Getting to Chemicals and Advanced Biofuels from Cellulosic Feedstocks

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Getting to Chemicals and Advanced Biofuels from Cellulosic Feedstocks 2013 BIO World Congress on Industrial Biotechnology June 17, 2013 2013 Gevo, Inc. 1

Forward-Looking Statements Certain statements within this presentation may constitute forward-looking statements within the meaning of the Private Securities Litigation Reform Act of 1995. Such statements relate to a variety of matters, including but not limited to: the timing and costs associated with and the availability of capital for Gevo s scheduled retrofits of existing ethanol production facilities, its future isobutanol production capacity, the timing associated with bringing such capacity online, the availability of additional production volumes to seed additional market opportunities, the expected applications of isobutanol, including its use to produce renewable paraxylene, PET, isobutanol-based fuel blends for use in small engines, and ATJ bio-jet, addressable markets, and market demand, Gevo s ability to produce commercial quantities of isobutanol from cellulosic feedstocks, the suitability of Gevo s idgs for the animal feed market, the expected cost-competitiveness and relative performance attributes of isobutanol and the products derived from it, the strength of Gevo s intellectual property position and other statements that are not purely statements of historical fact. These forward-looking statements are made on the basis of the current beliefs, expectations and assumptions of Gevo s management and are subject to significant risks and uncertainty. All such forward-looking statements speak only as of the date they are made, and Gevo assumes no obligation to update or revise these statements, whether as a result of new information, future events or otherwise. Although Gevo believes that the expectations reflected in these forward-looking statements are reasonable, these statements involve many risks and uncertainties that may cause actual results to differ materially from what may be expressed or implied in these forward-looking statements. For a discussion of the risks and uncertainties that could cause actual results to differ from those expressed in these forward-looking statements, as well as risks relating to the business of the company in general, see the risk disclosures in Gevo s Annual Report on Form 10-K for the year ended December 31, 2011, as amended, and in subsequent reports on Forms 10-Q and 8-K and other filings made with the Securities and Exchange Commission by Gevo. This presentation is based on information that is generally available to the public and does not contain any material, non-public information. This presentation has been prepared solely for informational purposes and is neither an offer to purchase nor a solicitation of an offer to sell securities. 2013 Gevo, Inc. 2

Multiple Feedstocks; Proprietary Technology; Numerous End Markets Feedstock Proprietary Technology Bio- Cracker GIFT Separator Direct drop-in Green Processing Target Markets 2013 Gevo, Inc. 3

Seven Strategic End Markets; Strong Customers Specialty Chemicals Gasoline Blendstock C4 Market Bio-PX/PET Bio-Jet Hydrocarbon Fuels Co-Product Revenues Lower Cost, Drop-In Cleaner Performance Structurally Short Supply Green Supply Chain High Performance Fully Renewable Food First ~$7bln TAM ~$100bln TAM ~$8bln TAM ~$100bln TAM ~$200bln TAM >$1trl TAM ~$6bln TAM Sasol off-take and distribution agreement in place Accounts for majority of Luverne and Redfield capacity Sasol has begun customer sampling of Gevo s isobutanol Mansfield agreement, with their 900+ supply points, will initially focus on Marine VP Racing Fuels to evaluate a wide array of fuel applications LOI with Total to evaluate isobutanol as a second-gen biofuel blendstock LANXESS 10- year exclusive global supply agreement in place Negotiating terms for Canadian supply agreement Coca-Cola partnership to create fully renewable PET for plant-based packaging Toray off-take agreement to create renewable Paraxylene for fibers and films U.S. Air Force s (USAF) initial volume delivered with testing underway USAF interested in energy security / alternative jet fuel supply USAF test flight end of June United Airlines LOI in place Mansfield agreement, with supplier network in place, will support regional distribution rollout strategy Purina, the premier brand owner, partnership to maximize value of co-products Exploring how to enhance the value of isobutanol Distillers Grains (idgs or animal feed) Source: Company materials, IEA, EIA and Nexant 2013 Gevo, Inc 4

Oil:Corn Starch Ratio ($/MT Basis) Historical Oil:Corn Relationship 6.0 5.0 4.0 3.0 2.0 1.0 0.0 2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 Ratios determined using EIA Brent Oil, CBOT corn Net Corn determined with DDGs value at 80% of corn, DDG yield of 17 lb/bu and dextrose yield of 36 lb/bu Sources: CBOT, EIA 2013 Gevo, Inc. 5

