King Industries, Inc. Additives & Synthetic Base Oils for Use in Lubricants with Incidental Food Contact

Transcription

1 King Industries, Inc. Additives & Synthetic Base Oils for Use in Lubricants with Incidental Food Contact NSF HX-1 Registered Products: KR - Synthetic Base Oils AW - Multi-functional Additive K-CORR NF - Yellow Metal Deactivator AO - Antioxidant NA-SUL - Corrosion Inhibitor

2 Innovative Products Supported By Dedicated Technical Service Visit Us At: CONTACT King Industries, Inc. USA Headquarters Science Road Norwalk, CT PH: FAX: King Industries - Europe Noordkade EZ Waddinxveen, The Netherlands PH: FAX:

3 King Industries NSF HX-1 Registered Products King Industries now offers a number of high performance additives and base oils/base oil modifiers that are NSF HX-1 registered for use in lubricants with incidental food contact. Complying with FDA CFR , these specialty products include: KR-006FG, KR-015FG, and KR-029FG are unique alkylated aromatic base oils with good solubility and exceptional hydrolytic and thermo-oxidative stability. AW-6400FG is a high performance, multi-functional additive that offers anticorrosion, antiwear and extreme pressure properties. AO-142 is a liquid, easy to handle, diphenylamine antioxidant. K-CORR NF-200 is an ashless, yellow metal deactivator/corrosion inhibitor. NA-SUL CA-770FG is a premium rust inhibitor that provides excellent demulsibility and filterability and is compatible with a wide range of additives and base stocks. PRODUCT Chemical Composition 40 C ASTM D445 DIN C ASTM D 4052 Misc. Maximum Allowable Treat Level NSF HX-1 Registration # SYNTHETIC BASE OILS & BASE OIL MODIFIERS KR-006FG KR-015FG KR-029FG Proprietary Alkylated Aromatic Proprietary Alkylated Aromatic Proprietary Alkylated Aromatic 36 mm 2 /s (cst) 124 mm 2 /s (cst) 174 mm 2 /s (cst) 0.90 g/ml 7.5 lbs./gal g/ml 7.40 lbs./gal g/ml 7.29 lbs./gal. HIGH PERFORMANCE ADDITIVES - Liquid Rust Preventive/Demulsifier NA-SUL CA-770FG Neutral Calcium Sulfonate in PAO 214 mm 2 /s (cst) 0.91 g/ml 7.6 lbs./gal. Pour Point ASTM D 97-33ºC Pour Point ASTM D C Pour Point ASTM D C LIQUID MULTI-FUNCTIONAL ADDITIVE - Anticorrosion, Antiwear & Extreme Pressure AW-6400FG Amine Salts of Aliphatic Phosphoric Acid Esters 1400 mm 2 /s (cst) LIQUID DIPHENYLAMINE BASED ANTIOXIDANT AO-142 Butylated, Octylated Diphenylamine 280 mm 2 /s (cst) 0.97 g/ml 8.06 lbs./gal g/ml 8.20 lbs./gal. LIQUID YELLOW METAL DEACTIVATOR/CORROSION INHIBITOR K-CORR NF-200 Proprietary Heterocyclic Derivative 78 mm 2 /s (cst) 0.95 g/ml 7.90 lbs./gal. * Not to exceed minimum amount required to achieve desired technical effect 165ºC 10% by weight Content Nitrogen 2.4% Phosphorus 8.3% Nitrogen Content 4.5% Flash Point, COC ASTM D 92 DIN C 100%* %* %* % by weight 0.5% by weight 0.1% by weight

