List of contributors Woodhead Publishing Series in Energy

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2 Contents List of contributors Woodhead Publishing Series in Energy Preface ix xiii xix 1 Rechargeable lithium batteries: key scientific and technological challenges 1 M. Bini, D. Capsoni, S. Ferrari, E. Quartarone, P. Mustarelli 1.1 Introduction Current market position of rechargeable lithium batteries, chiefly as far as concerns the portable electronics Major fundamental and technological challenges in the development of rechargeable lithium batteries Future trends and developments Sources of further information 13 References 14 Part One Materials and characterization 19 2 Materials for positive electrodes in rechargeable lithium-ion batteries 21 F. Liu, P.P. Mukherjee 2.1 Introduction Overview of different metal oxide cathode materials Lithium intercalation mechanism 27 Acknowledgments 37 References 37 3 Catalytic cathode nanomaterials for rechargeable lithium air batteries: status and challenges 41 H. Cheng, K. Scott 3.1 Introduction Catalysts for air cathodes Support materials for air cathodes Future trends Sources of further information and advice 65 References 67

3 vi Contents 4 Electrolytes for rechargeable lithium batteries 73 M. Montanino, S. Passerini, G.B. Appetecchi 4.1 Introduction Organic liquid electrolytes Ionic liquid electrolytes Polymer electrolytes Solid inorganic electrolytes Future trends Sources of further information and advice 98 References 98 Appendix: list of acronyms Materials and technologies for rechargeable lithium sulfur batteries 117 N. Azimi, Z. Xue, S.S. Zhang, Z. Zhang 5.1 Introduction Fundamental chemistry of lithium sulfur (Li S) battery Problems and challenges Current advances in the Li S battery Conclusions and outlook 138 References Electrochemistry of rechargeable lithium air batteries 149 J. Hou, X. Jie, J. Graetz, M.W. Ellis, R.B. Moore, K. Uosaki 6.1 Introduction Fundamental electrochemical analysis of the lithium air (Li air) battery Application of model electrode Future trends 176 References Electrochemical characterization of rechargeable lithium batteries 183 C. Villevieille 7.1 Introduction Advantages and disadvantages of ex situ and in situ/operando techniques Common in situ cell designs Bulk characterizations Surface characterizations Optical characterizations Conclusion 224 Acknowledgments 224 References 224

4 Contents vii 8 Atomistic modeling of the behavior of materials in rechargeable lithium-ion and lithium air batteries 233 P. Kaghazchi 8.1 Introduction Method Si anodes Initial stage of solid electrolyte interphase (SEI) formation on Si surfaces Sn anodes Role of defective graphene in lithium air (Li air) battery cathodes Conclusions and outlook 256 Acknowledgments 257 References 258 Part Two Performance and applications Aging and degradation of lithium-ion batteries 263 N. Omar, Y. Firouz, H. Gualous, J. Salminen, T. Kallio, J.M. Timmermans, Th. Coosemans, P. Van den Bossche, J. Van Mierlo 9.1 Introduction Methodology Results Conclusions 277 References System-level management of rechargeable lithium-ion batteries 281 A.G. Stefanopoulou, Y. Kim 10.1 Introduction Battery state estimation Battery cell equalization Battery thermal management Conclusion 297 References Environmental performance of lithium batteries: life cycle analysis 303 M. Messagie, L. Oliveira, S. Rangaraju, J.S. Forner, M.H. Rivas 11.1 Introduction Problem setting: environmental impacts and lithium resource availability Depletion of metal resources: the case of lithium Methodology: life cycle assessment of batteries Results: life cycle impact assessment Conclusions 316 References 317 Appendix: abbreviations 318

5 viii Contents 12 Rechargeable lithium batteries for energy storage in smart grids 319 K. Zaghib, A. Mauger, C.M. Julien 12.1 Introduction Energy storage Lithium-ion batteries Supercapacitors Vehicle-to-grid Future trends 341 References Rechargeable lithium batteries for medical applications 353 M.J. Cleland 13.1 Introduction Critical care and patient monitoring Defibrillation Heart failure Circulatory assist devices Biomedical engineering Summary 365 References Rechargeable lithium batteries for aerospace applications 369 W.Q. Walker 14.1 Introduction Primary aerospace applications Recent aerospace-related lithium/lithium-ion (Li/Li-ion) battery failures Future trends Sources of further information 382 References 382 Index 385

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