EFFICIENCY OPTIMIZATION OF TRIBOSYSTEMS BY SILICON COATING

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EFFICIENCY OPTIMIZATION OF TRIBOSYSTEMS BY SILICON COATING Wind Energy Automotive Marine Industry

Content Company and Products Technology Scientific tests 2-disc Sealing durability Pin on disc Examples of applications (dyno test) Conclusion Next steps

REWITEC COMPANY AND PRODUCTS

Establishment in 2003 Developer, manufacturer and distributor of nano and micro particle based surface refinement products for the protection and the repair of tribologic systems Patents Europe, China, US application World wide sales network, office in Chicago Founder and Managing Partner: Stefan Bill

Target Markets WIND ENERGY - ONSHORE - OFFSHORE INDUSTRY - STEEL - CEMENT - MINING - OIL, GAS SHIPPING - MARINE - INLAND - YACHTS - SUBMARINE AUTOMOTIVE - CONSUMER - OEM - MOTORCYCLES - RACING - OLDTIMER

The coating process Step 1 Chemical-physical process The product uses the lubricant as carrier to the mixed friction zones Step 2 Chemical reaction The coating particles ceramize the metal surfaces in mixed friction zones Step 3 New metal-ceramic surface Original material properties will be improved in terms of friction, temperature and wear significantly

REWITEC IN ACTION SCIENTIFIC TESTS

Competence Center of Tribology Mannheim-Germany 2-Disc Assembly Rolling Wear Tests Stress value: 1 GPa (normal force 2150 N) Rotating speed: 424 rpm / 339 rpm, slip 20 % Test-duration: 39,3 h Temperature: oil inlet temperature 60 C

2-Disc assembly rolling wear test wind turbine oils Castrol Optigear X320 with REWITEC added after 19 hours 39 minutes R z, before = 2,389 µm R z, after = 1,129 µm (-53 %) R a, before = 0,360 µm R a, after = 0,180 µm (-50 %)

2-Disc assembly rolling wear test wind turbine oils Castrol Optigear X320 without REWITEC R z, before = 2,389 µm R z, after = 1,663 µm (-30 %) R a, before = 0,360 µm R a, after = 0,285 µm (-21 %)

2-Disc assembly rolling wear test wind turbine oils Castrol Optigear X320 with REWITEC R z, before = 2,389 µm R z, after = 1,024 µm (-57 %) R a, before = 0,360 µm R a, after = 0,151 µm (-58 %)

2-Disc assembly rolling wear test wind turbine oils Red graph without REWITEC Blue graph with REWITEC added after 20 hours Green graph with REWITEC added at the beginning Reduction of the surface roughness (R a ) due to wear up to 58 % Reduction of the friction force up to 22 %

2-Disc assembly rolling wear test wind turbine oils Castrol Optigear Synthetic X320 Mobilgear SHC XMP 320

2-Disc assembly rolling wear test wind turbine oils Klübersynth GEM 4-320N Fuchs Unisyn CLP 320

2-Disc assembly rolling wear test wind turbine oils Amsoil PTN 320 Shell Omala S4 GX 320

2-Disc assembly rolling wear test wind turbine oils Klüberbio EG 2-150

2-Disc assembly rolling wear test grease test FAG Arcanol Multitop grease Hertzian Stress: Rotational Speed: Slip: 15 % Duration: 40 h 1700 N 212 min -1 and 180 min -1

2-Disc assembly rolling wear test wind turbine oils Overview Measured data Oil grade Castrol Optigear Synthetic X320 Mobilgear SHC XMP 320 Klübersynth GEM 4-320N Klüberbio EG 2-150 Fuchs Unisyn CLP 320 Amsoil PTN 320 Shell Omala S4 GX 320 R a, before [µm] 0,22 µm 0,22 µm 0,22 µm 0,22 µm 0,22 µm 0,22 µm 0,22 µm R a, after [µm] 0,129 µm 0,123 µm 0.100 µm 0.133 µm 0.109 µm 0.180 µm 0.165 µm R a, Reduction [%] 41 % 44 % 54 % 40 % 50 % 18 % 25 % R z, before [µm] 2,00 µm 2,00 µm 2,00 µm 2,00 µm 2,00 µm 2,00 µm 2,00 µm R z, after [µm] 1,52 µm 1,18 µm 0.91 µm 1,04 µm 1.02 µm 1.51 µm 1.42 µm R z, Reduction [%] 24 % 41 % 55 % 48 % 49 % 25 % 29 % Friction Force, before 62.9 N 63,3 N 73.5 N 120,0 N 69 N 81.8 N 81 N Friction Force, after 42.6 N 41,0 N 44,0 N 54,0 N 44,0 N 44,0 N 47,0 N Reduction Friction Force 33 % 35 % 40 % 55 % 36 % 46 % 42 %

2-Disc assembly rolling wear test steel vs. phosphated discs 2-Disc Assembly Rolling Wear Tests with VW first fill manual gearbox oils Stress value: 1 GPa (normal force 2150 N) Rotating speed: 424 rpm / 339 rpm, slip 20 % Test-duration: 39,3 h Temperature: oil inlet temperature 60 C

2-Disc assembly rolling wear test steel vs. phosphated discs Left: Right: Standard steel disc Phosphated disc

2-Disc assembly rolling wear test steel vs. phosphated discs Left picture: Standard steel disc without REWITEC Right picture: Phosphate disc without REWITEC

