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ADVANCES in NATURAL and APPLIED SCIENCES ISSN: 1995-0772 Published BY AENSI Publication EISSN: 1998-1090 http://www.aensiweb.com/anas 2016 Special10(7): pages 49-55 Open Access Journal Effect of injection timing on performance and emission characteristics of diesel engine with coated piston running on sunflower biodiesel blends 1 Piramanandhan M and 2 Mohana Sundara Raju N, 3 Venkatesan R 1 Deputy manager-cutting systems, ESD ESAB, G-22, SIPCOT Industrial Park Irunkattukottai, Chennai, India. 2 Professor, Department of mechanical engineering Mahendra Institute of Technology Namakkal, India. 3 Professor, Department of Mechanical Engineering Sona College of Technology Salem, India. Received 25 April 2016; Accepted 28 May 2016; Available 5 June 2016 Address For Correspondence: Piramanandhan M, Deputy manager-cutting systems, ESD ESAB, G-22, SIPCOT Industrial Park Irunkattukottai, Chennai, India E-mail: femram@gmail.com Copyright 2016 by authors and American-Eurasian Network for Scientific Information (AENSI Publication). This work is licensed under the Creative Commons Attribution International License (CC BY). http://creativecommons.org/licenses/by/4.0/ ABSTRACT The aim of present study is to investigate the effect of injection timing on the performance of alumina-titania coated piston in diesel engine operating with blends of sunflower biodiesel. The sunflower methyl ester (SFME) of two different blend ratio (20% SFME and 40% SFME) are tested and compared with standard diesel fuel engine. In the investigation observed that maximum of 9% of improvement in thermal efficiency for the coated piston with 40% SFME at retardation compared to normal injection timing. The reduction in brake specific fuel consumption is noted as 8% for 20% SFME at retarded injection. The NOx emission reduction is noted as 21% for 20%SFME on retardation compared standard engine at normal injection timing of 24 o before top dead centre (btdc). The study revealed that the fuel advancing having significant effect on smoke reduction which is observed as 9% less than standard engine. The normal injection of coated 20% and 40% SFME released better level of hydrocarbons (HC) compared to retardation and advancing injection at peak loads. It is also observed around 22% reductions in carbon monoxide (CO) at retardation for 20% SFME at peak load compared to standard engine. The overall study summarized that some trade off on the injection timing is needed to obtain optimum level of NOx and smoke intensity with improved performance of engine. KEYWORDS: Exhaust emissions; Variable injection timing; Injection retardation; thermal barrier coating; NOx reduction. INTRODUCTION The emission reductions with fuel saving strategies are recent day s global challenge for automotive and stationary engine applications. There are numerous studies and investigations are made in past to overcome this efficiency of energy conversion issues and to reduce harmful exhaust emissions with turbo charging, EGR, catalytic convertors, biodiesel, duel fuel techniques, fuel additives and multi fuel technique including advanced electronic fuel injections are adapted and achieved considerable improvement. Now days the combination of low heat rejection engine with renewable fuel strategy also playing much attention for addressing this emission and performance enhancement strategy. The vegetable oil is renewable and it can release emission level than conventional diesel fuel. The major drawback of vegetable or biodiesel is viscosity which is directly related to the combustion characteristics. This problem can be easily addressed with thermal barrier coating for improved performance and emission reduction. The usability of biodiesels in coated engines are experimentally investigated and reported in many studies with improvement in thermal efficiency and also minimized the exhaust emissions [1-3]. Most of the investigations and To Cite This Article: Piramanandhan M and Mohana Sundara Raju N, Venkatesan R., Effect of injection timing on performance and emission characteristics of diesel engine with coated piston running on sunflower biodiesel blends. Advances in Natural and Applied Sciences. 10(7); Pages: 49-55

50 Piramanandhan M et al., 2016/ Advances in Natural and Applied Sciences. 10(7) Special 2016, Pages: 49-55 studies are with stabilized zirconium oxide due to low conductivity and thermal stability. The effect of sunflower biodiesel blends on the performance of PSZ coated piston was carried out and reported [4] approximately 5% improvement in thermal efficiency and 4-6% fuel saving compared to standard engine. The alteration in fuel injection timing will help to overcome the delay period issues of the vegetable fuel. The effect of advancing of injection timing is studied and reported smooth performance compared to normal injection timing for rapeseed oil fuelled diesel engine [5]. Although many studies [6-9] are carried out on LHR with different coating material and fuel combinations, the effect of injection timing variation on the performance of LHR engine is limited along with different biodiesel blend ratio. In the present study, the combined effects of injection timing variation and thermal barrier coating with 20% and 40% blends of sunflower biodiesel are presented. The variation in the physical delay will affect the engine performance and emission release [10-11], in the present investigation the ignition delay period