Gandipet, Hyderabad Telangana State, India. Chevella, Rangareddy (dist) , Telangana, India

Transcription

1 Experimental investigations of comparative performance and exhaust emissions of cottonseed biodiesel fuelled DI diesel engine with low grade LHR combustion chamber M.V.S. Murali Krishna 1, D. Srikanth 2, and P.Ushasri 3 1 Mechanical Engineering Department, Chaitanya Bharathi Institute of Technology Gandipet, Hyderabad Telangana State, India 2 Department of Mechanical Engineering, Sagar Group of Institutions Chevella, Rangareddy (dist) , Telangana, India Mechanical Engineering Department, College of Engineering, Osmania University Hyderabad , Telangana State, India ABSTRACT Investigations were carried out to evaluate the performance and study exhaust emission of a low grade low heat rejection (LHR) diesel engine with ceramic coated cylinder head [ceramic coating of thickness 500 microns was done on inside portion of cylinder head] with different operating conditions [normal temperature and pre-heated temperature] of cotton seed biodiesel with varied injector opening pressure and injection timing. Performance parameters [brake thermal efficiency, brake specific energy consumption, exhaust gas temperature, coolant load and volumetric efficiency] were evaluated at different values of brake mean effective pressure (BMEP) of the engine, while exhaust emissions [particulate emissions and nitrogen oxide (NO x) levels)]were measured at full load operation of the engine. Comparative studies were made with conventional engine (CE) with biodiesel and also with mineral diesel operation working on similar operating conditions. Engine with LHR combustion chamber improved its performance when compared with CE with biodiesel operation. The optimum injection timing with CE with biodiesel was 31 o btdc (before top dead centre), while it was 30 o btdc for engine with LHR combustion chamber. Engine with LHR combustion chamber at optimum injection timing of 30 o btdc with biodiesel operation increased peak brake thermal efficiency by 7%, at full load operation decreased coolant load at full load by 15%, reduced volumetric efficiency by 6%, particulate emissions by 69% and increased NOx levels by 29 % in comparison with CE with neat diesel operation at manufacturer s recommended injection timing of 27 o btdc Keywords: Crude vegetable oil, biodiesel, LHR combustion chamber, fuel performance, Exhaust emissions. 1. INTRODUCTION Increased environmental awareness and depletion of resources are driving industry to develop alternative fuels that are environmentally more acceptable. Fuel crisis because of dramatic increase in vehicular population and environmental concerns have renewed interest of scientific community to look for alternative fuels of bio-origin such as vegetable oils. Vegetable oils are important substitutes of diesel fuels, as their properties are comparable to diesel fuels. The idea of using vegetable oil as fuel has been around from the birth of diesel engine. Rudolph diesel, the inventor of the engine that bears his name, experimented with fuels ranging from powdered coal to peanut oil and hinted that vegetable oil would be the future fuel [1]. Several researchers experimented the use of vegetable oils as fuel on conventional engines and reported that the performance was poor, citing the problems of high viscosity, low volatility and their polyunsaturated character. [1 3].These problems can be solved to some extent, if neat vegetable oils are chemically modified (esterified) to bio-diesel. Experiments were conducted on conventional diesel engine with biodiesel operation and it was reported that biodiesel increased efficiency marginally and decreased particulate emissions and increased oxides of nitrogen.[4 6]. Experiments were conducted on preheated vegetable oils in order to equalize their viscosity to that of mineral diesel may ease the problems of injection process [7 9]. Investigations were carried out on engine with preheated vegetable oils. It was reported that preheated vegetable oils marginally increased thermal efficiency, decreased particulate matter emissions and NO x levels, when compared with normal biodiesel. Increased injector opening pressure may also result in efficient combustion in compression ignition engine [10-11]. It has a significance effect on performance and formation of pollutants inside the direct injection diesel engine combustion. Experiments were conducted on engine with biodiesel with increased injector opening pressure. It was reported that performance of the engine was improved, particulate emissions were reduced and NO x levels were increased marginally with an Volume 3, Issue 9, September 2014 Page 321