2-Disc assembly rolling wear test steel vs. phosphated discs Left picture: Standard steel disc with REWITEC Right picture: Phosphated disc with REWITEC Difference of the surface roughness up to 77 %

2-Disc assembly rolling wear test steel vs. phosphated discs without REWITEC with REWITEC Reduction of the wear up to 9 % Reduction of the friction force up to 28 %

2-Disc assembly rolling wear test steel vs. phosphated discs VW G 052 527 A2 with REWITEC added after 19 hours 39 minutes Graph with REWITEC steel-steel discs Reduction of the friction force compared to phosphated discs: 51 % without REWITEC 33 % with REWITEC

2-Disc assembly rolling wear test Engine oil Test parameters: Test specimens Camshaft manufacturer Test period Lubricant Test discs from previously damaged camshaft German engine manufacturer 40 h Engine Oil SAE 10W-40 of the engine manufacturer

2-Disc assembly rolling wear test Engine oil before Camshaft disc before testing with REWITEC : Heavy grooves in the right section before the test-run after Camshaft disc after testing with REWITEC : Grinding pattern completely disappeared Grooves significantly reduced Significant reduction of friction

2-Disc assembly rolling wear test Engine oil Without REWITEC With REWITEC Upper graph without REWITEC Lower graph with REWITEC Reduction of the friction force up to 45 % Reduction of the surface roughness up to 73 %*) *) 50% less surface roughness can lead to a 20-fold life expectancy thesis of Dr.-Ing. Michael Gleß.

Sealing Durability of Radial Shaft Seals

Sealing Durability of Radial Shaft Seals Test 1: Engine oil (10W-40) without REWITEC Test 2: Engine oil (10W-40) with REWITEC None of the test pairings showed significant signs of abrasion

Sealind Durability of Radial Shaft Seals Test 1: Engine oil (10W-40) without REWITEC Test 2: Engine oil (10W-40) with REWITEC None of the test pairings showed significant signs of abrasion

Pin-on-disc test Micro Tribometer Electrical motor Heatable oilsump Tribological contact (bearing ball on a plan steel plate) Spring system to adjust normal force

relative friction Scientific tests Pin-on-disc test Initial run-in of contact Additive is added 2 nd run-in process Measurement procedure: I. Run-in of the contact until stable interface conditions are established II. Additive is added Stable interface conditions after run-in Decrease of friction due to additive (schematic representation of typical measurement) Figures shown later focus on this region III. 2 nd Run-in : improved tribo-contact is developed due to additive effects IV. New stable interface conditions are established V. Difference of friction levels before and after additiv addition: Reduction of friction due to additive

Pin-on-disc test Exxon Marine Oils Oil Mobilgard 412 for A/E Oil Mobilgard 300C for M/E Circ. Oil Mobilgard 5100 L.O. Cyl. Parameter: 70 C; 7 N; 2,500 min -1

Pin-on-disc test Honda Engine Oils Following very low viscosity oils were tested with REWITEC : Motor oil Honda Ultra Next: 0W-8 Motor oil Honda Ultra Green: 0W-25

Pin-on-disc test Honda Engine Oils Honda Ultra Next motor oil Room temperature; load 5 N; 4000 min -1 Friction reduction 30 % after 1 hour

Pin-on-disc test Honda Engine Oils Honda Ultra Green engineoil Room temperature; load 5 N; 4000 min -1 Honda Ultra Green engine oil 70 C; load 5 N; 4000 min -1 friction reduction 35 % after 1 hour friction reduction 27 % after 1 hour

Examples of application: Coating and analysis of a generator on a ship Task: Fuel saving Result: In long-term testing with certificated measurement instruments, the following was noted: Significant fuel savings in the tested diesel generator Daihatsu 6 DK28 up to 14.000,- US$ per year

Examples of application: Coating and analysis of a diesel generator Task: Fuel saving Result: In long-term testing with certificated measurement instruments, the following was noted: Up to 9 % fuel savings in the tested diesel generator

Examples of application: Nissan GT-R R32 engine treatment by M. Krumm Test dynamometer: Dynapack Chassis Dynamometers Evolution 3000 Baseline: 281 BHP / 348 Nm Treatment with REWITEC PowerShot L (29.01.2016) Improvement after 2 h: +16 BHP / 15 Nm Additional transmission treatment with REWITEC G5 (30.01.2016) Complete end-result-improvement after 6 weeks: +28 BHP

Examples of application: Nissan GT-R R32 engine treatment by M. Krumm 29.01.2016 17.03.2016 29.01.2016

Conclusion Up to 55% less friction and 54% less surface roughness (Ra) in 2-disc tests with gear lubricants Up to 35% less friction in Pin-on-disc tests with engine lubricants Very thin tribo layer with a high ratio of Si and Al in SNMS analyses (Secondary Neutral Mass Spectrometry)

Next Steps Detailed engine tests: Bench tests at Ruhruniversität Bochum Fuel efficiency, emissions FIB Micro sections for more detailed tribo layer analyses Further product formulation optimization for engine applications

Many thanks FOR YOUR ATTENTION

Dr.-Hans-Wilhelmi-Weg 1 35633 Lahnau, Deutschland Telefon: +49 (0) 6441 / 445 99-0 E-Mail: info@rewitec.com www.rewitec.com Visit us on Facebook or YouTube.