is varied with timing of fuel injection. The advancing and retardation is carried out mainly to study the effects on biodiesel blends due to its viscous characteristics with piston coating to enable better performance. The test engine normal injection timing is 24 o btdc and it is adjusted to 19 o btdc (retardation) and 28 o btdc (advancing) for the present study. The engine piston is coated with multilayer of NiCrAl and Al 2 O 3 -TiO 2 for 150 microns and 200 microns respectively over the substrate of aluminum alloy piston with plasma spraying process as shown in figure1. The addition of TiO 2 (40-45% by volume) in the alumina is added to have wear and better thermal stability [12]. The test is conducted with same operating conditions for both coated and uncoated engines with diesel and blends of biodiesel for comparative analysis. Fig. 1: Uncoated piston (a) and Coated piston (b) Experimental Set Up And Investigation: The photographic view of experimental set up is illustrated in fig.2. It consists of test engine (1), exhaust gas analyzer (2), exhaust gas temperature sensor (3) connected with swing field electrical dynamometer (4) with electrical load varying (5) options. The engine specifications are single cylinder; vertical-air cooled and rated brake power of 4.4 kw and 1500 rpm with compression ratio of 17.5:1. The set up is equipped computerized combustion analyzer tool to obtain required combustion and emission outputs and the pressure release estimations with pressure transducer of 250 bar measurement range. The engine is also incorporated with AVL 365C angle Fig. 2: Experimental setup encoder for proper injection timing measurement in the pressure release output. The air intake is measured with orifice accompanied with large stagnation tank to eliminate fluctuations in measurement and fuel consumption is measured through time taken for 10 cc of volume in the manometer. The estimated properties of fuel and biodiesel blends are listed in table 1.

51 Piramanandhan M et al., 2016/ Advances in Natural and Applied Sciences. 10(7) Special 2016, Pages: 49-55 Table 1: Properties Diesel SFME 20% SFME 40% SFME Density, Kg/m 3 860 900 868 876 Calorific value, kj/kg 42800 37800 41800 40800 Viscosity, centistokes 3.01 5.8 3.568 4.126 Flash point, o C 60 98 67.6 75.2 Diesel index 50 48 49.6 49.2 The experimental study is carried out for four different cases and recorded the observations for constant injection pressure of 200 bar with diesel fuel, 20% and 40% sunflower methyl esters. Standard engine with diesel fuel for standard injection timing (referred as D in the plots) Coated engine with standard injection timing 20% and 40%SFME (referred as C20SF and C40SF respectively in results plot) Coated engine with advance injection timing of 20% and 40% SFME blends (referred as C20SF A28 and C40SF A28 respectively) for 28 o btdc Coated engine with retarded injection timing of 20% and 40% SFME blends (referred as C20SF R19 and C40SF R19) for 19 o btdc First the engine is calibrated and tested for its normal running with standard injection pressure and timing for diesel fuel with uncoated piston. Then the test is conducted with 20% SFME and 40% SFME on coated engine with normal injection pressure and normal injection timing. Later the injection timing advancement and retardation set observations are noted for biodiesel blends. The fuel measurements are obtained from four trials of time recording to estimate the fuel consumption accurately. Five gas analyzer was used in the set up to obtain the emission output readings. The compression ratio variation due to coating thickness is eliminated with stainless steel foil gasket. RESULTS AND DISCUSSIONS A. Thermal efficiency: The brake thermal efficiency is the indication of capability of power conversion for the given input of fuel energy. Most of the combustion heat energy is wasted through exhaust gases and cooling which can be reduced and utilized effectively if the piston is coated with ceramic material of low thermal conductivity. The variation of thermal efficiency with brake power for different blend ratio and injection timing are plotted in fig.3. Due to the coating of piston in the present investigation it is found that the thermal efficiency of the coated 40% SFME at retarded condition is 9% higher than standard diesel engine. The thermal efficiency is increasing with increase in blend ratio and it is increasing more for late injection due to the reason of attaining heat release after top dead centre and it is leaded to complete combustion. For the normal injection both 20% and 40% bio fuels showed only slight changes in the thermal efficiency and it is equivalent to standard engine. Fig. 3: Thermal efficiency variation with brake power for different injection and blend ratio B. Specific fuel consumption: The variation of specific fuel consumption is shown in fig.4 for different fuel injection timing and blend ratio. At maximum loading the coated piston with 20% SFME shows 8% reduction in SFC at retardation compared to standard engine at normal injection. The range of SFC for uncoated diesel is 0.58 kg/kw-hr to 0.33 kg/kw-hr but it is 0.55kg/kW-hr to 0.32 kg/kw-hr for 20% SFME with injection at 19 btdc. It shows better fuel saving in retardation due to better combustion with minimal delay due to availability of heat in coated piston. The fuel advancing shows more consumption due to peak heat release is before the TDC which may degrade effective power output of engine.