4 Synthetic Base Oils KR-006FG, KR-015FG & KR-029FG These unique synthetic base oils are used to formulate high performance lubricants and greases. They offer outstanding solubility and excellent hydrolytic and thermo-oxidative stability. The chart that follows offers a relative, property comparison of the KR products to other commonly used HX-1 base fluids. Property NA-LUBE KR-006FG, KR-015FG & KR-029FG PAO Esters White Oils Thermo-oxidative Stability Excellent Good Good to Excellent Fair Thermal Stability Excellent Excellent Excellent Good Hydrolytic Stability Excellent Excellent Poor Excellent Additive Solubility Good to Excellent Poor Excellent Good Thermal Stability The Cincinnati Milacron Thermal Stability Test is used to evaluate the thermal stability of fluids in the presence of copper and steel at elevated temperatures for 168 hours. Normally, run at 135 C, KR-015FG and a PAO were tested at elevated temperatures (200 C and 225 C) both neat and with an package containing an antioxidant and a yellow metal deactivator. Not surprisingly, due to breakdown and polymerization, the PAO experienced a very high viscosity increase. CINCINNATI MILACRON THERMAL STABILITY TEST - Modified to higher temperatures, 200 C, 225 C BASE FLUID Total Sludge (mg/100ml) Neat 200 C Neat 225 C % Viscosity Increase Total Sludge (mg/100ml) %Viscosity Increase KR-015FG PAO* * PAO viscosity of C Thermo-Oxidative Stability Both KR-015FG and KR-029FG demonstrated significant performance advantages over PAO (blended to an equal viscosity) when tested in the Rotating Pressure Vessel Oxidation Test (RPVOT-ASTM D 2272) as neat fluids and with the addition of 0.2% antioxidants. When tested using Pressure Differential Scanning Calorimetry versus both a white oil and PAO, at 200 C and 210 C, the KR products again demonstrated their superior oxidative stability. RPVOT - ASTM D Rotating Pressurized Vessel Oxidation Test BASE FLUID PAO* KR-015FG KR-029FG Induction Time (Minutes) Neat Induction Time Minutes with 0.2% NA-LUBE AO PDSC - ASTM D Pressure Differential Scanning Calorimetry BASE FLUID PAO White Oil KR-015FG KR-029FG Induction Time 200 C <1 < Induction Time 210 C <1 <1 9 4

5 Liquid Rust Preventive/Demulsifier NA-SUL CA-770FG NA-SUL CA-770FG is a premium rust inhibitor for petroleum and synthetic lubricants, greases, and rust preventive fluids. It provides excellent demulsibility and filterability and is compatible with a wide range of additives and base stocks. Base Oil PAO 6 cst (39 cst at 40 C) White Oil (40 cst at 40 C) NA-LUBE KR-006FG (37 cst at 40 C) Treat Level 0.05% 0.05% 0.05% Steel Corrosion (ASTM D 665, DIN ) B Pass Pass Pass Demulsibility (ASTM D 1401, DIN ) Oil Water Emulsion Time (Minutes) NA-SUL CA-770FG Rust & Corrosion Inhibitor Food grade HX-1 Aluminum Complex Grease ASTM 1743 Fail 0.5% NA-SUL CA-770FG in HX-1 Food Grade Aluminum Complex ASTM 1743 Pass Additives - 0.5% NA-SUL CA-770FG 0.5% NA-LUBE AO-142 Base Grease Al Complex Al Complex ASTM D 1743 (48 hrs.)* Water Type Rating * Performance Shown in Pictures Above Distilled Fail Distilled Pass Additives - 1.5% NA-SUL CA-770FG 0.5% NA-LUBE AO-142 Base Grease Al Complex Al Complex ASTM D 5969 (24 hrs.) Water Type Rating SSW = Synthetic Sea Water 5% SSW Fail 5% SSW Pass

6 Multi-functional Additive AW-6400FG NA-LUBE AW-6400FG is an ashless, HX-1 approved, multi-functional additive that offers anticorrosion, antiwear and EP properties. It is especially well suited for food grade lubricants that require rust protection and high load capacity (FZG) at low treat levels. Typically used in the % range, NA-LUBE AW-6400FG is: Light in color An easy to handle, liquid Soluble in all common food grade basestocks and most common solvents Corrosion Inhibition Comparison (Synthetic Sea Water - Steel Corrosion Test) 0.2% NA-LUBE AO-142, 0.5% Ashless Dithiocarbamate 0.2% AO-142, 0.5% Ashless Dithiocarbamate and 0.5% NA-LUBE AW 6400FG TESTS FORMULATIONS All HX-1 Base Oils Treated with 0.50% NA-LUBE AW-6400FG HX-1 Approved Base Oils PAO 10 White Oil PAG (water soluble) 40 C (ASTM D 445, DIN ) NA-LUBE KR-015FG NA-LUBE KR-029FG Ester 66 cst 110 cst 120 cst 124 cst 174 cst 220 cst 100 C (ASTM D 445, DIN ) Steel Corrosion (ASTM D 665 A & B, DIN ) Demulsibility (ASTM D 1401, DIN ) Oil-Water-Emulsion Separation Time (Minutes) Copper Corrosion (ASTM D 130, DIN ) 3 hours, 100 C 24 hours, 100 C Four Ball Weld Load (ASTM D 2783) OK Load (kgf) Weld Load (kgf) Four Ball Wear (ASTM D 4172) Scar Diameter (mm) 1 hour, 75 C, 1200 rpm, 30 kg 1 hour, 75 C, 1200 rpm, 40 kg 10 cst 12 cst 27 cst 14 cst 19 cst 20 cst Pass Pass Pass (stain) Pass Pass Pass (stain) NA FALEX Pin & Vee (ASTM D 3233) lbs

