Argonne Mobility Research Impending Electrification. Don Hillebrand Argonne National Laboratory

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Argonne Mobility Research Impending Electrification Don Hillebrand Argonne National Laboratory 2018

Argonne: DOE s Largest Transportation Research Program Located 25 miles from the Chicago Loop, Argonne was the first national laboratory, chartered in 1946 Operated by the University of Chicago for the U.S. Department of Energy Major research missions include basic science, environmental management, and advanced energy technologies About 3,500 employees, including 178 joint faculty, 1000 visiting scientists and 6500 facility users Annual operating budget of about $750 million ( 80% from DOE) http://www.anl.gov/ Research collaboration and partnerships are highly valued 2

Argonne s Center for Transportation Research Unique Facilities and Depth of Expertise Basic & Applied Combustion Research - Fuels and After treatment Modeling and Simulation - CFD Engine Combustion - Vehicle PT Energy & Controls Materials Research Tribology Thermal Mechanical Advanced Powertrain Research Facility EV-Smart Grid Interoperability Smart Mobility 17

Argonne Develops Advanced Battery Technologies for Electric-Drive Vehicles Advancing electrochemical storage beyond lithium-ion batteries to other systems with new material discoveries Developing and demonstrating energy storage prototype, manufacturing, and recycling processes and technologies Developing large energy storage and power management systems that improve grid reliability Optimizing efficiency, performance, and emissions of electric-drive powertrains

WTW Results: GHG Emissions of a Mid-Size Car (g/mile) Low/high band: sensitivity to uncertainties associated with projection of fuel economy and fuel pathways (DOE EERE 2010, Record 10001) 5

PEV Market PEV monthly sales volumes are flat and growing slowly

250,000 200,000 150,000 100,000 Annual U.S. Plug-In Electric Vehicle Sales Bolt Others Tesla Model X BMW i3 Ford C-Max Energi Ford Fusion Energi Prius PHEV Tesla Model S* Chevy Volt LEAF 50,000 0 2012 2013 2014 2015 2016 2017 2018* 7

Argonne s 50-year of Battery R&D Timeline Prime R&D focus: 1964 1998 High/Moderate temperature Li batteries 1998 Room-temperature Li-ion batteries

Argonne Works Across the Value Chain Material Discovery Models, Synthesis Material Characterization In Situ, Operando System-level Analysis Vehicle, Grid, Techno-Economic Electrode and Cells Modeling, Characterization Recycling Life Cycle, Processing BATTERY RESEARCH AT ARGONNE Li-ion, Li-metal, flow batteries, multivalent systems Material Process R&D and Scale Up Organic, Inorganic Cell Diagnostics and Modeling Performance, Degradation Large Format Devices Pouch, 18650 Standardized Testing Vehicle, Grid

Moore s law for batteries: 5% per year Li-ion commercialized Li-ion:5% per year Lead acid Nickel Metal Hydride Batteries are improving steadily; but at a slow pace 1 0

Costs are Decreasing Enabling a Range of Possibilities 1 1

Lessons from Lithium-ion Cost (US$/kW.h) 3000 2000 1000 Development of Lithium Batteries 1970-2015 Li-ion Li-ion Li MnO 2 Li V 3 O 8 300 200 100 Gravimetric Energy Density (W.h/kg) Li MoS 2 LiAl TiS 2 0 1970 1980 1990 2000 2010 Year 2015 0

Areas of Research in Container Batteries e - e - Anode Electrolyte Cathode e - Separator Lead Graphite Silicon Li metal Mg, Ca, Zn Na-ion Sulfuric acid Liquid electrolyte High voltage electrolyte Solid conductor Liquid electrolytes Liquid electrolyte Lead oxide Metal oxide High voltage cathode Sulfur, oxygen Intercalant cathode Intercalant cathode Focus on chemistries of the future. And from the past 13

New Materials for Flow Batteries Anode Cathode Separator Vanadium, iron Zinc Hydrogen High Voltage systems Redox Organic Molecules Redox active polymers Tuned aqueous molecules liquid aqueous electrolytes Proton exchange membranes Separation membranes: Size selective ion exchange Vanadium Halogens(chlorine, bromine) chromium High Voltage systems Redox Organic Molecules Redox active polymers Tuned aqueous molecules Next generation redox molecules can help decrease cost 14

Comparison of Present-day Li-ion Batteries vs. Plug-in vehicle Goals Specific Power-Discharge, 10s (317 W/kg) Operating Temperature Range (-30 to +50 C) Production Price @100k/yr ($293/kWh usable) 140% 120% 100% 80% 60% 40% 20% 0% Useable Specific Energy-C/1 (96 Wh/kg) Power Density (475 W/liter) Calendar Life (15 years) Useable Energy Density-C/1 (145 Wh/liter) Cycle Life-70% DOD (5,000 cycles) FreedomCAR Goals lithium-ion Over the next 5 years, PHEVs will become cost effective

The next material on the roadmap: Li metal Systems exist that promise very high theoretical energy However challenges are significant All numbers represent theoretical energy densities

Are we seeing a solar effect in storage?