52 Piramanandhan M et al., 2016/ Advances in Natural and Applied Sciences. 10(7) Special 2016, Pages: 49-55 Fig. 4: Effect of injection timing and blend ratio on specific fuel consumption C. Unburned hydrocarbon release: The fig.5 shows hydrocarbon emission release in present investigation. At low load conditions coated engine 20% SFME with normal injection releasing more unburned hydrocarbons and at peak load conditions the same blend released relatively low HC due to attaining of complete combustion with high temperature availability in the ceramic coated piston. The fuel advancing helps in the high load conditions to release low HC for 40% SFME same time the release of HC is more for both 20% SFME and 40% SFME in injection advancing and it may be due to the lean mixture of fuel. Fig. 5: Hydrocarbon release with brake power and injection timing D. Carbon monoxide and Carbon dioxide release: The CO release for retarded injection of 20% SFME is the lowest among all different experimental set as shown in fig.6 and it is 22% less than standard engine at maximum loading. The maximum CO release is noted for 40% SFME at normal injection timing. It shows that even with minimum combustion duration the coated engine able to burn the biodiesel to maximum extend and it is also leads to conversion of unburned CO to CO 2.For all blend ratio the CO release increasing with respect to brake power and the minimum values are noted at average loading. Fig. 6: Carbon monoxide release with brake power and injection timing

53 Piramanandhan M et al., 2016/ Advances in Natural and Applied Sciences. 10(7) Special 2016, Pages: 49-55 Fig. 7: Carbon dioxide release with brake power and injection timing The CO 2 emission release is shown in fig.7. The coated piston with 20% and 40% SFME released lowest level compared to all other set of run and it is 7% lower than the standard diesel engine.the highest CO 2 release is observed for advancing conditions it may be due to conversion of CO to CO2 at increased duration of combustion in advanced injection (28 btdc) E. Oxides of nitrogen release: The NOx release of present experimental investigation showed some interesting output when compared to 100% SFME fuel operation [1] and it is plotted in fig.8.the coated piston with 20%SFME for retarded conditions released 21% lower than the standard diesel engine for the reason of minimum reaction time presents for the mixture inside the combustion chamber and which reduces the NOx reactions. The maximum NOx release is noted for 40%SFME at increased injection timing duration (28 btdc) due to the reason of more reaction duration with high temperature condition of coated piston which is 45% more than standard engine. The Nox release plots depicts that decreasing injection timing for biodiesel blends will release less NOx compared to uncoated standard engine. Fig. 8: Oxides of nitrogen with brake power and injection timing F. Smoke emission release: In contradiction to NOx the smoke intensity is decreasing while advancing the injection as shown in fig.9. The minimum values are noted for advanced injection of 40%SFME and 20%SFME at maximum loading which is 11% less than standard engine. The smoke release is increased 19% more than standard engine for coated 20% and 40% SFME at normal injection, which clearly indicates that the smoke can be reduced for blends in the coated engine with fuel advancing in thermal barrier coated engine. The late injection of fuel increase the smoke level compared to standard engine.

