Additin RC 9321 Additive Package

Transcription

1 Technical Data Sheet Additin Additive Package Type Ashless multifunctional oxidation and rust inhibiting additive package - for R&O oils, hydraulic fluids HL, gear oils CL according to: DIN 51524, part 1 (HL); DIN 51517, part 2 (CL); AFNOR NF E (HL); Cincinnati-Machine P-38 (HL-32), P- 55 (HL-46), P-54 (HL-68), P-57 (HL-15), P-62 (FC-1) - for turbine oils according to: DIN 51515, part 1 (L-TD), part 2 (L-TG); ISO 868; Siemens TLV 913 4/1; British Standard BS 489; General Electric GEK F; MIL-L D; CEGB Standard 271; Brown Boveri HTGD 9117; U.S. Steel 12; Westinghouse Electric Corp. Turbine Oil Spec.; Solar ES 9-224; Alstom HTGD 9117 V1 S - for compressor oils according to: DIN 5156 (VBL, VCL, VDL); ISO / DP 6521 (DAA, DAB, DAH, DAG) Technical data* Composition Appearance Nitrogen Sulphur Phosphorus Viscosity, 4 C (ASTM-D 445) Density, 2 C (ASTM-D 1298) Flash point, COC (ASTM-D 92) Mineral oil content combination of antioxidants, corrosion inhibitors, non-ferrous metal deactivators light brown, clear, low viscosity liquid approx. 3.6 weight approx. 7. weight approx..5 weight approx. 8 mm²/s approx. 1 kg/m³ > 13 C approx. 5 weight Application - R&O oils - hydraulic fluids HL - turbine oils - gear oils CL - compressor oils - greases Additin is an ashless additive package with outstanding oxidation and corrosion inhibiting properties. Additin is particularly recommended for use in the formulation of lubricants for which high performance demands have to be met: - high oxidation stability Page 1 of 3 Edition: 13. Feb 212

2 Technical Data Sheet - good thermal stability - excellent hydrolytic stability - no sludge formation - very low acid number - good protection against corrosion of steel and non-ferrous metals - good demulsifying behaviour - good foam behaviour These properties can be obtained at low treat level in a broad range of different base oils, especially in PAO, HC, HVI and Group II base oils. The recommended treat level is in the range of.3 to.6 by weight. Depending on application Additin may cause yellowish discolouration due to oxidative processes. Page 2 of 3 Edition: 13. Feb 212

3 Technical Data Sheet Solubility Soluble in mineral oils, PAO, HC, HVI and Group II base oils. However, it is necessary to verify the solubility in the base oils used and the compatibility with other additives. Test results see technical report Packing unit 2 kg bunghole drums Storage conditions in a dry place at room temperature approx. 24 months. This product is liable to crystallization at low temperatures. If this occurs, gentle warming up to 4-5 C with agitation will ensure homogeneity of the product without adverse effects. Local overheating - above 6 C - must be avoided. Handling Consult material safety data sheet (MSDS) for additional handling information on Additin = registered trade mark * The analytical data are guide values. Additin is on EINECS and TSCA inventory. Our technical advice - whether verbal, in writing or by way of trials - is given in good faith but without warranty, and this also applies where proprietary rights of third parties are involved. It does not release you from the obligation to test the products supplied by us as to their suitability for the intended processes and uses. The application, use and processing of the products are beyond our control and, therefore, entirely your own responsibility. Should, in spite of this, liability be established for any damage, it will be limited to the value of the goods delivered by us and used by you. We will, of course, provide products of consistent quality within the scope of our General Conditions of Sale and Delivery. LANXESS Deutschland GmbH Business Unit Additives Kennedyplatz 1 D-5569 Cologne, Germany lubricant.additives@lanxess.com Page 3 of 3 Edition: 13. Feb 212

