Shimadzu's Total Solutions for the Hydrocarbon Processing Industry

Analytical and Testing Instruments for the HPI Market Shimadzu's Total Solutions for the Hydrocarbon Processing Industry C10G-E067

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Shimadzu's Total Solutions for the Hydrocarbon Processing Industry (Petrochemical, Chemical) The Hydrocarbon Processing Industry (HPI), encompassing petroleum refining, gas processing, petrochemical and chemical, is a foundational field for all industry. In the HPI market, many kinds of analytical and measuring instruments are used for quality control purposes and process management. With a wide range of products, from GC and Elemental Analyzers to an On-line Water Quality Analyzer, Shimadzu offers total support for laboratories in the HPI market. From Upstream to Downstream, our rugged, high-quality products are perfectly suited to meet the demands of your laboratory and contribute to your business success. Upstream Developing, Extracting Exploration, Finding Transporting, Storage Supply, Trading Manufacturing, Refining Downstream For more information about Shimadzu's solutions for the HPI market, visit our website at: https://www.shimadzu.com/an/industry/petrochemicalchemical/index.html

Shimadzu Customized GC Analyzers Nexis GC-2030 Product Lineup Natural Gas Analyzers Refinery Gas Analyzer (RGA) Process and Custom Gas Analyzers TOGA/DGA Analyzer Petrochemicals analyzer ASTM D1945/D1946 UOP 539, ASTM D7833, ASTM D1946 ASTM D3612C ASTM GPA 2261, GPA 2177 D 2163 ASTM E1746 D6228 Applicable Methods GPA 2286, GPA 2186 ISO 6975 Analysis C1-C6+ Hydrocarbons, Non Condensable gases O2, N2, CO, CO2 and H2S Optional Hydrogen Extended NGA C1-C14+ C1-C6+ Hydrocarbons saturates and unsaturates H2S, Non Condensable gases O2, N2, CO, CO2 and H2 O2, N2, CO, CO2 Impurities in Chlorine TOGA with Head Space H2, O2, N2, CO, CO2, C1, C2's, C3's Trace Sulfur NGL, Dual Oven NGA LPG Sampling High Speed NGA Vaporizer Analysis time 10 min. Analysis time less than Special Hastelloy High Sensitivity PFPD for Sulfur 6 min. Material for Chlorine Analyzer Extension up to C4 Various Applications in the HPI Market Transformer Oil Gas Analyzer (TOGA) Support third-party detectors, including a pulsed flame photometric detector (PFPD) and a pulsed discharge helium ionization detector (PDHID). Support third-party software for detailed hydrocarbon analysis (DHA) and Chrom Merge. Support liquefied petroleum gas (LPG) sampling devices and vaporizers. Complete application manual and methods 4

Trace Moisture Analysis GC System Barrier Ionization Discharge (BID) Detector High Sensitivity Detection Sensitivity over 100 x Higher than TCD, 2 x Higher than FID Novel Universal Detector Single Detector Approach for Complex Analyses Long-Term Stability Long-Term Stability with New Discharge Design Quartz tube (dielectric substances) Column He plasma 15000 12500 10000 7500 5000 2500 0 uv BID 1. Easily analyzes both liquid and gas samples 2. Uses a variety of Watercol TM GC columns depending on the matrices 3. Uses a simple, high-sensitivity, and very stable low-cost GC detector LPG(Main) Water 25 ppm, RT= 14.3 min, S/N=350+ 2.5 5.0 7.5 10.0 12.5 15.0 17.5 20.0 min Note: With baseline subtraction Analysis of Water in LPG Simulated Distillation DHA Analyzers Oxygenates Analyzers Sulfur Analyzers Aromatics Analyzers ASTM D7096, D7213, D3710, D2887, D6417, D6352, D7500, D5307, D7169, IP 480, ISO3924 ASTM D5134, D6729, D6730, D6733 ASTM D4815,D7423 UOP 960 ASTM D6228 ASTM D5504 ASTM D5623 ASTM D3606, 5580 Boiling Point Distribution C1-C110 (As per method) C1-C14 Hydrocarbons PIONA Report C1-C4 Alcohols Trace Sulfur Analysis Individual components Aromatics Fast Simdist Correlations with D86 and D1160, Integrated Shimadzu Software Tuned D6730 column Fast DHA Front End PIONA Room Temperature Database Use of N2 Carrier for D4815 Use of FPD, PFPD or SCD Detectors Combination model for D3606, D5580. D4815 Simulated Distillation Analyzer C14 C16 C18 C20 C24 C26 C30 C32 C34 C36 C38 C42 C44 C46 C48 C50 C52 C54 C56 C28 C40 C68 C72 C76 C80 C84 C88 C92 C96 C100 C60 C64 C110 C12 ASTM D7500 Calibration Mix Shimadzu's Total Solutions for the Hydrocarbon Processing Industry Analytical and Testing Instruments for the HPI Market 5