2 increase of injector opening pressure. The drawbacks (high viscosity and low volatility) of biodiesel call for LHR engine which provide hot combustion chamber for burning these fuels which got high duration of combustion. The concept of engine with LHR combustion chamber is to minimize heat loss to the coolant by providing thermal insulation in the path of the coolant thereby increases the thermal efficiency of the engine. Several methods adopted for achieving LHR to the coolant are i) using ceramic coatings on piston, liner and cylinder head (low grade LHR combustion chamber) ii) creating air gap in the piston and other components with low-thermal conductivity materials like superni (an alloy of nickel), cast iron and mild steel etc. (medium grade LHR combustion chamber) and iii) combination of low grade and medium grade LHR combustion chamber resulted in high grade LHR combustion chamber. Investigations were carried out on engine with l ow grade LHR combustion chamber with neat diesel operation and it was reported that ceramic coatings provided adequate insulation and improved brake specific fuel consumption (BSFC). [12 13]. Studies were made on ceramic coated diesel engines with biodiesel and reported that performance was comparable, particulate emissions decreased while NO x levels increased in comparison with neat diesel operation on CE. [14 16] However, comparative studies were not made with mineral diesel operation working on similar conditions. The present paper attempted to evaluate the performance parameters and exhaust emissions of the engine with LHR combustion chamber which contained ceramic coated cylinder head fuelled with different operating conditions of cotton seed biodiesel with varied injector opening pressure and injection timing and compared with CE with biodiesel operation and also with mineral diesel operation working on similar working conditions. 2. MATERIALS AND METHODS 2.1 Preparation of biodiesel: The chemical conversion of esterification reduced viscosity four fold. Cotton seed oil contains up to 70 % (wt.) free fatty acids. The methyl ester was produced by chemically reacting crude cotton seed oil with methanol in the presence of a catalyst (KOH). A two stage process was used for the esterification of the crude cotton seed oil [5]. The first stage (acid-catalyzed) of the process is to reduce the free fatty acids (FFA) content in cotton seed oil by esterification with methanol (99% pure) and acid catalyst (sulfuric acid-98% pure) in one hour time of reaction at 55 C. Molar ratio of cotton seed oil to methanol was 9:1 and 0.5% catalyst (w/w). In the second stage (alkali-catalyzed), the triglyceride portion of the cotton seed oil reacts with methanol and base catalyst (sodium hydroxide 99% pure), in one hour time of reaction at 65 C, to form methyl ester (biodiesel) and glycerol. To remove un reacted methoxide present in raw methyl ester, it is purified by the process of water washing with air bubbling. The properties of the Test Fuels used in the experiment were presented in Table-1. Table.1. [5] Properties Test Fuels 2.2 Experimental Set-up: Partially stabilized zirconium (PSZ) of thickness 500 microns was coated on inside portion of cylinder head. Experimental setup used for study of exhaust emissions on low grade LHR diesel engine with linseed biodiesel in Fig.1 The specification of the experimental engine is shown in Table.2 The engine was connected to an electric dynamometer (Kirloskar make) for measuring its brake power. Dynamometer was loaded by loading rheostat Figure.1. Experimental Set up Volume 3, Issue 9, September 2014 Page 322

3 1.Engine, 2.Electical Dynamo meter, 3.Load Box, 4.Orifice meter, 5.U-tube water manometer, 6.Air box, 7.Fuel tank, 8, Three way valve, 9.Burette, Exhaust gas temperature indicator,11. AVL Smoke meter, 12. NOx Analyzer, 13. Outlet water jacket temperature indictor, 14. Water flow meter, The combustion chamber consisted of a direct injection type with no special arrangement for swirling motion of air. Burette method was used for finding fuel consumption of the engine. Air-consumption of the engine was measured by air box method. The naturally aspirated engine was provided with water-cooling system in which outlet temperature of water is maintained at 80oC by adjusting the water flow rate. Engine oil was provided with a pressure feed system. No temperature control was incorporated, for measuring the lube oil temperature. The naturally aspirated engine was provided with water-cooling system in which outlet temperature of water is maintained at 80oC by adjusting the water flow rate. Injector opening pressure was changed from 190 bar to 270 bar using nozzle testing device. The maximum injector opening pressure was restricted to 270 bar due to practical difficulties involved. Injection timing was changed by inserting copper shims between pump body and engine frame. Exhaust gas temperature (EGT) and coolant water outlet temperatures were measured with thermocouples made of iron and iron-constantan attached to the temperature indicator. Exhaust emissions of particulate matter emissions and nitrogen oxide levels at full load operation were recorded