctoral research was developing biodiesel and related engine tribology investigations. Dr Agarwal joined Engine Research Center, University of Wisconsin, Madison, USA for pursuing his Post-Doctoral research from August 999 February. His main areas of current interest are combustion phenomenon study in IC engines, automobile emissions, biodiesel development and characterization, laser diagnostic techniques, PIV, lubricating oil consumption phenomenon, lubricating oil tribology, development of micro sensors, alternative fuels for diesel engines etc. Rakesh Kumar Maurya is a Graduate student working with Dr. Agarwal on his doctoral dissertation in mechanical engineering from IIT Kanpur. He completed his Dual Degree (B.Tech. and M.Tech.) from IIT Kanpur in Mechanical Engineering in year 6. His areas of interest include Internal Combustion Engines, Engine Instrumentation, HCCI Combustion, and emission control.