4 Performance Data according to: DIN 51524, p.1 (HL); DIN 51517, p.2 (CL); ISO 868; ASTM D 434; AFNOR NF E (HL); JIS K 2213; BS 489; DIN 51515, p.1(l- TD), p.2(l-tg); Cincinnati-Milacron P-38 (HL-32), P-55 (HL-46), P-54 (HL-68), P-57 (HL-15), P-62 (FC-1); Siemens TLV 913 5; GEK 32568F/G; GEK 28143A; MIL-L D; CEGB 271; Brown Boveri HTGD 9117; Alstom HTGD V1 S; Solar ES 9-224, U.S.Steel 12; Westinghouse Electric Corp. Turbine Oil Spec. Additin Circulating oil package for base stocks group II, III and IV Base oil: IDW-VHVI base oil ISO VG 32 Additive:.3 wt or.6 wt Additin Base Stock Characteristics Test method Unit Test results Source of Base Oil IDW-VHVI Viscosity ISO VG 32 Viscosity Index 128 C (aromatic) C (paraffinic) C (naphthenic-monoring) C (naphthenic-multiring) Sulphur ppm < 5 Flash Point COC (ASTM D 92) C 23 Lubricant Characteristics.3 wt.6 wt Most severe requirements Acid number (ASTM D 974) mgkoh/g.6.7 BS 489, GEK, Siemens TLV max..2 Viscosity at 4 C (ASTM D 445) mm²/s group II, III, IV base stock page 1 of 4 Edition September 213

5 Surface Characteristics Test method Unit Test results Most severe requirements.3 wt.6 wt Air release properties / 5 C (DIN p.1) min 2 3 ALSTOM HTGD 9117: max. 4 Water separation ability after steam treatment (DIN p.1) s DIN max. 3 Demulsification capacity / 54 C (ASTM D 141) oil-water emulsion separation time ml min Siemens TLV min max. 2 Foaming behavior Surface foam (ASTM D 892) sequence I 25 C sequence II 95 C sequence III 25 C / / / / / / ISO 868 (L-TGF and L-TGSE) 5 / 5 / 5 / Corrosion Protection Copper corrosion (ASTM D 13) 3 h / 1 C 24 h / 1 C 1a 1b - 2a 1a 1b - 2a GEK max. 1b - Steel corrosion (ASTM D 665) procedure A (distilled water) procedure B (synthetic sea water) pass pass pass pass pass (DIN, GEK) pass (Siemens TLV) EP / AW - Properties AW - Four Ball Test (DIN 5135, part 3) scar diameter [15 rpm / 1 h / 3 N] [18 rpm / 1 h / 4 N] (ASTM D 4127) [12 rpm / 1 h / 4 N, 75 C] mm mm mm.5.42 n. d Westinghouse - max..6 SOLAR ES max..9 mm group II, III, IV base stock page 2 of 4 Edition September 213

6 Test method Unit Test results Most severe requirements.3 wt.6 wt FZG gear test A 8.3 / 9 (visual) (DIN 51354, part 2) damage-load stage 1 (.5) 1 min. 8 (Siemens TLV-EP) min. 9 (Alstom HTGD) Thermo - Oxidative Stability TOST (ASTM D 431) [95 C, H 2O, O 2,, Fe and Cu catalyst] after 1 h: sludge TAN mg mgkoh/g Brown Boveri max. 1 max..3 ISO 868 TOST (ASTM D 943) [95 C, H 2O, O 2, Fe and Cu catalyst] time to TAN 2 mgkoh/g h > 7 > 14 GEK 17395A min. 7 RPVOT (ASTM D 2272) [15 C, H 2O, O 2, Cu catalyst] life time min GEK 17395A min. 1 RPVOT Modified (acc. to GEK A) [48 h / 121 C / 3 l N 2 per hour] life time decrease of lifetime compared with unmodified test Min GEK - max CIGRE (IP 28) [164 h / 12 C / soluble Fe and Cu cat. / 1 l O 2 per hour] TOP (total oxidation products) precipitate (sludge) ISO 868 max..4 max..25 Cincinnati Milacron (Procedure A) [168 h / 135 C / Fe and Cu cat.] viscosity, change neutralization number, change sludge Copper rod appearance Iron rod apprearance mg/1 ml *) < Cincinnati Milacron max. 5 max. 5 max. 25 max. 5 max. 1 Residue after distillation of 8 vol (DIN 51356, DIN 51551) conradson carbon residue wt n. d. <.1 GEK 32568F (ASTM D 524 or equivalent) max..1 n. d. = not determined *).4 wt group II, III, IV base stock page 3 of 4 Edition September 213