by Smoke opacity meter (AVL India, 437) and NOx analyzer (Netel Chromatograph NOx Analyzer, VM 4000). Table.2 Specifications of the Test engine 2.3 Operating Conditions: Different configurations of the combustion chamber used in the experiment were conventional engine and engine with LHR combustion chamber. The various operating conditions of the vegetable oil used in the experiment were normal temperature (NT) and preheated temperature (PT It is the temperature at which viscosity of the vegetable oil is matched to that of diesel fuel, 80oC). The injection pressures were varied from 190 bar to 270 bar. Various test fuels used in the experiment were biodiesel and diesel. The engine was started and allowed to have a warm up for about 15 minutes. Each test was repeated twelve times to ensure the reproducibility of data according to error analysis (Minimum number of trials must be not less than ten). The results were tabulated and a comparative study of performance parameters, were determined for various loads, injector opening pressures, injection timings at different operating conditions of the fuel. 3. RESULTS AND DISCUSSION 3.1 Fuel Performance The optimum injection timing was 31o btdc with CE, while it was 30o btdc for engine with low grade LHR combustion chamber with mineral diesel operation [14,15]. From Fig.2, it is observed CE with biodiesel at 27o btdc showed comparable performance at all loads due to improved combustion with the presence of oxygen, when compared with mineral diesel operation on CE at 27o btdc. CE with biodiesel operation at 27o btdc decreased peak BTE by 3%, when compared with diesel operation on CE. This was due to low calorific value and high viscosity of biodiesel. CE with biodiesel operation increased BTE at all loads with advanced injection timing, when compared with CE with biodiesel operation at 27o btdc. This was due to initiation of combustion at early period and increase of resident time of fuel with air leading to increase of peak pressures. CE with biodiesel operation increased peak BTE by 4% at an optimum injection timing of 31o btdc, when compared with diesel operation at 27o btdc. Volume 3, Issue 9, September 2014 Page 323

4 Figure.2 Variation of brake thermal efficiency (BTE) with brake mean effective pressure (BMEP) in conventional engine (CE) and with various injection timings at an injector opening pressure of 190 bar with biodiesel Curves in Fig.3 indicate that LHR version of the engine at recommended injection timing showed the improved performance at all loads except at full load compared with CE with pure diesel operation. High cylinder temperatures helped in improved evaporation and faster combustion of the fuel injected into the combustion chamber. Reduction of ignition delay of the vegetable oil in the hot environment of the LHR combustion chamber improved heat release rates and efficient energy utilization. The optimum injection timing was found to be 30obTDC with LHR combustion chamber with different operating conditions of biodiesel operation. Since the hot combustion chamber of LHR combustion chamber reduced ignition delay and combustion duration and hence the optimum injection timing was obtained earlier with LHR combustion chamber when compared to conventional engine with the biodiesel operation. Part load variations were very small and minute for the performance parameters. The effect of varied injection timing on the performance was discussed with the help of bar charts while the effect of injector opening pressure and preheating of biodiesel was discussed with the help of Tables. Figure.3 Variation of brake thermal efficiency (BTE ) with brake mean effective pressure (BMEP) in LHR combustion chamber at different injection timings with biodiesel (LSOBD) operation. From Fig.4, it is noticed that CE with biodiesel operation decreased peak BTE by 4% at 27o btdc and 7% at 31o btdc when compared with neat diesel operation on CE. This was due to high viscosity and low calorific value and volatility of biodiesel. Engine with LHR combustion chamber with biodiesel operation increased peak BTE by 2% at 27o btdc and 3% at 30o btdc when compared with neat diesel operation on same configuration of the combustion chamber. This was due to improved combustion with higher cetane value of biodiesel in hot environment provided by the LHR combustion chamber Figure.4 Bar charts showing the variation of peak brake thermal efficiency (BTE) with test fuels at recommended and optimized injection timings at an injector opening pressure of 190 bar in conventional engine and ceramic coated LHR combustion chamber Volume 3, Issue 9, September 2014 Page 324

