BioComm Biodiesel B-20 Laboratory certified, biodegradable, renewable, clean burning alternative fuel About BioComm Biodiesel B-20 BioComm Biodiesel B-20 is an alternative fuel created by blending diesel (refined from crude) with a biofuel produced from agricultural products such as canola/rapeseed, soybeans, mustard seeds or camelina. BioComm Biodiesel B-20 is produced using Ultra Low Sulfur Diesel and Biodiesel produced from vegetable base stocks grown in Canada. BioComm Biodiesel B-20 is a FORD Motor Company laboratory tested and approved alternative fuel source. BioComm Biodiesel B-20 has received the FORD Tox Number 181501. BioComm Biodiesel B-20 represents an excellent balance between cost savings, emissions, cold weather performance, materials compatibility, cleaning effects and respect for the environment. Biodiesel B-20 may be treated and used exactly like traditional diesel fuel in most conditions. Every 5 gallons of Biodiesel B-20 used in vehicles replaces 0.75 gallons of crude oil. Biodiesel B-20 can reduce the total hydrocarbon emission by up to 30%, the Carbon Monoxide up to 20% and the total particulate matter up to 15%. Biodiesel B-20 has been extensively tested by government agencies, universities, transit authorities and private industry in the USA, Canada, Mexico and Europe. It is recognized as an alternative fuel by the Department of Energy and the Environment. Applications BioComm Biodiesel B-20 is best suited for: Laboratory research environments On and off-road vehicles Marine applications Railway applications Available Packaging These products are available in pails (19L/5 US Gal), drums (208L/55 US Gal), and bulk (1250L/330 US Gal) containers. Performance Benefits BioComm Biodiesel B-20 provides the following benefits: Cleans dirty engine deposits produced by conventional diesel fuels Thermally stable can be used in multiple weather conditions Reduces harmful exhaust emissions (unburned hydrocarbons, Carbon Monoxide and particulate) Clean burning Renewable energy source More cost effective Greater ignition and combustion characteristics due to an increased Cetane Index No reported effect on fuel consumption Reduced release of Carbon Dioxide (one of the main greenhouse gasses) to the atmosphere Reduced black soot level Ultra low to no sulfur thus reducing the sulfur dioxide production which is considered to be one of the main precursors to ac id rain. Compatible with typical seals, gaskets and adhesives found in today s vehicles Increased lubricity over conventional diesel fuels thus reducing the engine wear 1
BioComm Biodiesel B-20 Laboratory certified, biodegradable, renewable, clean burning alternative fuel Technically Speaking Biodiesel B-20 Viscosity, cst @ 40ºC 2.2 3.2 Sulfur Content (PPM) (ASTM D-5453) 15 Maximum Cetane Number (ASTM D-613) 40-55 Ester Content (%w/w) (EN 14103) 18-22 Initial Boiling Point (ASTM D-1160) Report Cloud Point ( C/ F) (ASTM D-5773) Minimum -10 C/14 F Cold Filter Plug Point (CFPP) ( C/ F) (ASTM D-6371/IP309/EN116) Minimum -10 C/14 F Flash Point, ºC (ºF)(PMCC) (ASTM D-93) > 55ºC (>131ºF) Pour Point, ºC/ºF <-50/<-58 Specific Gravity, g/ml 0.880 Density, lbs./us Gal 7.343 These are typical figures and do not constitute a specification. 2
SECTION 1: Product Information and Company Identification Common Name BioComm Biodiesel B-20 Product Code 0800 Material Use Biodegradable and renewable energy source Manufacturer Commonwealth Oil Corp. 2080 Ferriss Rd. N., Harrow ON. N0R 1G0 In Case of Emergency CANUTEC (613) 996-6666, collect 24 hours SECTION 2: Composition and Information on Ingredients Component CAS Registry # OSHA PEL ACGIH TVL Concentration, % Fatty acid alkyl esters 67784-80-9 Not Established LD50: >17.4 g/kg < 25.0 Hydrosulfurized Kerosene 64742-81-0 200 mg/m 3 200 /m 3 >75.0 See SECTION 8 for Exposure Limits and SECTION 11 for Toxicological Data SECTION 3: Hazards Information Chemical Family Physical State Emergency Overview Routes of Entry Potential Acute Health Effects Medical Conditions Aggravated By Overexposure Overexposure Signs and Symptoms See SECTION 11 for Toxicological Data SECTION 4: First Aid Measures Eye Contact Skin Contact Saturated Hydrocarbon Liquid No specific hazard Use with care Follow good industrial hygiene practices Dermal and eye contact, inhalation, ingestion None known None known Not available Check for and remove any contact lenses. In case of contact, flush eyes with plenty of water for at least 20 minutes. Cold water may be used. Get medical attention should irritation persist. Remove any contaminated clothing. Wash with soap and water. Get medical attention should irritation persist. 3
