CONFERENCE ON AVIATION AND ALTERNATIVE FUELS

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CAAF/09-IP/11 19/10/09 English only CONFERENCE ON AVIATION AND ALTERNATIVE FUELS Rio de Janeiro, Brazil, 16 to 18 November 2009 Agenda Item 1: Environmental sustainability and interdependencies IMPACT OF ALTERNATIVE FUELS ON AIRCRAFT ENGINE EMISSIONS (Presented by the International Coordinating Council of Aerospace Industries Associations) SUMMARY Engine and aircraft manufacturers along with the supporting governments have conducted tests to assess the impact of alternative fuels on engine performance and emissions. Engine emissions and performance measurements have been made on several aircraft engines with 100% pure and blended alternative drop-in fuels. While having little impact on engine performance and gaseous emissions, alternative fuels use leads to large reduction in particulate matter emissions. 1. INTRODUCTION 1.1 Find attached test results from the tests conducted at GE, P&W and RR. 2. RESULTS 2.1 GE testing: To summarize the emissions results, the addition of the Bio-SPK to the conventional jet fuel was found to have insignificant effects on emissions. The resulting emissions values for the test blends meet the current regulatory requirements. There was a slight reduction in NOx (~1-5%), and an increase in the CO (~5-9%) and UHC emissions (~20-45%). While some parts of the observed changes to emissions are due to measurement variability, they are primarily explained by the anticipated reduction in the peak flame temperature due to the change in hydrocarbon to carbon ratio in the fuel compared to the conventional kerosene tested. Additionally, the impact on spray quality and flame location is also expected to play a major role for emissions levels, especially for CO (carbon monoxide) and UHC (unburned hydrocarbon), and it has to be observed that the changes in these emissions are in absolute terms very small as the datum emissions are very small. Lower smoke emissions (~13-30%) were observed, and this is understood to be as a result of the reduction in the aromatic content of the blends compared to the conventional jet fuel. The emissions may vary among (10 pages) CAAF.09.IP.011.1.en.doc

CAAF/09-IP/11-2 - various Bio-SPKs and the current results should be taken to be specific to the Bio-SPK tested. The results from the tests are shown in figures 1 and 2. 2.2 Rolls Royce testing: A series of engine ground runs were conducted on an Air New Zealand Boeing 747-400 aircraft equipped with Rolls-Royce RB 211-524G2-T engines prior to the test flight including a switch of fuel at various progressions of Engine Pressure Ratio (EPR) settings. The engine showed no change in behavior from the operational perspective. A small subset of the Digital Flight Data Recorder/Quick Access Recorder (DFDR/QAR) data from the 1.4 EPR condition, representative of the steady state performance results, is shown in Figure 3. 2.3 The ANOVA (analysis of variance) method was used to correctly establish if there was a statistical difference between the engine measurement data. ANOVA plainly looks at the data presented and therefore generally accounts for all the possible factors present within the dataset; in this case variations in EPR, EGT, throttle angle and measurement variations. 2.4 During the 1.4 EPR power setting condition, a 1.07% lower fuel flow was observed on the engine run of the Bio-SPK blend which is consistent with the 1.08% higher energy density per unit mass of the Bio-SPK fuel blend, which was determined experimentally. This engine-to-lab results comparison gives a practical difference of 1% (1.08/1.07) by mass which when compared to the 95% confidence limits (from ANOVA) of 1.0-1.13% confirms the fuel flow effect seen is real and accurate. 2.5 RR also conducted a test program to assess the impact of Syntroleum Fischer-Tropsch fully synthetic aviation kerosene on performance and material compatibility of aircraft gas turbine engines by evaluating combustion characteristics in a production annular combustor and fuel nozzle assembly and effect on oxidation of turbine blade and vane alloys in a cyclic oxidation rig. Shown in figure 4 are some of the fuel properties that can impact different combustion characteristics. Tests were conducted to determine lean blowout and ignition characteristic of the alternative fuel, emissions and combustor exit temperatures in an annular rig (figure 5). Details of this test program were presented by Rolls Royce at the ICAO organized Alternative Fuels Workshop in Montreal, 2009. Some of the observations made from the tests were: Alternative fuel exhibits similar stability and ignition characteristics at low and higher operating conditions to those for JP-8 fuel within experimental error; CO, NOx (figure 6), and UHC emissions are similar for both fuels; Full annular AE3007 combustor behaves like engine in producing extremely low smoke and remains nearly smoke free for both alternative fuel and JP-8; and No measurable differences are observed in pattern factor and radial profiles between JP-8 and FSJF fuels suggesting no adverse impact on turbine vanes durability. 2.6 Pratt & Whitney testing: No engine degradation was evident via control, operability and performance or hardware inspection at the conclusion of the test. The emissions tests of the regulated species were compared for the jet fuel, 50%, and 100% ratios used, and showed no significant change in hydrocarbon (HC), Carbon Monoxide (CO), or Nitrogen Oxides (NOx). While the test setup is shown in Figure 7, figure 8 and 9 show fuel characteristics. Some of the test observations (shown in Table 1 and figure 10 for gaseous species and figures 10, 11 and 12 for PM emissions): Negligible Thrust and Fuel Flow impact of alternative fuel as compared to JP8