5 However, engine with LHR combustion chamber with biodiesel increased peak BTE by 4% at 27 o btdc and 3% at 30 o btdc in comparison with CE at 27 o btdc and at 31 o btdc. This was due to provision of insulation on cylinder head which reduced heat rejection leading to improve the thermal efficiency. This was also because of improved evaporation rate of the biodiesel. High cylinder temperatures helped in improved evaporation and faster combustion of the fuel injected into the combustion chamber. Reduction of ignition delay of biodiesel in the hot environment of the engine with LHR combustion chamber improved heat release rates and efficient energy utilization. Brake specific fuel consumption, is not used to compare the two different fuels, because their calorific value, density, chemical and physical parameters are different. Performance parameter, brake specific energy consumption (BSEC), is used to compare two different fuels by normalizing brake specific energy consumption, in terms of the amount of energy released with the given amount of fuel. From Fig.5, it is evident that engine with LHR combustion chamber with mineral diesel decreased BSEC at full load operation by 8% at 27 o btdc and 6% at 30 o btdc in comparison with CE at 27 o btdc and at 31 o btdc. This was due to reduction of ignition delay with neat diesel operation with LRH engine as hot combustion chamber was provided with engine with LHR combustion chamber. CE with biodiesel operation showed comparable BSEC at full load at 27 o btdc, while increasing it by 6% at 31 o btdc when compared with neat diesel operation on CE. This was due to low calorific value of biodiesel requiring higher energy to produce unit brake power. Engine with LHR combustion chamber with biodiesel operation decreased BSEC at full load by 3% at 27 o btdc and 1% at 30 o btdc when compared with neat diesel operation on same configuration of the combustion chamber. Figure.5 Bar charts showing the variation of brake specific energy consumption (BSEC) at full load operation with test fuels at recommended and optimized injection timings at an injector opening pressure of 190 bar in CE and LHR combustion chamber. This was due to reduction of ignition delay and producing peak pressures at near TDC with biodiesel operation. However, engine with LHR combustion chamber with biodiesel decreased BSEC at full load operation by 2% at 27 o btdc and 1% at 30 o btdc in comparison with CE at 27 o btdc and at 31 o btdc. BSEC was higher with CE due to due to higher viscosity, lower volatility and reduction in heating value of biodiesel lead to their poor atomization and combustion characteristics. The viscosity effect, in turn atomization was more predominant than the oxygen availability leads to lower volatile characteristics and affects combustion process. BSEC was improved with LHR combustion chamber with lower substitution of energy in terms of mass flow rate. BSEC decreased with advanced injection timing with test fuels. This was due to initiation of combustion and increase of atomization of fuel with more contact of fuel with air. BSEC of biodiesel is almost the same as that of neat diesel fuel as shown in Figure.4. Even though viscosity of biodiesel is slightly higher than that of neat diesel, inherent oxygen of the fuel molecules improves the combustion characteristics. This is an indication of relatively more complete combustion. Figure.6. Bar charts showing the variation of exhaust gas temperature (EGT) at full load operation with test fuels at recommended and optimized injection timings at an injector opening pressure of 190 bar in conventional engine and LHR combustion chamber. Though calorific value of biodiesel is less, its density is high giving rise to higher heat input and hence higher EGT than mineral diesel operation. This was also due to retarded heat release rate of biodiesel due to its high duration of Volume 3, Issue 9, September 2014 Page 325

6 combustion with its high viscosity. Engine with LHR combustion chamber with biodiesel operation increased EGT at full load by 6% at 27 o btdc and 5% at 30 o btdc when compared with neat diesel operation on same configuration of the combustion chamber. However, engine with LHR combustion chamber with biodiesel operation increased EGT at full load by 6% at 27 o btdc and 10% at 30 o btdc in comparison with CE at 27 o btdc and at 31 o btdc. This indicated that heat rejection was restricted through cylinder head, thus maintaining the hot combustion chamber as result of which the exhaust gas temperature increased. EGT decreased with advanced injection timing with test fuels as seen from Figure. This was because, when the injection timing was advanced, the work transfer from the piston to the gases in the cylinder at the end of the compression stroke was too large, leading to reduce in the value of EGT. Though the calorific value (or heat of combustion) of fossil diesel is more than that of biodiesel; density of biodiesel was higher,therefore greater amount of heat was released in the combustion chamber leading to higher exhaust gas temperature with conventional engine, which confirmed that performance was comparable with CE with biodiesel operation in comparison with neat diesel