Aromatics Analysis HPLC ASTM D 6591, D6379, IP 391, IP 436, IP 548, IP590 Aromatics in fuels Poly-aromatics in diesel FAME in jet fuel 200 190 180 Mono-Aromatics Di-Aromatics 170 160 150 140 130 Non-Aromatics 120 110 100 90 80 70 60 50 Switching Valve Configuration Super Performance and Expandability Precise Sample Injection 40 30 Tri-Aromatics 20 10 0 0.0 2.5 5.0 7.5 10.0 12.5 15.0 17.5 Aromatics Ref. Std. ASTMD6591 ASTM D5837 Components in transformer oil Furan Analysis HPLC Chromatogram View mav 15.0 PDA Ch1 Absorbance (220nm+/- 4nm) (+) Max Intensity : 7,116 Time 0.000 Inten. 0.015 12.5 10.0 7.5 Furfury alcohol/6.452 5.0 2.5 /5.102 /7.233 /8.414 /9.378 0.0 0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 min mav Max Intensity : 14,654 15.0 PDA Ch2 Absorbance (282nm+/- 4nm) (+) Time 2.044 Inten. 0.029 12.5 10.0 7.5 5.0 2.5 0.0 5-hydroxymethyl-2-furaldehyde/5.102 2-furaldehyde/7.233 /7.233 2-furaldehyde/8.414 /8.414 /8.414 5-hydroxymethyl-2-furaldehyde/9.388 Fully Integrated System Network Connectivity High Sensitivity Detector 0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 min Furan Chromatogram 6

LC / MS / MS Additives in polymers LCMS-8060 High Speed and High Sensitivity Scan Speed 30000u / sec MRM 555 Ch / Sec EPA 8270B, TO -14, IP-585 MS Chromatograms of Polymer Additives Analysis of Additives in Plastic VOCs Analysis GC-MS Volatile organic compounds Arsine phosphine in ethylene FAME in jet fuel HS-20 Headspace Analysis System GCMS-QP2020 NX Accessories HS, TD and P&T High Sensitivity and Reduced Cost High Efficiency Multicomponent Analysis TD-30 Thermal Desorption System Shimadzu's Total Solutions for the Hydrocarbon Processing Industry Analytical and Testing Instruments for the HPI Market 7

Inductively Coupled Plasma Mass Spectrometer (ICP-MS) Customized Trace elements in naphtha Determination of toxic arsenic species using LC-ICP-MS AsV AsIII DMAs AsB Arsenic Chromatogram Easy Method Development Lowest Running Costs High Stability, High Sensitivity and Low Interference Elemental Analysis ASTM D4951, D5184 ASTM D4951,D5184 UOP 389, UOP 303 UOP 714, APHA 3120, IFP 9507 All elements Lubricating oils Petroleum naphtha, gasoline Marine fuel, fuel oil, heavy oils ICP Atomic Emission Spectrometer (ICPE) Cr 267.716 Cond 2 Intensity Intensity ICPE-9800 Series Cr in Naphtha with ISO Mist Kit Easy Method Development Low Argon Consumption All Wavelength Acquisition 8