Inhalation Ingestion Note to Physician SECTION 5: Fire Fighting Measures If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious patient. Should large amounts be swallowed, call a physician. Not available Flammability Auto-Ignition Temperature Not Established Flash Point (COC) > 55ºC (> 131ºF) Limits Lower Limit 0.6 Upper Limit 7.5 Hazardous Combustion Products Products are smoke, carbon monoxide, carbon dioxide, and trace oxides of Sulphur Fire Hazard in Presence of Various Substances in presence of open flames, spark, static discharge and at Explosion Hazard in Presence of Various Substances Fire Fighting Media and Instructions Protective Clothing (Fire) Special Remarks on Fire Hazards or above flash point Risk in Presence of Mechanical Impact: Not available Risk in Presence of Static Discharge: Not available Small Fire: Use chemical powder, water spray (fog), foam, carbon dioxide and vaporizing type extinguishing agents. Large Fire: Use water spray, fog or foam, carbon dioxide and dry chemical powder. Use water spray to cool surface of containers. Do not use water jet. Water may be used to disperse the vapors or provide protection to personnel attempting to disperse vapors or stop a leak. Fire fighters should wear positive pressure self-contained breathing apparatus (SCBA) and full turnout gear. Be sure to use MSHA/NIOSH approved respirator or equivalent None 4
SECTION 6: Accidental Release Measures Small Spill and Leak Shut-off ignition sources; no flares, smoking or flames in the hazard area. Absorb with an inert material and put spilled material into appropriate waste disposal Large Spill and Leak Shut-off ignition sources; no flares, smoking or flames in the hazard area. Absorb with an inert material and put spilled material into appropriate waste disposal Do not allow any potentially contaminated water, including rain water, runoff from fire fighting or spills, to enter ay waterway, sewer or drain See SECTION 8 for Personal Protective Equipment and SECTION 13 for Waste Disposal SECTION 7: Handling and Storage Handling Storage This liquid is volatile and gives off invisible vapors. Either the liquid or vapor can settle in low areas as well as travel some distance along the ground or surface to ignition sources, such as heat, sparks, pilot lights, static electricity and open flames. Proper grounding procedures should be used as static charge may accumulate Avoid prolonged or frequent contact. Wash exposed area with soap and water. Avoid breathing vapors or spray mists Avoid contact with eyes, skin and clothing Always wash your hands after handling. Use good personal hygiene Do not cut, weld, heat or pressurize containers Keep containers tightly closed Store in dry, cool, and ventilated areas Do not store near open flames or sources of ignition 5
SECTION 8: Exposure Controls and Personal Protection Personal Protection Eyes Body Respiratory Hands Feet Protection for Large Spills Engineering Controls Safety glasses or goggles are advisable Lab coat or suitable protective clothing are advisable Respirator with approved cartridges Chemical resistant or oil impervious gloves are advisable Shoes (as required by work place) Splash goggles, full suit, vapor respirator, boots, chemical resistant gloves Good ventilation should be sufficient to control airborne levels Local exhaust is recommended to control emissions at the source Mechanical ventilation should be used for confined areas Eyewash stations and safety showers should be proximal to the workstation Exposure Limits ACGIH TLV (US and Canada) - TLV-TWA: No OSHA PEL or ACGIH TLV have been assigned but the following is suggested: 5 mg/m 3 If vapor and/or mist are generated by heating, spraying etc. a NIOSH approved organic vapor cartridge respirator may be used. Consult your local authorities for your acceptable exposure limits SECTION 9: Physical and Chemical Properties Physical State Liquid Appearance and Colour Clear colorless to light amber solution Odour Petroleum odor ph N/A Flash Point (COC) > 55ºC (> 131ºF) Boiling/Condensation Range C/( F) 154/(309) to 371/(700) Pour Point Not Available Freezing Point Not Available Specific Gravity 0.880 g/ml (Water = 1g/ml) Density 7.343 lbs./us Gal Vapor Pressure <0.3 kpa (<2 mm Hg) @20 C Vapor Density (Air=1): Boiling >5 % Volatility, by volume 100 Evaporation Rate 0.05 VOC 100% Viscosity (cst @ 40ºC) 2.2 3.2 (typical) Solubility in Water Negligible 6