operation. Injector opening pressure was varied from 190 bar to 270 bar to improve the spray characteristics and atomization of the test fuels and injection timing is advanced from 27 to 34 o btdc for CE and LHR combustion chamber. As it is observed from Table.3, peak brake thermal efficiency increased with increase in injector opening pressure at different operating conditions of the biodiesel. For the same physical properties, as injector opening pressure increased droplet diameter decreased influencing the atomization quality, and more dispersion of fuel particle, resulting in turn in better vaporization, leads to improved air-fuel mixing rate, as extensively reported in the literature [ 10,11 ]. In addition, improved combustion leads to less fuel consumption. Performance improved further with the preheated biodiesel when compared with normal biodiesel. This was due to reduction in viscosity of the fuel. Preheating of the biodiesel reduced the viscosity, which improved the spray characteristics of the oil causing efficient combustion thus improving brake thermal efficiency. The cumulative heat release was more for preheated biodiesel than that of biodiesel and this indicated that there was a significant increase of combustion in diffusion mode. This increase in heat release was mainly due to better mixing and evaporation of preheated biodiesel, which leads to complete burning. From Table.3, it is noticed that BSEC at full load operation decreased with increase of injector opening pressure with different operating conditions of the test fuels. This was due to increase of air entrainment in fuel spray giving lower BSEC. BSEC decreased with the preheated biodiesel at full load operation when compared with normal biodiesel. Preheating of the biodiesel reduced the viscosity, which improved the spray characteristics of the oil. From same Table, it is noticed that EGT at full load operation of preheated biodiesel was higher than that of normal biodiesel, which indicates the increase of diffused combustion due to high rate of evaporation and improved mixing between methyl ester and air. Therefore, as the fuel temperature increased, the ignition delay decreased and the main combustion phase(that is, diffusion controlled combustion) increased, which in turn raised the temperature of exhaust gases. The value of exhaust gas temperature decreased with increase in injector opening pressure with test fuels as it is evident from Table. This was due to improved spray characteristics of the fuel with increase of injector opening pressure. Table.3 Data of Peak Brake Thermal Efficiency, brake specific energy consumption and exhaust gas temperature at full load operation Figure.7 indicates CE with biodiesel operation increased coolant load at full load by 3% at 27 o btdc and 5% at 31 o btdc when compared with neat diesel operation on CE. This was due to un-burnt fuel concentration at combustion chamber walls. Engine with LHR combustion chamber with biodiesel operation decreased coolant load at full load by 5% at 27 o btdc and 6% at 30 o btdc when compared with neat diesel operation on same configuration of the combustion chamber. This was due to improved combustion eliminating deposits at near combustion chamber walls. Coolant load at full load operation increased with CE while decreasing with engine with LHR combustion chamber with advanced injection timing with test fuels.. In case of CE, un-burnt fuel concentration reduced with effective utilization of energy, released from the combustion, coolant load with test fuels increased marginally at full load operation, due to un-burnt fuel concentration reduced with effective utilization of energy, released from the combustion, with increase of gas temperatures, when the injection timing was advanced to the optimum value. However, the Volume 3, Issue 9, September 2014 Page 326

7 improvement in the performance of CE was due to heat addition at higher temperatures and rejection at lower temperatures, while the improvement in the efficiency of the engine with LHR combustion chamber was due to recovery from coolant load at their optimum injection timings with test fuels. Figure.7 Bar charts showing the variation of coolant load at full load operation with test fuels at recommended and optimized injection timings at an injector opening pressure of 190 bar in conventional engine and LHR combustion chamber. Volumetric efficiency depends on density of the charge which intern depends on temperature of combustion chamber wall. Fig. 8 denotes that engine with LHR combustion chamber with mineral diesel decreased volumetric efficiency at full load operation by 6% at 27 o btdc and 9% at 30 o btdc in comparison with CE at 27 o btdc and at 31 o btdc. Figure.8 Bar charts showing the variation of volumetric efficiency at full load operation with test fuels at recommended and optimized injection timings at an injector opening pressure of 190 bar in conventional