Light-Duty SI Engine Technologies and the Impact of Higher Carbon Alcohol Fuels

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1 Sustainable Fuels and Clean Vehicles Light-Duty SI Engine Technologies and the Impact of Higher Carbon Alcohol Fuels Jeffrey D. Naber APSRC Center Director Ronald and Elaine Starr Professor of Energy Systems in ME jnaber@mtu.edu

Spark-ignition engines undergoing rapid development and technology integration Direct-injection, advanced ignition, charge control via flexible cam systems, and boosting downsizing downspeeding, Ethanol an important US biofuel as a blend over the past decade US Renewable Fuel Standard (RFS2) requires an increase in the use of advanced biofuels of up to 36 billion gallons by 2022. Longer chain alcohols, cellulosic ethanol and synthetic biofuels, can meet demand while adhering to the RFS2 corn-based ethanol limitation. Higher carbon number alcohols can be utilized to improve the energy content, knock resistance, and petroleum displacement of alcohol blends in comparison to higher ethanol blends (>E15) 2

3 FUEL CONSUMPTION (CO 2 EMISSIONS) REGULATED EMISSIONS (NO X, HC, CO, PM)

CO 2 (Fuel Consumption) Regulations Grams (CO 2 / km) 140 g CO2 /km 40 mpg 9.5 L/100km 56 mpg e 2000 2005 2010 2015 2020 2025 CO 2 Fuel Consumption (l/100km) 1/MPG Tank to Wheels Only

Emissions Regulations US Emission Standards* European Emission Standards PZEV = SULEV levels with no evaporative emissions *Standards in g/mi converted to g/km EPA Tier II - Different Bins Must Meet Fleet Average CARB LEVIII EPA TIER III Different standards for gasoline and diesel Euro 6 (PM + PN)

Emissions Standards Future US 6 US Tier II CARB LEV III US Tier III (Proposed) 120,000 Miles 150,000 Miles 150,000 Miles Phase in: 2004-2009 Phase in: 2015-2025 Phase in: 2017-2025 Emission Category NMOG +NOx PM Emission Category NMOG +NOx PM Emission Category NMOG +NOx 8 325 20 LEV160 160 10 Bin 160 160 3 7 240 20 ULEV125 125 10 Bin 125 125 3 6 190 10 ULEV70 70 10 Bin 70 70 3 5 160 10 ULEV50 50 10 Bin 50 50 3 4 110 10 SULEV30 30 10 Bin 30 30 3 3 85 10 SULEV20 20 10 Bin 20 20 3 2 30 10 Bin 0 0 0 1 0 0 * mg/mile * mg/mile * mg/mile Fleet Average Fleet Average by 2025 Fuel Sulfur: 30 ppm Extremely low emissions gasoline vehicles since 2004 (SULEV) Fleet standard reduction of 5x (160 30) Fuel Sulfur: 10 ppm Bin 160 = Tier II Bin 5 Bin 30 = Tier II Bin 2 PM

Emission Standards EU & China EU Emissions Standards EURO5 (2009) Beijing () EURO6 (2014) Emission Category HC +NOx PM 4 (CI) 483 300 40 25 NA 4 (SI) 290 180 NA NA 5 (CI) 370 230 85 NA 5 (SI) 257 160 85 NA 6 (CI) 274 170 85 10 10 6 10 11 6 (SI) 257 160 85 10 10 6 10 11 China EURO4 (2008-) 62,000 100,000 miles km * mg/mile mg/km Fuel Sulfur: <10 ppm (2009) Cetane #: 51 Higher Diesel Fuel Quality High NOPN X and Differing CI / SI Emissions Standards Promote diesel LDV LEV III == SULEV LEV III << EURO6 US Tier III (Proposed) 150,000 Miles Phase in: 2017-2025 Emission Category NMOG +NOx PM Bin 160 160 3 Bin 125 125 3 Bin 70 70 3 Bin 50 50 3 Bin 30 30 3 Bin 20 20 3 Bin 0 0 0 * mg/mile Fleet Average by 2025 Fuel Sulfur: 10 ppm Bin 160 = Tier II Bin 5 Bin 30 = Tier II Bin 2 7

Air Quality Index 8 AQI Classification PM 10 PM 2.5 NO 2 (Rating) (Rating) (ug/m 3 ) (ug/m 3 ) (ppm) 0 50 Good 0 54 0 15.4 0-51 100 Moderate 55 154 15.5 40.4 - - 101 150 Unhealthy (Sensitive) 155 254 40.5 65.4 - - 151 200 Unhealthy 255 354 65.5 150.4-0.64 201 300 Very Unhealthy 355 424 150.5 250.4 0.65 1.24 300 401 Hazardous 425 504 250.5 350.4 1.25 1.64 401 500 Hazardous (No data) 505 604 350.5 500.4 1.65 2.04 US EPA Guidelines for the Reporting of Daily Air Quality - the Air Quality Index (AQI) EPA-45/B-06-001 May 2006

US Tier 0 5000 Air Quality US US Tier I US Tier II CARB LEV III US Tier III 9 4000 All US Cities Days AGI>100 3000 2000 1000 0 1990 1992 1994 1996 1998 2000 2002 2004 2006 2008 2010 Year http://www.noaanews.noaa.gov/stories2012/20120809_laairqualitystudy.html

10 LDV POWERTRAIN TECHNOLOGIES

Log Scale Vehicle Energies 11 COST vs Savings

US Spark-Ignition Engines LDV Powertrain Technologies Production Share SI engines dominate US and will like continue to dominate LDV powertrains for the next several decades Lowest cost Lowest emissions Diesel vs gasoline fuel cost differential will likely widen Fuel Flexibility: Ethanol, NG, Synergies with HEV s Improving efficiency; however, disadvantage to CI Further enhancement required EPA-420-R-12-001, 2012

13 ALTERNATIVE FUELS FOR SI ENGINES

US Renewable Fuels 14 SI Fuel Consumption Remains Flat Increased driven miles offset by FE Improvements RPS2 Fraction Nears 30% Wallner et al. Argonne / MTU

Ethanol Blends Characterized and Modeled 15 Crank start combustion and emissions Compression Ratio Impacts & optimization High Dilution (Cam Phasing and Cooled EGR) Predictive combustion for engine simulation Ignition systems E00 E10 E20 E50 E85 CR 11.0 CR 12.5 CR 14.0 CR 15.5 CR 17 CR 18.5

Alcohol Properties 16 Wallner et al. Argonne / MTU

Optimal Alcohol Blends RON [-] #1B Eth. equiv. 95 15-20 20-25 94 > 25 E15 93 #1C E10 #1A 92 40.1 40.4 40.7 41 41.3 LHV [MJ/kg] RON [-] 98 96 94 #2B E25 #2C Eth. equiv. 25-30 30-35 > 35 E15 #2A 92 38.4 38.8 39.2 39.6 40 40.4 40.8 LHV [MJ/kg] Can exceed E10 LHV, E15 RON, or E25 PD. Can exceed E15 LHV, E25 RON, or E35 PD. Lawyer et al. Argonne / MTU

Summary 18 Combined CO 2 and Emissions Reduction Challenges & Opportunities for LDV Emissions reduction factor in improving air quality SI engines can meet current and future emissions regulations (NMOG/NO X /PM) but significant reduction in CO 2 required. Advanced engine technologies Alternative fuels including alcohol blends (CO 2 credits) Electrification (HEV) and vehicle technologies (light weight materials, advanced trans, )

20 THANK YOU