Atomic Absorption Spectrophotometer (AAS) ASTM D6595, D3237, D3567, D3605, D3635, D3831, D3919, D4628, IFP9312, UOP946, D5863 Additives in polymers All elements Lubricating oil Petroleum oils Lead in gasoline Abs 0.200 Unique 3D Double Beam Optics AA-7000 Comprehensive Safety Functions Dual Background Correction Functions 0.100 0.000 0.000 5.000 10.000 15.000 20.000 Conc(NONE) Abs=0.011100Conc+0.0043463 r=0.9989 Arsenic in Vacuum Gas Oil (VGO) ASTM D5839, ASTM D4294, C114 ISO 8754 Sulfur in oil All elements Energy Dispersive X-ray Fluorescence Spectrometer (EDX) 004 10.0 Measured Intensity (cps/ua) 8.0 6.0 4.0 2.0 002 003 EDX-7000/8000/8100 001 0.0 0.0 50.0 100.0 150.0 200.0 250.0 300.0 Standard Value (ppm) High Sensitivity, High Speed and High Resolution Large Sample Chamber Easy-To-Use Operation Zn in Lubricant Oil Shimadzu's Total Solutions for the Hydrocarbon Processing Industry Analytical and Testing Instruments for the HPI Market 9

Fourier Transform Infrared Spectrophotometer (FTIR) D7371, EN 14078, D7575, D7678 Fame in biodiesel Total petroleum hydrocarbons Additives in polymers Oil in water 1.2 Abs 1.0 0.8 CSD1 CSD2 CSD3 CSD4 CSD5 CSD6 CSD7 Concentration Sample Absorbance [ppm] Height CSD1 0.0020 0.73 IRSpirit 0.6 0.4 CSD2 0.026 4.54 CSD3 0.096 15.23 CSD4 0.28 40.56 0.2 0.0 r=1.0 CSD5 0.60 87.57 CSD6 0.87 127.55 CSD7 1.2 168.70 3100 3080 3060 3040 3020 3000 2980 2960 2940 2920 2900 2880 2860 2840 2820 2800 2780 2760 2740 2720 cm -1 Space Efficient with High Expandability Dedicated IR Pilot Program High Reliability Enlarged View of Peaks Around 2920 cm -1 Calibration Curve and Standard Sample Concentrations Analysis of Oil in Water ASTM D1840, D2008 Petroleum products Turbine fuels Mineral oils UV-VIS Spectrophotometer (UV-Vis) 100 0.90 0.80 80 0.70 Transmittance (%) 60 40 20 y 0.60 0.50 0.40 0.30 0.20 0.10 UV-1900 0 380 500 600 700 780 Wavelength (nm) Transmittance Spectra of Colored Cellophane Tape 0.00 0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 x Chromaticity Diagram of XY Color System Analysis of Colored Cellophane Tape Easy Operation Allows Obtaining Answers Rapidly Advanced Regulatory Compliance High Performance to Meet Diverse Needs 10

Thermal Analyzers ASTM D3417, D3418, D4419, D4591, D5483, ASTM D3850, D6370, D6375, Thermal properties of polymers DSC, TGA, TG/DTA, TMA DSC mw 40 HDPE -203.67 J/g DSC-60 Plus 30 20 10 132.9 C 20.00 C 144.90 C 175.00 C PP 69.76 J/g -95.46 J/g 163.4 C 20.00 C 144.90 C 175.00 C Blend (PE8-PP2) 160.5 C 869.90 mj 72.04 mj High Performance DSC / TGA Diverse Measurements by Simple Operations High Sensitivity -0 135.5 C -0 50 100 150 200 Temp [ C] DSC Curves of HDPE, PP, and Blend Sample ASTM D5412, JPI-5S-71-2010 Measuring oil in water Coumarin in diesel Spectrofluorophotometer 150000.0 Calibration Curve Fluorescence Intensity 100000.0 50000.0 Fluorescence Intensity RF-6000 0.0 390.0 450.0 500.0 550.0 600.0 630.0 nm Coumarin in Diesel Concentration (mg/l) High Sensitivity High Stability and High Speed High Speed 3D Scanning Fluorescence Quantum Yield and Fluorescence Quantum Efficiency Measurement Shimadzu's Total Solutions for the Hydrocarbon Processing Industry Analytical and Testing Instruments for the HPI Market 11