engine and LHR combustion chamber. This was due increase of temperature of incoming charge in the hot environment created with the provision of insulation, causing reduction in the density and hence the quantity of air. However, this variation in volumetric efficiency is very small between these two versions of the engine, as volumetric efficiency mainly depends on speed of the engine, valve area, valve lift, timing of the opening or closing of valves and residual gas fraction rather than on load variation. However, engine with LHR combustion chamber with biodiesel decreased volumetric efficiency at full load operation by 5% at 27o btdc and 8% at 30o btdc in comparison with CE at 27o btdc and at 31o btdc with biodiesel operation. Volumetric efficiency was higher with neat diesel operation at recommended and optimized injection timing with both versions of the combustion chamber in comparison with biodiesel operation. This was due to increase of combustion chamber wall temperatures with biodiesel operation due to accumulation of un-burnt fuel concentration. This was also because of increase of combustion chamber wall temperature as exhaust gas temperatures increased with biodiesel operation in comparison with neat diesel operation. Volumetric efficiency increased Volume 3, Issue 9, September 2014 Page 327

8 marginally with both versions of the engine with test fuels with advanced injection timing. This was due to decrease of combustion chamber wall temperatures with improved air fuel ratios Table4 Data of Coolant Load and Volumetric Efficiency at full load operation From Table.4, it is observed that coolant load decreased marginally with preheating of biodiesel. This was due to improved air fuel ratios with improved spray characteristics. From same Table, it is seen that coolant load increased marginally in CE, while decreasing it in engine with LHR combustion chamber with increase of the injector opening pressure with test fuels. This was due to the fact with increase of injector opening pressure with conventional engine, increased nominal fuel spray velocity resulting in improved fuel-air mixing with which gas temperatures increased. The reduction of coolant load in the LHR combustion chamber was not only due to the provision of the insulation but also it was due to better fuel spray characteristics and increase of air-fuel ratios causing decrease of gas temperatures and hence the coolant load. From Table.4, it is evident that preheating of the biodiesel marginally decreased volumetric efficiency, when compared with the normal temperature of biodiesel, because of reduction of bulk modulus, density of the fuel and increase of exhaust gas temperatures. Volumetric efficiency at full load operation increased with increase of injector opening pressure with test fuels. This was due to improved fuel spray characteristics and evaporation at higher injection pressures leading to marginal increase of volumetric efficiency. This was also because of decrease of exhaust gas temperatures and hence combustion chamber wall temperatures. This was also due to the reduction of residual fraction of the fuel, with the increase of injector opening pressure. Figure.9. Variation of particulate emissions in Hartridge smoke unit (HSU) with brake mean effective pressure (BMEP) in conventional engine (CE) and engine with LHR combustion chamber at recommended injection timing and optimum injection timing and at an injector opening pressure of 190 bar with biodiesel 3.2 Exhaust Emissions Particulate emissions at full load reduced marginally with CE with biodiesel operation in comparison with mineral diesel operation on CE. This was due to improved combustion with improved cetane number and also with presence of oxygen in composition of fuel. Particulate emissions further reduced with engine with LHR combustion chamber when compared with CE. This was due to improved combustion with improved heat release rate. Particulate emissions reduced with advanced injection timing with both versions of the combustion chamber. This was due to increase of resident time and more contact o fuel with air leading to increase atomization. Availability of oxygen and high temperatures are favorable conditions to form NO x levels. Fig.10 indicates that NO x levels were marginally higher in Volume 3, Issue 9, September 2014 Page 328

