Compact State of the Art Methanol as a Marine Fuel. Göteborg 8th May 2014 Ulf T Freudendahl

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1 Compact State of the Art Methanol as a Marine Fuel Göteborg 8th May 2014 Ulf T Freudendahl

2

3

4 The Immediate Challenge g NOx/kWh IMO NOx Technical code NOx Tier II (Global) 12 NOx Tier III (NOx emission control areas) rpm

5 Heavy Fuel Oil + Scrubber or Marine Gas Oil max 0.1% Sulphur

6 LNG or Methanol Natural Gas has potential to be a very important energy source for marine propulsion H H C H H Methanol is also an efficient energy carrier with high potential for marine propulsion and with possibilities O to be renewable H C H H H

7 CO2 and particles Methanol LNG MGO/Fuel oil kg CO2/ MJ. Particles almost zero kg CO2/MJ. Particles almost zero kg CO2/MJ. Particles considerable

8 Rules and regulations for transportation of gases and low flashpoint liquids International Code for the Construction and Equipment of Ships Carrying Liquefied Gases in Bulk. The IGC Code International Code for the Construction and Equipment of Ships Carrying Dangerous Chemicals in Bulk. The IBC Code

9 Existing Rules & regulations for low flash point fuels. IMO Res MSC.285(86). INTERIM GUIDELINES ON SAFETY FOR NATURAL GAS-FUELLED ENGINE INSTALLATIONS IN SHIPS. The IGF-Code. Adresses only natural gas as fuel. LR. Rules and Regulations for the Classification of Natural Gas Fuelled Ships. Adresses natural gas and natural gas in combination with oil. DNV. Gas Fuelled Ship Installations. Adresses natural gas as fuel and gives opening for other fuels after special consideration. Other Class Societies Rules.

10 The DRAFT INTERNATIONAL CODE OF SAFETY FOR SHIPS USING GASES OR OTHER LOW FLASH POINT FUELS (IGF CODE). Under development. Intended fuels: Natural Gas (LNG) CH4 IGF Code Part A-1 Propane C3H8 Butane (i and n) C4H10 Propane/Butane mixtures Ethyl alcohol C2H5OH IGF Code Part A-2 Methyl alcohol CH3OH IGF Code Part A-2 Hydrogen H2 Dimethyl-ether CH3OCH3

11 Preamble General & Def. Goal & funct. req. General requir. Ship deasign and arr. Fuel containment syst material & gen pipe design Bunkering Fuel supply to consumers Power generation Fire safety Explosion protection Ventilation Electrical installation Control, monitoring & safety syst Alternative design Manufacture, workmanship & test Training an op requirement Op requirements (bunkering) Draft IGF Code. Gap LNG - Methanol GAP Matrix LNG and Methanol A A A A A-1 A-1 A-1 A-1 A-1 A-1 A-1 A-1 A-1 A-1 A-1 A-1 B B B ) Valid for LNG as well as methanol Partly valid for methanol or valid after interpretration Not valid for methanol Additional requirements for Methanol

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13 LR has Rules in draft. Provisional Rules and Regulations For the Classification of Methanol Fuelled Ships Estimated to be finished March To be under LR Technical Committe in November 2014

14 LNG Fuelled vessels. Newbuildings. LNG-carriers. Long and excellent experience. Glutra. Jan Now Around 100 existing ships and confirmed orders.

15 Conversion from HFO to LNG. BIT VIKING. 2 x 500 m3 cryogenic tanks on deck

16 VIKING GRACE LR Rules Gas storage tanks are to be located on the open deck or, where not practicable, in enclosed or semi-enclosed spaces.

17 OSV Viking Energy Installation of the LNG storage tank Stainless steel vacuum insulated thermo tank provided by CRYO AB Volume 220 m 3 Design pressure 9 bar Refuelling ton LNG every 10th day 17

18 Methanol fuelled newbuildings 7 x dwt Chemical Tankers on order. MAN S50ME-B9.3-LGI Two stroke high pressure gas (methanol) engine

19 MS MARINEX. Tanker for Oil Products and Chemicals. Source: MARINVEST

20 Conversion to Methanol: 1 +?

21 2CH 3 OH CH 3 OCH 3 + H 2 O Liquid methanol Temp increase to 200 C Catalytic reactor approx 90% conversion Does not work as diesel fuel Modified diesel engine Pressure increase to 16 bar Service tank 1600 L DME 260 L Water 140 L Me SPIRETH

22 LNG Terminal Nynäshamn m3. Inagurated 2011

23 LNG Feeder Tanker for Liquefied Gas

24 LNG Bunkering barge. Tanker for Liquefied gas

25 Methanol can be stored in tanks similar to tanks for petroleum products.

26 Methanol tank at Perstorp ton per year

27 Tanker for Oil and Chemicals

28 Bunker vessel oil & methanol Tanker for Oil and Chemicals

29 Ships other than chemical carriers - transporting methanol DNV Pt 5 Sec 8 B 102. Where not bound by bottom shell plating or pump room, the tanks shall be surrounded by cofferdams.

30 Double walled High pressure fuel pipes Ballast tank converted to methanol fuel tank High pressure pump room Transfer pump room

31 Methanol in integral tanks and service tank on deck

32 Fuel storage onboard and ashore. LNG storage require complex and expensive fuel containment systems. Methyl alcohol is far less complicated to store.

33 WÄRTSILÄ & MAN

34 The Great Challenge Established targets 2C Target of global temperature increase COP 15 meeting December 2009 in Copenhagen organized by United Nations Framework on Climate Change UNFCCC 50-85% Global GHG emission level in 2050 of todays level in order to reach 2C target according to Intergovernmental Panel On Climate Change IPCC % EU target for CO2 emission reduction by 2050 Complication All scenarios from IPCC (Intergovernmental Panel on Climate Change) shows that GHG emission will increase not decrease

35 atmospheric co2 concentration ppmv Total CO2 GtC The Great Challenge 1200 IPCC CO2 concentration 40 IPCC CO2 emission C target Year Year

36 Georg A. Olah Nobel Price Chemistry 1994

37 CO2 + 3H2 = CH3OH + H2O Carbondioxid to Methanol Methanol

38 Renewable Energy Source: METANEX Corporation.

39 Special Gas Carrier - Transport of CO2

40 Summary Methanol is a clean low flash point fuel fullfilling upcoming requirements. The methanol fuel containment system onbord and the infra structure ashore are considerably less expensive than for LNG Rules and regulations exist to a large extent and are under further development. In many parts similar requirements as for LNG. There is no doubt we can handle safety issues re methanol onbord used for fuel The existing methanol industry can coop with an increase in demand of 20 mill ton.

41 Thank you for listening.

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