Economics and Pricing Breakdown Lower Oil ~Current Oil Higher Oil Oil (MT) $445 ($60/bbl) $742 ($100/bbl) $1,002 ($135/bbl) Carbohydrate (MT) $104 ($60/MT biomass) $144 ($80/MT biomass) $184 ($100/MT biomass) Oil / Carbohydrate Ratio Addressable Market 4.3 5.2 5.5 $10 B >$40 B >$3 T **Market opportunity driven by spread between carbohydrate and oil 2013 Gevo, Inc. 6

Our Technology is Based on Metabolic Engineering 2013 Gevo, Inc. 7

Retrofit Commercial Ethanol Yeast to Make Isobutanol Ethanol Isobutanol Glucose Glucose

Titer of ibuoh (g/l) Cellulosic Sugar Converting Yeast Cellulosic Sugars Isobutanol Conversion of C5 & C6 sugars to butanol X X 120.00 100.00 80.00 60.00 40.00 20.00 0.00 X

Gevo s Approach to Cellulosic Feedstock Customers are very excited about cellulosic feedstocks sustainability advantages and avoidance of Food vs. Fuel Discussion Cellulose has the potential to significantly impact our feedstock cost and ultimately the cost of production of isobutanol Gevo looks to suppliers of cellulosic sugars in any of a number of possible relationships Gevo will not develop cellulosic sugar technology 2013 Gevo, Inc. 10

Gevo s Isobutanol Process with Corn Feedstock The Process of making ethanol starts here Fresh Water & 4 Recycled Water Sources Steam Enzymes New Jet Cooker Fermentation Re-Use Isobutanol Recovery GIFT Finished Product Molecular Sieves Beer DDGS Drum Dryer Syrup Wet Grain Re-Use Distillation System Evaporation System Thin Stillage 2013 Gevo, Inc. 11

Gevo s Isobutanol Process with Cellulose Feedstock The Process of making ethanol starts here Fresh Water & 4 Recycled Water Sources Steam Enzymes New Could be Cellulosic Sugar with Lignin Co-Product Finished Product Jet Cooker Molecular Sieves Fermentation Re-Use Beer Isobutanol Recovery GIFT DDGS Drum Dryer Syrup Wet Grain Re-Use Distillation System Evaporation System Thin Stillage 2013 Gevo, Inc. 12

Possible Cellulosic Sugar Partners Cellulosic sugar technologies that are or have started commercial operations are easily converted or can be designed using the identical GIFT as those using corn dry mill sugar Other emerging cellulosic sugar technologies potentially offer different opportunities for integration with Gevo Technology 2013 Gevo, Inc. 13

Feedstocks Gevo as a sugar consumer is open to multiple feedstocks which are obviously more of a design issue to the converter of Biomass to sugar, but will most likely impact the supplied sugar stream Feedstocks that we ve Tested Include: Arundo Donex Douglas Fir Douglas Fir Slash Corn Stover We are a proponent of campaigning feedstocks to minimize storage and risk of supply disruptions Campaigns would allow for adjusting of processing to accommodate differences 2013 Gevo, Inc. 14

Commercial Production 2013 Gevo, Inc. 15

Our Plants 1 st Commercial Plant: Luverne, MN ~18 MGPY commercial isobutanol production facility Purchased in 2010 & 100% owned by Gevo 2 nd Commercial Plant: Redfield, SD ~40 MGPY commercial isobutanol facility Entered into JV with 650 members in 2011 with economics, post retrofit, to be split approximately 50/50 Luverne, MN Plant Redfield, SD Plant 2013 Gevo, Inc. 16

Leveraging Petrochemical & Refinery Assets Jet Fuel Blendstock Octane, Gasoline ATJ Demonstration Facility near Houston Delivered >17K gallons ATJ to AFRL Alcohol-to-Fuel US Patent 8,193,402 Covers C2-C6 alcohols to hydrocarbon fuel Diesel Blendstock Para-xylene (for PET) 2013 Gevo, Inc. 17

Gevo ATJ Fuel Makes History in USAF Flight June 28, 2012 40 th Flight Test Squadron made history flying Gevo s 50% ATJ and 50% JP- 8 fuel blend It flew like a usual A-10 without any issues. Maj. Olivia Elliott, A-10 pilot You won t be able to determine the difference and you won t care, because all perform as JP-8. Jeff Braun, Chief for the Air Force Alternative Fuel Certification Division 2013 Gevo, Inc. 18