9 CE, while they were drastically higher in engine with LHR combustion chamber at different operating conditions of the biodiesel at the full load when compared with diesel operation on CE. Figure.10. Variation of nitrogen oxide levels with brake mean effective pressure (BMEP) in conventional engine (CE) and engine with LHR combustion chamber at recommended injection timing and optimum injection timing and at an injector opening pressure of 190 bar with biodiesel This was also due to the presence of oxygen (10%) in the methyl ester, which leads to improvement in oxidation of the nitrogen available during combustion. This will raise the combustion bulk temperature responsible for thermal NO x formation. Increase of combustion temperatures with the faster combustion and improved heat release rates associated with the availability of oxygen in LHR engine caused drastically higher NO x levels in engine with LHR combustion chamber. From Table.5, it is understood that particulate emissions decreased with preheating with both versions of the combustion chamber. This was because of reduction of density, viscosity of fuel and improved spray characteristics of fuel. From same Table, it is noticed that, particulate emissions decreased with increase of injector opening pressure in both versions of the engine with test fuels. This was due to improved air fuel ratios with improved spray characteristics of the test fuels. Data in Table.3 shows that, NO x levels decreased with preheating of biodiesel. As fuel temperature increased, there was an improvement in the ignition quality, which caused shortening of ignition delay, which lowered the peak combustion temperature and suppressed NO x formation. Table.5 Data of Exhaust Emissions with biodiesel operation Injection timing (deg. btdc) Combustion chamber version Test Fuel Exhaust Emissions at full load operation Particulate Emissions (HSU) NO x Levels (ppm) Injector Opening Pressure (bar) Injector Opening Pressure (bar) NT PT NT PT NT PT NT PT CE Diesel CE BD LHR Diesel LHR BD LHR Diesel LHR BD CE Diesel CE BD NO x levels increased with an increase of injector opening pressure with different operating conditions of biodiesel with CE. Fuel droplets penetrate and find oxygen counterpart easily with the increase of injector opening pressure. Turbulence of the fuel spray increased the spread of the droplets which caused increase of gas temperatures marginally thus leading to increase in NO x levels with CE. Marginal decrease of NO x levels was observed in engine with LHR combustion chamber, due to decrease of combustion temperatures with improved air fuel ratios. 4. SUMMARY Advanced injection timing and increase of injector opening pressure improved performance with biodiesel operation nd reduced pollution levels of the engine with LHR combustion chamber. Preheated biodiesel further improved performance in both versions of the combustion chamber. Volume 3, Issue 9, September 2014 Page 329

10 Comparison with CE with biodiesel: Engine with low grade LHR combustion chamber with cottonseed biodiesel improved performance over CE on the aspect of peak brake thermal efficiency, brake specific energy consumption, coolant load, reduced particulate emissions. However, it increased exhaust gas temperatures marginally, reduced volumetric efficiency and drastically increased nitrogen oxide levels in comparison with CE. Engine with low grade LHR combustion chamber with cottonseed biodiesel decreased particulate emissions at full load operation by 22% at 27 o btdc and 40% at 30 o btdc in comparison with CE at 27 o btdc and 31 o btdc. It increased nitrogen oxide levels by 39% at 27 o btdc, while decreasing them by 4% at 30 o btdc in comparison with CE at 27 o btdc and 31 o btdc. Comparison with mineral diesel operation: Conventional engine with biodiesel operation showed comparable performance, while engine with LHR combustion chamber improved performance when compared with mineral diesel operation. Hence it can be conveniently said that that engine with LHR combustion chamber is more suitable for biodiesel operation. Conventional engine with biodiesel operation decreased particulate emissions at full load operation by 6% at 27 o btdc and 17% at 31 o btdc in comparison with CE at 27 o btdc and 31 o btdc with mineral diesel operation. Engine with LHR combustion chamber with biodiesel decreased particulate emissions at full load operation by 30% at 27 o btdc and 57% at 30 o btdc in comparison with same configuration of the combustion chamber with diesel operation at 27 o btdc and 30 o btdc. Conventional engine with biodiesel operation increased nitrogen oxide levels at full load operation by 6% at 27 o btdc and 5% at 31 o btdc in comparison with CE at 27 o btdc and 31 o btdc with mineral diesel operation. Engine with LHR combustion chamber with biodiesel increased nitrogen oxide levels at full load operation by 4% at 27 o btdc and 5% at 30 o btdc in comparison with same configuration of the combustion chamber with diesel operation at 27 o btdc and 30 o btdc 4.1. Research Findings Performance was evaluated with engine with LHR combustion chamber consisting of ceramic coated combustion chamber with varied injector opening pressure and injection timing at different operating conditions of cottonseed biodiesel. 4.2Recommendations Engine with low grade LHR combustion chamber gave lower volumetric efficiency at full load operation. The reduction of volumetric efficiency can be reduced by super charging. It gave higher NOx levels and hence selective catalytic reduction technique can be adopted to reduce NOx levels.