54 Piramanandhan M et al., 2016/ Advances in Natural and Applied Sciences. 10(7) Special 2016, Pages: 49-55 Fig. 9: Smoke intensity with brake power and injection timing Summary of investigation and conclusions: The investigation focused on partially insulated air cooled diesel engine with biodiesel blends of 20% and 40% sunflower methyl ester and obtained considerable improvements in emission release and performance. The aspect of varying injection timing also studied and noted for better emission characteristics for HC, CO, NOx and smoke emissions for retarded and advanced injection compared to normal injection. The key findings of the present study and experimental investigations are as follows, Maximum improvement in thermal efficiency is noted as 9% for 40%SFME in retarded injection (19 o btdc) at maximum loading compared to standard engine injection timing (24 o btdc). The minimum fuel consumption is noted in retardation for 20% SFME which is 8% lower than standard engine and also noted relatively low consumption for 40% SFME in retardation. Low HC emissions are observed at normal injection compared to injection advancement or retardation for both 20% and 40% SFME but it is 10% more than the level of emissions obtained in100%sfme [1] at normal injection. The study shows increasing the blend ratio can reduce the HC emissions in coated engine. The lowest CO emission is noted for 20%SFME in retardation which is 22% less than standard engine at peak load. In low load condition the CO release if low for biodiesel blends but while increasing load it is increased more than standard engine, it may be due to lean mixture strength at peak load..the minimum CO 2 release is observed for standard injection of 20% and 40% SFME and it is increased adversely with fuel advancing as result of CO to CO 2. The reduction in NOx emission is observed in current study for retardation. The lowest level is noted for 20% SFME which is 21% less than standard engine and in the same time the smoke intensity is increased to 11% more than standard engine for retardation. It shows some trade off in injection timing is needed to obtain optimum level of NOx and Smoke intensity. REFERENCES 1. Piramanandhan, M., N. Mohana Sundara Raju and R.Venkatesan, 2016. Performance and emission characteristics of multi layer thermal barrier coated DI diesel engine fuelled with sunflower bio-diesel, International Journal of Applied Environmental Sciences, ISSN 0973-6077, 11(1): 267-277. 2. Hanbey Hazar and Ugur Ozturk, 2010. The effects of Al2O3-TiO2 coating in a diesel engine on performance and emission of corn oil methyl ester, Renewable Energy, 35: 2211-2216. 3. Taymaz, I., K. Cakir and A. Mimarglu, 2005. Experimental study of effective efficiency of ceramic coated diesel engine, Surface and coating technology, 2000: 1182-1185. 4. Huseyin Aydin, 2013. Combined effects of thermal barrier coating and blending with diesel fuel on usability of vegetableoils in diesel engines, Applied Thermal Engineering. 51. 5. Simhadri, K. and P. Srinivas, 2015. Performance and Emission Analysis of Partially Insulated Four Stroke Diesel Engine Fuelled with Blends of Sunflower Methyl Ester, International Journal of Engineering Trends and Technology, 27(6). 6. Nwafor, O.M.I., G. Rice and A.I. Ogbonna, 2000. Effect of advanced injection timing on the performance of rapeseed oil in diesel engines, Renewable Energy, 21: 433-444. 7. Ekrem Buyukkaya, Tahsin Engin and Muhammet Cerit, 2006. Effects of thermal barrier coating on gas emissions and performance of a LHR engine with different injection timings and valve adjustments, Energy Conversion and Management, 47: 1298-1310. 8. Ekrem Buyukkaya and Muhammet Cerit, 2008. Experimental study of NOx emissions and injection timing of a low heat rejection diesel engine, International Journal of Thermal Sciences, 47: 1096-1106. 9. Maharaja Gasti and M.C. Navindgi, 2013. Comparative Experimental investigation of performance and combustion characteristics in a single cylinder thermal barrier coated diesel engine using diesel and castor biodiesel, Interna tional Journal of Engineering Research and Technology, 2(7).

55 Piramanandhan M et al., 2016/ Advances in Natural and Applied Sciences. 10(7) Special 2016, Pages: 49-55 10. Prasanna Raj Yadav, S., C.G. Saravanan and M. Kannan, 2015. Influence of injection timing on DI diesel engine charac teristics fuelled with waste transformer oil, Alexandria Engineering Journal., 54: 881-888 11. Simhadri, K. and P. Srinivas, 2013. Performance and Emission Analysis of M.Shahabuddin, A.M.Liaquat, H.H.Masjuki, M.A.Kalam and M.Mofijur, Ignition delay, combustion and emission characteristics of diesel engine fueled with bio diesel, Renewable and Sustainable Energy Reviews, 21: 623-632. 12. Cao, X.Q., R.Vassen and D. Stoever, 2004. Ceramic materials for thermal barrier coatings, Journal of the European Ceramic Society, 24: 1-10. 13. Nwafor, O.M.I., G. Rice and A.I. Ogbonna, 2000. Effect of advanced injection timing on the performance of rapeseed oil in diesel engines, Renewable Energy, 21: 433-444.