- 3 - CAAF/09-IP/11 No significant difference in Gaseous emissions for the different fuels; Lower volatile PM emissions (measured at 50m) for synthetic fuels than for JP8: 1) EIm sulphate depends linearly on fuel sulphur content; and 2) At 50 m, plume generated by alternative fuel contain less particle sulphate than even ambient air. Particulate Matter (PM) emissions for the different fuels: 1) For pure alternative fuel, PM EI values are orders of magnitude lower in both number & mass at idle relative to JP8. Differences between the fuels diminish with increasing power; 2) Changes in observed Number EIs largely independent of instrument; mass EIs sensitive to measurement technique; 3) Emission reductions not proportional to the fraction of alternative fuel; 4) Alternative fuel suppresses volatile aerosol formation in plume as the fuel contains 0 Sulphur; and 5) At the 50 meter probe, JP8 idle Number EIs were 45 times higher that alternative fuel. Powering the engine with the alternative fuel also did not result in any engine performance deterioration, as evidenced by a comparison of the initial and post-test data with JP8 fuel. Upon completion of the testing, the engine was stripped and inspected. No engine hardware deterioration as a result of testing with the alternative fuel was noted. Also, no unusual odors were noted as a result of the use of the alternative fuel, during both handling (i.e., filling of tanks, mixing of fuel blend, etc.), and engine running.

CAAF/09-IP/11-4 - (a) (b) (c) Figure 1. Emissions set-up: (a) Emissions trailer, (b) Emissions installation, (c) Emissions probes 50% 40% 25/75 Jatropha-Algae/Jet A 50/50 Jatropha-Algae/Jet A CFM56-7B18 50% 40% CFM56-7B27 30% % Change wrt Jet A 20% 10% 0% -10% -20% NOx CO HC Smoke # % Change wrt Jet A 30% 20% 10% 0% NOx CO HC Smoke # -30% -10% -40% -20% Figure 2. LTO emissions and maximum smoke number for test blends as % difference from Jet A for lowest (18K) and highest (27K) CFM56-7B engine ratings.

- 5 - CAAF/09-IP/11 12300 ANZ Biofuel ground run 29 Dec 08 12200 Engine #1 Fuel flow analysis for ground test during the switch between 50% bio-spk blend and Jet A-1 @ 1.4 EPR 12100 Fuel Flow lbs/hour 12000 11900 Running on 50% bio-spk blend Running on Jet A1 Running on 50% bio-spk blend 11800 11700 11600 Difference by ANOVA analysis method is 1.07% 1350 1370 1390 1410 1430 1450 1470 1490 1510 1530 1550 Time (seconds) Figure 3. Engine ground-run data is shown from a RR RB211-524G2-T engine taken at Auckland on Dec 30, 2008. The data shows a reduction in fuel flow, due to the higher heat of combustion of the 50% Bio- SPK blend. Figure 4. Fuel properties that can impact different combustor performance characteristics

CAAF/09-IP/11-6 - Figure 5: A schematic of the annular rig at Rolls Royce used for testing Alternative fuels. 30 NOx emissions, g/kg fuel 20 10 JP-8 F-T 0 0 200 400 600 800 1000 BIT, F Figure 6. NOx emissions for FT Fuel are in general higher than for JP-8

C 11 C 12-7 - CAAF/09-IP/11 Figure 7. Engine Test setup used at P&W facility to test engine performance and emission characteristics with alternative fuels C 10 C 13 Concentration C 9 C 14 JP-8 C 15 C 8 C 16 C 17 C 7 C 18 C 19 0 5 10 15 20 25 30 C C 10 9 C 8 C 11 5172 F-T Kerosene C 12 Time--> 5 10 15 20 25 30 Figure 8. Spectra of fuel used in the tests.

CAAF/09-IP/11-8 - Property JP-8 Blend Synthetic Viscosity (cst) 1.38 1.14 0.96 Specific Gravity 0.8050 0.7734 0.7377 Net Heat of Combustion (Btu/lb) 18,533 18,735 18,960 Hydrogen % mass 13.95 14.78 15.71 Particulate contamination (mg/l) 0.71 0.21 0.11 Sulphur content (%) 0.123 0.065 0.003 Aromatic content (%) 19 10.1 0.17 Figure 9. Fuel properties of the alternative fuels RATIO - Blend/JP8 RATIO FT100%/JP8 Thrust (Rotor Speed N1) Fuel flow NOx CO LOW 0.999 0.97 0.95 INTERMEDIATE 1.00 0.98 NA HIGH 0.995 1.0 NA SO 2 0.5 0.54 0.54 Fuel flow NOx CO 0.98 0.97 0.90 0.98 0.97 0.97 0.98 NA NA SO 2 0.0 0. 0.1 Table1. Gaseous emissions and performance characteristics of an engine with alternative fuel as compared to JP8

- 9 - CAAF/09-IP/11 Figure 10. Emission data collected for Jet A-1, blend of 50% Jet A-1 and 50% Neste Oil and 100% Neste Oil in a Pratt and Whitney Canada small turbofan engine.

CAAF/09-IP/11-10 - 0% Engine Setting 30% 65% 75% 85% 5% 10% 5% 7% 11% % Change Relative to JP 8 Smoke Number 15% 20% 25% 30% 35% 40% 18% 39% 41% FT Blend FT 45% 44% 44% 50% Figure 11. SN reduction seen with alternative fuels 5E+6 4E+6 Number count 3E+6 2E+6 JP8 Blend 100% Synthetic 5E+6 4E+6 Number count 3E+6 2E+6 JP8 Blend 100% Synthetic 1E+6 1E+6 0E+0 0 50 100 150 200 Particle diameter, nm 0E+0 0 50 100 150 200 Particle diameter, nm Figure 12. Large reductions in PM with alternative fuels at idle than at higher powers END