[17] 4.3 Scientific Significance Change of injection timing and injection pressure were attempted to evaluate the performance of the engine with change of configuration of combustion chamber with different operating conditions of the biodiesel. 4.4 Social Significance Use of renewable fuels will strengthen agricultural economy, which curbs crude petroleum imports, saves foreign exchange and provides energy security besides addressing the environmental concerns and socio-economic issues. 4.5 Novelty Change of injection timing of the engine was accomplished by inserting copper shims between pump body and engine frame ACKNOWLEDGMENTS Authors thank authorities of Chaitanya Bharathi Institute of Technology, Hyderabad for providing facilities for carrying out research work. Financial assistance provided by All India Council for Technical Education (AICTE), New Delhi is greatly acknowledged. REFERENCES [1] N. Venkateswara Rao, M.V.S. Murali Krishna, and P.V.K. Murthy, Comparative studies on performance of tobacco seed oil in crude form and biodiesel form in direct injection diesel engine, International Journal of Automobile Engineering Research & Development, 3(4), pp , [2] D. Srikanth, M.V.S. Murali Krishna, P.Ushasri, and P.V.K. Krishna Murthy, Performance evaluation of a diesel engine fuelled with cotton seed oil in crude form and biodiesel form, International Journal of Academic Research for Multidisciplinary, 1(9) pp ,2013. [3] Avinash Kumar Agarwal and Atul Dhar, Experimental investigations of performance, emission and combustion characteristics of Karanja oil blends fuelled DICI engine, Renewable Energy, 52, pp , Volume 3, Issue 9, September 2014 Page 330

11 [4] P.M. McCarthy, M.G. Rasul, and S.Moazzem, Analysis and comparison of performance and emissions of an internal combustion engine fuelled with petroleum diesel and different biodiesels, Fuel, 90, pp , [5] Anirudh Gautam and Avinash Kumar Agarwal, Experimental investigations of [6] comparative performance, emission and combustion characteristics of a cottonseed biodiesel fueled four stroke locomotive diesel engine, Int J Engine Res,14, pp ,2013. [7] Maddali Krishna, and R. Chowdary, Comparative studies on performance evaluation of waste fried vegetable oil in crude form and biodiesel form in conventional diesel engine, SAE Paper , [8] M/ Pugazhvadivu, and K. Jayachandran, Investigations on the performance and exhaust emissions of a diesel engine using preheated waste frying oil as fuel, Renew energy, 30(14), pp , [9] D. Agarwal, and A.K. Agarwal, Performance and emissions characteristics of jatropha oil _preheated and blends_ in a direct injection compression ignition engine. Appl. Therm. Eng, 27(13), pp , [10] Hanbey Hazar and Huseyin Aydin, Performance and emission evaluation of a CI engine fueled with preheated raw rapeseed oil (RRO)-diesel blends, Applied Energy, 87, pp , [11] I. Celikten, An experimental investigation of the effect of the injection pressure on engine performance and exhaust emission in indirect injection diesel engines. Appl Therm Eng, 23, pp , [12] Avinash Kumar Agarwal, Dhananjay Kumar Srivastava, Atul Dhar, et al. Effect of fuel injection timing and pressure on combustion, emissions and performance characteristics of a single cylinder diesel engine. Fuel, 111, pp , [13] B. Ekrem, E. Tahsin, and C. Muhammet, Effects of thermal barrier coating on gas emissions and performance of a LHR engine with different injection timings and valve adjustments, Energy Conversion and Management,47, pp , [14] Ciniviz, M. Hasimoglu, C., Sahin, F. and Salman, M.S. Impact of thermal barrier coating application on the performance and emissions of a turbocharged diesel engine. Proc. The Institution of Mechanical Engineers Part D-Journal of Automobile Eng, 222 (D12), , [15] N. Venkateswara Rao, M.V.S. Murali Krishna, and P.V.K. Murthy, Comparative studies on exhaust emissions and combustion characteristics of ceramic coated diesel engine with tobacco seed oil based biodiesel, International Journal of Advanced Scientific & Technical Research, 3(5), pp , [16] D. Srikanth, M.V.S. Murali Krishna, P. Ushasri, and P.V. Krishna Murthy, Performance exhaust emissions, and combustion characteristics of cotton seed oil based biodiesel in ceramic coated diesel engine. International Journal of Mechanical Engineering, 2(5), pp , [17] R.P. Chowdary, M.V.S. Murali Krishna, and T.Kishen Kumar Reddy, Studies on exhaust emissions from ceramic coated diesel engine with waste fried vegetable oil based biodiesel, International Journal of Mechanical Engineering and Technology, July, 5(7), pp ,2014. [18] N. Janardhan, P. Ushasri, M.V.S Murali Krishna, and P.V.K. Murthy, Performance of biodiesel in low heat rejection diesel engine with catalytic converter. International Journal of Engineering and Advanced Technology, 2(2), ,2012. Volume 3, Issue 9, September 2014 Page 331