Total Organic Carbon (TOC) Analyzer ASTM D7573, EN 1484, EPA 415.1 APHA 5310B TOC in various types of water, including high salt content water TOC-L Series 680 DegC Combustion Method High Salt Kit Standalone System TOC in Brine Solution TOC in various types of water On-line TOC Analyzer 0,35 0,3 0,25 NPOC in mg/i 0,2 0,15 0,1 0,05 0,00 1 20 39 58 77 96 115 134 153 172 191 210 229 248 267 Number of Measurements TOC Analysis in Condensate Sample Mean Value 0.208mg/L, SD 0.006mg/L, DL 0.05mg/L Superior Sampling Units Low Operation Costs Low Maintenance Costs 12

Testing Machines ISO 6892, ISO 527, ASTM D638 Tensile properties of metals Tensile properties of plastics 100 90 80 PP_1 PC_1 PVC_1 70 Stress (N/mm 2 ) 60 50 40 AG-Xplus Series 30 20 10 Short Test Cycle Time Ultrafast Sampling Rate Eight Fold High Resolution 0 0 10 20 30 40 50 60 70 80 90 100 110 120 Displacement (Strain) (%) Tensile Test of PP, PV, PVC Various petrochemicals streams Particle Size Analyzer Polystyrene Latex : 50nm, : 100nm, : 50nm + 100nm Normalized Particle Amount Particle Diameter (nm) SALD-2300 Normalized Particle Amount Particle Diameter (nm) Samples with Broad Distribution Wide Range 17nm-2500um Wide Range of Accessories High Sensitivity / High Concentration Shimadzu's Total Solutions for the Hydrocarbon Processing Industry Analytical and Testing Instruments for the HPI Market 13

Shimadzu Analytical Network Data System LabSolutions CS Controlling other vendor s GC and HPLC using LabSolutions DB/CS Client PC *2 ipad *3 Laboratory or office LabSolutions server Acquisition controller PC *1 Acquisition controller PC Shimadzu LC Shimadzu GC Shimadzu LC Shimadzu GC Agilent LC Agilent GC Agilent LC Agilent GC *1 The acquisition controller PC controls the analytical instruments. Analysis directions and re-analysis of data can be performed using a client PC. *2 It is not necessary to install LabSolutions software on the client PC for terminal service. *3 When using an ipad, the installation of Citrix s XenApp is required. ipad is a registered trademark of Apple Inc. Simple User Interface Agilent LC method editing Agilent LC batch editing Agilent LC analysis monitoring Launcher window Agilent GC method editing Agilent GC batch editing Agilent GC analysis monitoring 14

Fourier Transform Infrared Spectrophotometer IRSpirit IRSpirit, Ready to Run IRSpirit offers the highest S/N ratio in its class and high reliability using the technology inherited from the high-end model. The dedicated IR Pilot program simplifies routine analyses for all users. Gas Chromatograph The Next Industry Standard Nexis GC-2030, Shimadzu's premier gas chromatograph, offers a modern approach to a classic chromatographic technique. Designed with the user in mind, new innovative features, exceptional performance and high-throughput capabilities will elevate your lab to the next level. 15

Shimadzu's Total Solutions for the Hydrocarbon Processing Industry www.shimadzu.com/an/ For Research Use Only. Not for use in diagnostic procedures. This publication may contain references to products that are not available in your country. Please contact us to check the availability of these products in your country. Company names, products/service names and logos used in this publication are trademarks and trade names of Shimadzu Corporation, its subsidiaries or its affiliates, whether or not they are used with trademark symbol TM or. Third-party trademarks and trade names may be used in this publication to refer to either the entities or their products/services, whether or not they are used with trademark symbol TM or. Shimadzu disclaims any proprietary interest in trademarks and trade names other than its own. The contents of this publication are provided to you as is without warranty of any kind, and are subject to change without notice. Shimadzu does not assume any responsibility or liability for any damage, whether direct or indirect, relating to the use of this publication. Shimadzu Corporation, 2018