Comparison of Truck Powertrains Argonne performed a study using a performance based sizing process for various powertrain architectures. The process was extended to quantify the fuel savings attributable to the powertrain electrification. Transit Bus is taken as the example for analysis Baseline Vehicle Nova LFS Engine 209 kw, 9L, Diesel Transmission 6 speed, Automatic Auxiliary loads 10 kw Test weight 15382 kg Cargo/passenger 4000 kg Tires 305/70/22.5 Final drive ratio 5.13 Starter 8 kw Alternator 11 kw

Architectures considered in this study Conventional Pre-Trans Hybrid (HEV) Series Plug In Hybrid (PHEV) Mild Hybrid (ISG) Battery Electric (BEV)

Performance Based Sizing Ensures Fair Comparison Sizing assumptions No trade off on payload or performance Fixed payload across all powertrains Match or better the conventional vehicle in performance BEVs range will depend on the application. (150 miles assumed in this study) PHEVs will have 50 % all electric range as the BEV. power Accel 0-30 & 0-60 6% grade speed Cruise Daily driving (miles) Data from NREL FleetDNA duration As performance parameters are not widely published for heavy vehicles, the baseline values can be estimated through simulations. Vehicle ID & Deployment ID

Simulation can predict performance accurately Simulated performance estimates were verified against test data from Altoona Bus Research and Testing Center Acceleration and Grade performance matched with test data Based on test data and cruising speed observed in similar vehicles, the target performance was set at 60mph. Performance Criteria Test Simulation Target Cruising Speed (mph) 50* 72 60 6% Grade Speed (mph) 30 29 29 0 30 mph Acceleration Time (s) 14.5 14.3 14.3 0 60 mph Acceleration Time (s) NA* 66 66 A new vehicle, with an electrified powertrain architecture, that matches this performance can be expected to perform the same functions as the baseline vehicle

Performance Based Sizing Logic Component power requirements vary with powertrain architecture Goal of sizing To find minimum component sizes needed to meet performance targets To reduce fuel consumption (not optimization). Fully utilize the components available in architecture Powertrain Engine Motor Battery Conventional ISG HEV PHEV BEV Acceleration Grade & Cruise Grade & Cruise Size based on Starter & Alternator Maximize regen in ARB Transient Acceleration Grade & Cruise Energy: Sustain electric loads for at least 1 minute* Power: to sustain peak motor output Energy: Electric Range Driving Range in EPA 65. Power: Sufficient power to support motor & aux loads * Based on EPA off-cycle credit system in LDV. Transit buses could use longer stop time for sizing

Performance Based Sizing Results ISG Engine: same as the baseline, 209kW Motor sized for 11kW continuous load Based on Delco Remy alternators (10.8kW) and starter motors (8kW) used in transit bus applications Battery needs 200Wh usable energy to meet 11kW load for a minute HEV Engine is sized at 176kW (much smaller than a 9L engine) 120kW Motor and Battery pack. Based on commercially available cells, such a HEV pack would also have ~5kWh total energy. (Eg. BAE Hybridrive buses) PHEV Engine is sized at 160kW 330kW Motor. 230kWh battery pack. It can meet motor power requirements BEV 374kW Motor. 440kWh battery pack. It can meet motor power requirements * Based on EPA off-cycle credit system in LDV. Transit buses could use longer stop time for sizing

Approaches: Retrofit vs. New Design New Design: new body, lighter chassis, efficient auxiliary systems. Retrofit: Vehicles share the same chassis, body, wheels etc. Adding the mass of the new and replaced components will give the net difference in test weight. Note: Autonomie class 8 truck weights correlate well with results from electric drive implementation on class 8 trucks by TransPower.

Results: No Tradeoff in Performance In many aspects the performance of the electrified powertrains are better than that of the conventional baseline. The increases in weight of the powertrain is offset by the additional power available from the motor Acceleration Time (s) 40 30 20 10 0 Conv ISG HEV PHEV BEV 0 30 mph Time (seconds) 6% grade Speed (mph) 0 60 mph Time (seconds) Cruise Speed (mph) 80 60 40 20 0 Speed (mph) Difference in grade speed is within the 2% tolerance allowed in the sizing process.

Fuel savings depends on type of driving Vehicles are evaluated over 150 mile drive in 2 drive cycles. ISG benefits attributable to High efficiency electric machine replacing the alternator & Idle reduction HEVs offer 28% fuel savings in transient driving conditions. Smaller engine & Higher average engine efficiency PHEVs and BEVs are necessary to achieve petroleum displacement in highway driving

Preliminary results on cost impact of electrified powertrains At 87% cost increase, full petroleum displacement is achieved for transit bus. PHEV bus achieves 53% fuel displacement at 52% increase in cost Hybrid bus achieves 30% fuel displacement at 10% increase in cost. In this study cost implies estimated manufacturing cost based on component cost targets set by DOE. It is typically much lower than the selling price.

Summary A sizing logic is proposed for medium & heavy duty vehicles, without any tradeoff on cargo or performance. Fuel saving potential of various hybrid powertrains in evaluated in case of transit bus application. When sized for similar performance, 8% - 100% fuel savings can be achieved based on extent of electrification. Next Steps Consider real world driving, fuel costs and optimization of ownership costs for component sizing. Consider minimizing cost impact with other design choices Current Estimate: Manufacturing cost increase w.r.t conventional transit bus BEVs (+87%), PHEV(+52%), HEV(+10%) Evaluate a short range BEV option which can charge multiple times during the day. It could cost ~15% higher than conventional bus and still achieve 100% of petroleum displacement.

Concerns Infrastructure Grid Wireless Charging Fast Charging

31

THE FUTURE OF MOBILITY Don Hillebrand Energy Systems Division Future R&D Opportunities in Mobility. Travelling 3 Trillion miles per year and moving 11 Billion Tons of Goods. 32 Source: The Transforming Mobility Ecosystem: Enabling an Energy-Efficient Future. DOE/Reuben Sarkar. 2017