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Characteristics of PM Emissions of an Automotive Diesel Engine Under Cold Start and Transient Operating Conditions Dai Liu, Jianyi Tian and Hongming Xu School of Mechanical Engineering 24 May 2014 Cambridge Particle Meeting

Outline of Presentation Background Objectives Experimental Setup Fuel Property Results and Discussion Conclusions 2

Background Cold (warm) start and transients are frequent occurrences of vehicle driving Poor engine performance and high emissions are expected during the start and transient operation Research of transients (concerning PM) using advanced instrumentation is so far limited Bio-fuels are used widely in practical application 3

Objectives To improve understanding of the characteristics of combustion and emissions under cold start and transient conditions in a CR diesel engine To research the effect of using different bio-fuels blends (RME and HVO) on PM emissions during cold start and transient period To quantify the effect of engine coolant temperature on PM during the engine start 4

Test Conditions Test mode Initial condition Final condition Cold start Ambient soaking for >9h to 20 C 2 min steady idling Warm start With engine coolant heat up to 90 C 2 min steady idling Mode 1-3 750 RPM, 36 Nm 1500 RPM, 143 Nm Mode 2-3 1500 RPM, 72 Nm 1500 RPM, 143 Nm Mode 2-4 1500 RPM, 72Nm 2000 RPM, 167 Nm Engine tests were conducted in 5s, 8s and 12s transient period for each test mode Cumulative data for 12s transient test were calculated for 15s in order to cover all the transient recovery period 5

Engine and testing rig Bore X Stroke Swept Volume Max CP Max Power Max Torque Max Speed Injection Type Max Inj Press 84.0 mm X 90.0 mm 2993 cc 180 bar 199 KW @ 4000rpm, 475Nm 600 Nm @ 2000rpm 5000 rpm @ no Load CRDI 2000 bar New Ford/JLR Lion 3.0L V6 diesel (Twin turbo, CR) Programmable Dyno and AVL combustion analyser Capable for full speed and full load operation: Constant intake air temperature programmable between 18-25 o C ± 1 o C 6

Emission measurement equipment DMS500 Dilution ratio Cold/Warm start Primary Second 4:1 500:1 Mode 1-3 4:1 180:1 Mode 2-3 4:1 180:1 Mode 2-4 4:1 120:1 7

Experimental system 8

Fuel Properties Fuel Properties Unit Mineral diesel RME30 RME60 RME100 HVO60 Cetane number 56.7 57.8 60.3 61.2 64.3 density Kg/m3 832.7 847.9 863.3 883.3 798.7 net heat of combustion Viscosity @ 40 C Oxygen Content MJ/kg 42.72 40.76 38.98 36.41 43.66 10-3Pa.s 3.6 4.3 5.27 6.77 3.43 % 0 4.6 7.8 10.8 0 Fuels Data Provided by Shell Company 9

Cold and warm start 10

Cold start with mineral diesel

Cold start with mineral diesel NO and HC emissions peaked at around 1s RME produced the maximum NO and lowest HC peaks

PM emissions of cold start with different fuels Acceleration period (0.7-1.3s): Nucleation: RME60=Mineral diesel=hvo60; Accumulation: RME60<Mineral diesel<hvo60. Idling period (after 1.3s): Nucleation: RME60<Mineral diesel<hvo60; Accumulation: HVO60<Mineral diesel=rme60. 13

Particulate distributions from time 0.8s-1.3s Particulates roughly divide to two phase: accumulation particulate (diameter between 50nm-300nm), nucleation particulate (diameter less than 40nm) With high injected fuel quantity and low air flow inlet initially, the emission of large particulates increased, the emission of small particulates decreased. Combustion of RME60 produce lowest particulate emission. 14

Particle distribution from time 1.4s-1.8s With engine conditions getting steady, large particulates were oxidized and the size of emitted particle was decreased. When the size distribution got steady, the combustion of HVO60 produced the lowest particle emission while the combustion of RME60 produced the highest particle emission. 15

Relative cumulative PM in the first 10s PM of using all fuels decreased. But for HVO60, with lowest PM emissions at cold start, produced highest PM at warm start. 16

Transient 17

Transient conditions Diesel AFR (a) and Intake Air with Fuel Injection (b) for Mode 1-3 (750RPM, 36Nm-1500RPM, 143Nm in12s) 18

Emissions for Mode 1-3 (12s) The spike size (peak to initial ratio) decrease with the increasing NO biodiesel decreased blend slightly ratio and increased during acceleration. B100 produced the The highest length NO of the transient recovery period decreased with the biodiesel THC blend ratio increased increasing. slightly and decreased during acceleration. B100 produced the lowest THC. 19

Emissions for Mode 2-3 (12s) The initial decrease of NO was small compared with previous test. B100 produced the highest NO The initial increase of THC was small compared with previous test. B100 produced the lowest THC. Recovery period characteristics as same as mode 1-3 The spike size (peak to initial ratio) became smaller when biodiesel blending ratio increased The PN spike almost disappeared for B100. 20

Emissions for Mode 2-4 (12s) NO emissions for all fuels are almost the same initially. B100 produced the highest NO and lowest THC during acceleration. The duration of the recovery period decreased with the biodiesel blending ratio increasing The spike size (peak to initial ratio) lower than mode 1-3 21

Comparison between different modes Mode 2-4 emitted highest particles then the other two Mode 2-3, B100 emitted extremely low PM emission, nearly 75% less than B0 PN of both B30 and B0 were almost the same for each mode 22

Comparison between different fuels The spikes peak value ratios between the different recovery period are nearly the same. B100 has the shortest recovery period difference compare with the others 23

Conclusions Cold and warm start 1. Low PN was observed with using RME60 during the acceleration period of the cold start. However, the level of nucleation particles with using RME60 was similar to that of mineral diesel. 2. During the acceleration period of the cold start, using of HVO60 produced slightly higher accumulation particles but almost halved nucleation particles with respect to using of mineral diesel. 3. As engine coolant temperature was increased, the emissions of PM were decreased for all the fuel. However, at warm start, the combustion of biodiesel led to higher PM than the cases of using mineral diesel, due to the fuel impinging effect. 24

Conclusions Transient conditions 1. As biodiesel blending ratio increased, PN decreased for all the three transient conditions. 2. Due to turbocharger lag problem, AFR was highly influenced during the entire transient recovery period. 3. Spikes in transient PM were observed in all the transient tests. The ratio between the maximum PN and its initial value (i.e. the size of spikes) decreased with biodiesel blending ratio increasing. 4. The duration of the PM emission recovery period decreased with biodiesel blending ratio increasing for all the engine transient tests. 5. The engine with higher initial/final engine load and speed operating conditions emitted smaller PN spikes compared with low speed and load engine transient operation. 25

Acknowledgement The authors would like to thank Jaguar Land Rover and Shell Global Solutions UK, for their generous support and contribution to our on-going research in the University of Birmingham. The work is also financially supported by the European Regional Development Fund and Advantage West Midland. Technical support from CAMBUSTION with respect to the setup and maintenance of the emissions measurement equipment is also acknowledged. 26

Contact Professor Hongming Xu Head of Vehicle and Engine Technology Research Centre School of Mechanical Engineering University of Birmingham, B15 2TT, UK Tel: ++44 121 414 4153; Email: h.m.xu@bham.ac.uk http://www.eng.bham.ac.uk/mechanical/about/people_xu.shtml 27

Thanks for your attention Questions? 28