SECTION 10: Stability and Reactivity Stability and Reactivity Incompatibility with Various Substances Hazardous Conditions Hazardous Decomposition Products Hazardous Polymerization Stable under normal conditions Reactive with strong oxidizing agents such as chlorine bleach, concentrated oxygen, sodium hypo-chlorite or calcium hypo-chlorite. High temperatures Fumes, smoke, carbon monoxide, aldehydes, carbon dioxide and other products in case of incomplete combustion. Will not occur SECTION 11: Toxicological Information Chronic Effects on Humans Eyes Skin Ingestion Inhalation Other Effects Acute Toxic Data Other Toxic Effects on Humans Special Remarks on Toxicity to Animals Special Remarks on Other Toxic Effects on Humans Slightly irritating, but will not injure eye tissue. May irritate the eyes. Frequent or prolonged contact may irritate the skin. May cause nausea, vomiting, cramping, and depression of Central Nervous System ranging from mild headaches to anesthesia, coma and death. Pulmonary irritation secondary to exhalation of solvent. Elevated temperatures or mechanical action may form vapors, mists or fumes, which may be irritating to the eyes, nose, throat and lungs. Avoid breathing vapors and mists. Avoid breathing mist and fumes Proper ventilation should be utilized Low Low None reported 7
SECTION 12: Ecological Information BOD and COD Biodegradability/OECD Acute Aquatic Toxicity Products of Degradation Products of Biodegradation Special Remarks on the Products of Biodegradation SECTION 13: Disposal Considerations Wastes should be disposed of in accordance to local, federal and state environmental control regulations 8
SECTION 14: Transport Information Regulatory Information United States (DOT) Canada (TDG) Mexico (NOM- 004-SCT2-1994) IMDG Code UN Number 1993 1993 1993 Proper Shipping Name Liquid N.O.S. Liquid N.O.S. Liquid N.O.S. Class Packing Group Label Additional Information 3 III - - 3 III - - 3 III - - 1993 3 III - - Liquid N.O.S. IATADGR 1993 3 III - - Class Liquid N.O.S. NAERG (North American Emergency Response Guide): 128 SECTION 15: Regulatory Information United States: Federal Regulations TSCA 8(b) Inventory: All products are listed or exempt SARA 302/304/311/312 Extremely Hazardous Substances: No products found SARA 302/304 Emergency Planning and Notification: No products found SARA 302/304/311/312 Hazardous Chemicals: No products found SARA 311/312 MSDS Distribution Chemical Inventory Hazard Identification: No products found Clean Water Act (CWA) 307: No products found Clean Water Act (CWA) 311: No products found Clean Air Act (CAA) 112 Accidental Release Prevention: No products found Clean Air Act (CAA) 112 Regulated Substances: No products found Clean Air Act (CAA) 112 Regulated Toxic Substances: No products found United States: State Regulations California Prop. 65: No products found Canada: WHMIS B3 under WHMIS CEPA DSL: All products are listed or exempt "This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by the Controlled Products Regulations." 9
Mexico: Flammability: 2 2 Classification Healthy: 1 1 0 Reactivity:0 Special: SECTION 16: Other Information Label Requirements Use with care Use as directed Hazardous Material Information System (USA): Health 1 Fire Hazard 2 Reactivity 0 Personal B Protection National Fire Protection Association (USA): Flammability: 2 Healthy: 1 0 Reactivity: Special: Date of Issue September 21, 2010 Date of Previous Issue March 7, 2008 Note to Reader To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Authored By: Commonwealth Oil Corporation Technical Services Department, (519) 738-3503 10