7 Antioxidant AO-142 NA-LUBE AO-142 is a butylated, octylated, diphenylamine antioxidant that can be used at levels up to 0.50% in food grade applications. It is ashless, non-corrosive and soluble in a wide range of H-1 base fluids. As shown in the test data that follows, additive levels of 0.2% and 0.5% NA-LUBE AO-142 in various base oils resulted in a significant increase in the lifetime as measured by RPVOT - ASTM D % NA-LUBE AO-142 Testing RPOVT - Rotating Pressure Vessel Oxidation (ASTM D 2272) 40 C / 100ºC (cst) ASTM D 445 DIN Control No Antioxidant (min) W/ Base Oil (min) PAO / White Oil 110 / PAG (water soluble) 120 / NA-LUBE KR-015FG 124 / NA-LUBE AO-142 is a liquid product for easy incorporation and imparts enhanced thermal and oxidative stability. NA-LUBE KR-029FG 174 / Ester 220 / Yellow Metal Deactivator/Corrosion Inhibitor K-CORR NF-200 K-CORR NF-200 is a HX-1 food grade approved yellow metal deactivator that protects copper and copper alloys against corrosion initiated by active sulfur. K-CORR NF-200 also enhances the oxidation stability of food grade lubricants and greases when used in combination with HX-1 food grade approved AO-142 and an ashless dithiocarbamate. K-CORR NF-200 is recommended for formulating high performance food grade circulating and steam turbine oils, hydraulic oils, vacuum oils, and industrial gear oils, as well as greases. A B Copper Corrosion ASTM D 130 ISO VG 110 White Oil 24 C A. 0.2% NA-LUBE AO-142, 0.5% ashless dithiocarbamate B. A % K-CORR NF-200 TESTS BASE OIL FORMULATION 0.20% NA-LUBE AO % NA-LUBE AO % Ashless Dithiocarbamate ISO VG White Oil 0.20% NA-LUBE AO % Ashless Dithiocarbamate 0.05% K-CORR NF-200 Copper Corrosion ASTM D 130, DIN hours, 100 C 24 hours, 100 C 2a 3b Demulsibility ASTM D 1401, DIN Oil-Water-Emulsion Time (Minutes) RPVOT ASTM D 2272 Lifetime (Minutes)

8 DISCLAIMERS The results shown reflect data generated by King Industries Technical Service Laboratory. Actual results may vary depending on the additive package, base oil, and test equipment design. FG-11/13 The conditions of your use and application of our products, technical assistance and information (whether verbal, written or by way of product evaluations), including any suggested formulations and recommendations, are beyond our control. Therefore, it is imperative that you test our products, technical assistance and information to determine to your own satisfaction whether they are suitable for your intended uses and applications. Such testing has not necessarily been done by King Industries, Inc. ("King"). The facts, recommendations and suggestions herein stated are believed to be reliable; however, no guaranty or warranty of their accuracy is made. EXCEPT AS STATED, THERE ARE NO WARRANTIES, EXPRESS OR IMPLIED, OF MERCHANTABIL- ITY, FITNESS OR OTHERWISE. KING SHALL NOT BE HELD LIABLE FOR SPECIAL, INCIDENTAL, CONSEQUENTIAL OR EXEMPLARY DAMAGES. Any statement inconsistent herewith is not authorized and shall not bind King. Nothing herein shall be construed as a recommendation to use any product (s) in conflict with patents covering any material or its use. No license is implied or granted under the claims of any patent. Sales or use of all products are pursuant to Standard Terms and Conditions stated in King sales documents.