SGF Meeting, Södertälje, November 18-19, 2014 Tyre Performance Enhancement with Plasticising Oils Dr. Markus Hoffmann NYNAS AB
About Nynas Nynas is the largest specialty oil producer in Europe Offices in more than 30 countries around the globe Net Sales: 3 Billion USD Average number of employees: 860 Refineries in Nynäshamn (SE), Gothenurg (SE), Harburg (DE), Eastham JV (UK), Antwerp JV (BE), Isla JV (Curacao) 2 Nynas AB, Technical Development and Market Support
Extended Capacity Addition of the Harburg refinery in Germany in January 2014 350 000 tonnes increased capacity of specialty oils 3 Nynas AB, Technical Development and Market Support
Global Oil Consumption Other Lubricants, 97% (39 Mio tons / y) Tyre oils, 3% (1.3 Mio tons / y) Only 0.03% of total global oil demand Lubricants, 1% including motor oils, base oils, process oils, tyre oils 3.9 Billion tons / y 4 Nynas AB
Which oils are used in rubber goods? Heavy Naphthenics Vegetable Oils Paraffinic Gr I, Gr II, Gr III DAE TRAE RAE SRAE TDAE MES Naphthenic Black Oil 5 Nynas AB 12/9/2014
Polymer Oil Compatibility BR, NR EPDM, IIR PAR NAP SBR TDAE CR (H)NBR PVC Phthalates (DINP) Polarity 6 Nynas AB, Technical Development and Market Support
Refining of Rubber Process Oils
Group I Oil Refining 8 Nynas AB, Technical Development and Market Support
Naphthenic Oil Refining at Nynas Viscosity @ 40 C: 3-700 cst Sulphur < 15 ppm 0.9% Aromatics: 0 12 % 9 Nynas AB, Technical Development and Market Support
Refining Trends Group I Group II Group III Solvent Extraction Processing VI: ~ 80-100 Max. visc. @ 40 C: ~1000 cst Sulphur ~1 % Severe Hydrogen Processing VI: ~80-120 Max. visc. @ 40 C: 100 cst Sulphur < 10 ppm Severe Hydrogen Processing / Wax Isomerization VI: >120 Max. visc. @ 40 C: 50 cst Sulphur < 5 ppm Higher quality engine oils and fuels Group I refineries closing ~ 67% of process oils used in tyre production are based on Group I technology New capacities Group II, II+, III ~ 33% of process oils used in tyre production based on hydrotreating technology 10 Nynas AB, Technical Development and Market Support
Health, Safety and Environmental Legislations
1907/2006/EC (REACH), Annex XVII, Entry 50 Extender oils shall not be placed on the market, or used for production of tires or parts of tires if they contain: more than 1 ppm of or, more than 10 ppm of the sum of all listed PAHs 12 Nynas AB, Technical Development and Market Support
Commission Regulation (EU) No 1272/2013 amending 1907/2006/EC (REACH) Articles shall not be placed on the market for supply to the general public, if any of their rubber or plastic components that come into direct as well as prolonged or short-term repetitive contact with the human skin or the oral cavity, under normal or reasonably foreseeable conditions of use, contain more than 1 mg/kg (0.5 mg/kg for toys) of any of the listed PAHs. 13 Nynas AB, Technical Development and Market Support
Tire Labelling US Label on its way? EU Label in 2012 Japan Mandatory label in place Korea Mandatory label from Nov. 2012 Brazil Draft legislation filed Regulation (EC) No 1222/2009 14 Nynas AB, Technical Development and Market Support
Key Performance Parameters for Tyres Rolling Resistance (Fuel Economy) Wet Grip (Road Safety) Noise Emissions Tread Wear 15 Nynas AB, Technical Development and Market Support
Case Study: Truck Fleet: 100 trucks and trailers 13 SEK per Liter average diesel price 200 000 km annual milage 30 Liter per 100 Km fuel consumption On heavy vehicles such as trucks, the rolling resistance accounts for up to 40 percent of the energy consumed 60% on trailer axle 25% drive axle 15% steering axle 2.4 Million liters diesel eaten by the rolling resistance of the tires, corresponding to 31 MSEK 16 Nynas AB
Tire Labelling: How to get better ratings? Raw Materials Tyre Design & Modeling Process Equipment 17 Nynas AB, Technical Development and Market Support
Contribution of Chemistry Rolling Resistance Low styrene Low vinyl ESBR/CB SSBR/silica funct-ssbr/silica Wet Grip High styrene High vinyl High Tg Abrasion Low Tg High cis-br CB 18 Nynas AB
Rubber Test 19 Nynas AB, Technical Market Support
Rubber Test How do commercially available oils perform with the new types of S- SBRs? Functionalized (chain-end modified) SSBR in this test: Styrene content: 21 wt.% Vinyl content: 62.5 wt.% Mooney: 68 Tg: -25 C 20 Nynas AB
Tire Tread Formulation 21 Nynas AB
Oil Properties 22 Nynas AB
Mooney Viscosity 23 Nynas AB
Curing Time 24 Nynas AB
Scorch Time 25 Nynas AB
Hardness (Shore A) 26 Nynas AB
Tensile Strength 27 Nynas AB
Elongation at Break 28 Nynas AB
Modulus 29 Nynas AB
Tear Strength 30 Nynas AB
Rebound Resilience 31 Nynas AB
Filler Dispersion (Light Microscopy) 32 Nynas AB
DIN Abrasion 33 Nynas AB
tan δ temperature sweep 34 Nynas AB
DMA Wet Grip Rolling Resistance 35 Nynas AB
DMA 36 Nynas AB, Technical Development and Market Support
Fuel Economy Getting the balance right better Naphthenic Black Oil TDAE / MES RAE DAE Wet Grip better 37 Nynas AB, Technical Development and Market Support
Conclusions Refining Trends Low PAH legislation leads to a phase-out of DAE High-performance engine oil requirements lead to Group I oil refinery closures (affected oils: DAE, RAE, MES, TDAE) Demand for Naphthenics and Gr II, III Paraffinics will increase Tire tread compounds with Naphthenic Black Oil (Nytex 4700) show a superior performance in terms of fuel saving and hence help cutting CO 2 emissions. Today s portfolio of low-pah tire oils provides an excellent toolbox to steer the balance between rolling resistance and wet grip. 38 Nynas AB
Thank you for your attention. 39 Nynas AB, Technical Development and Market Support
Nynas Group Head Office P.O. Box 10700 SE-121 29 Stockholm Sweden Tel. +46-8-602 12 00 info@nynas.com www.nynas.com/tyreoils 40 Nynas AB, Technical Development and Market Support