7 Test method Unit Test results Most severe requirements.3 wt.6 wt Oxidation stability at high temperature (168 h at 121 C) (DIN 51394) viscosity change (maximum) acid number change (maximum) metal specimen mass change: Steel Aluminium Cadmium Copper Magnesium mg KOH/g mg/cm² *) , n. d. = not determined *).4 wt Hydrolytic Stability Beverage Bottle Method (ASTM D 2619) Copper wt. loss acidity of water layer TAN in oil: h 48 h insoluble content appearance of copper strip (acc. to ASTM-D 13) mg/cm² mgkoh/25g mgkoh/g none 1b none 3a - 3b no requirements (good values) max..2 max. 4 - none max. 3 = registered trademark Edition September 213 Our technical advice whether verbal, in writing or by way of trials is given in good faith but without warranty, and this also applies where proprietary rights of third parties are involved. It does not release you from the obligation to test the products supplied by us as to their suitability for the intended processes and uses. The application, use and processing of the products are beyond our control and, therefore, entirely your own responsibility. Should, in spite of this, liability be established for any damage, It will be limited to the value of the goods delivered by us and used by you. We will, of course, provide products of consistent quality within the scope of our General Conditions of Sale and Delivery. Rhein Chemie Rheinau GmbH Postfach Düsseldorfer Strasse D Mannheim Germany Telephone: Telefax: info@rheinchemie.com group II, III, IV base stock page 4 of 4 Edition September 213

8 Performance Data according to: DIN 51524, p.1 (HL); DIN 51517, p.2 (CL); AFNOR NF E (HL); Cincinnati-Milacron P-55 (HL-46), DIN 51515, p.1(l-td), p.2(l-tg); Siemens TLV 913 4; BS 489; GEK A/C; MIL-L D; CEGB 271; Brown Boveri HTGD 9117; Alstom HTGD V1 S; U.S.Steel 12; Westinghouse Electric Corp. Turbine Oil Spec., Solar ES 9-224, JIS K Additin Turbine oil package for Chevron base stocks group II Base oil: group II Chevron Neutral Oil ISO VG 46 Additive:.4 wt Additin Base Stock Characteristics Test method Unit Test results Source of Base Oil Chevron USA Viscosity ISO VG 44.4 Viscosity Index 13 Sulphur <.15 Lubricant Characteristics.4 wt in Chevron base oil Most severe requirements Acid number (ASTM D 974) mgkoh/g.11 BS 489, GEK, Siemens TLV max..2 Viscosity at 4 C (ASTM D 445) mm²/s 44.4 Viscosity Index 13 group II Chevron base stock page 1 of 3 Edition November 212

9 Surface Characteristics Test method Unit Test results Most severe requirements.4 wt in Chevron base oil Air release properties / 5 C (DIN p.1) min 5 BS 489, Brown Boveri, DIN: max. 5 Demulsification capacity / 54 C (ASTM D 141) oil-water emulsion separation time ml min Siemens TLV min max. 2 Foaming behavior Surface foam (ASTM D 892) sequence I 25 C sequence II 95 C sequence III 25 C / / / ISO 868 (L-TGF and L-TGSE) 5 / 5 / 5 / Corrosion Protection Copper corrosion (ASTM D 13) 3 h / 1 C 24 h / 1 C 1a 1a GEK max. 1b - Steel corrosion (ASTM D 665) procedure A (distilled water) procedure B (synthetic sea water) pass pass pass (DIN, GEK) pass (Siemens TLV) EP / AW - Properties AW - Four Ball Test (DIN 5135, part 3) scar diameter [15 rpm / 1 h / 3 N] [18 rpm / 1 h / 4 N] (ASTM D 4127) [12 rpm / 1 h / 4 N, 75 C] mm mm mm ) Westinghouse - max..6 Solar ES Max..9 mm wt group II Chevron base stock page 2 of 3 Edition November 212

10 Thermo - Oxidative Stability Test method Unit Test results Most severe requirements.4 wt in Chevron base oil TOST (ASTM D 943) [95 C, H 2O, O 2, Fe and Cu catalyst] time to TAN 2 mgkoh/g h >1 RPVOT (ASTM D 2272) [15 C, H 2O, O 2, Cu catalyst] life time min wt wt DIN (L-TG) min. 3 h to TAN 2 mgkoh/g DIN (L-TG) min. 8 Cincinnati Milacron (Procedure A) [168 h / 135 C / Fe and Cu cat.] viscosity, change neutralization number, change sludge colour 168 h Copper rod appearance Copper weight loss Iron rod apprearance Iron weight loss mg/1 ml mg mg Cincinnati Milacron max. 5 max. 5 max. 25 max. 5 max. 1 Hydrolytic Stability Beverage Bottle Method (ASTM D 2619) Copper wt. loss acidity of water layer TAN in oil: h 48 h insoluble content appearance of copper strip (acc. to ASTM-D 13) mg/cm² mgkoh/25g mgkoh/g none 1b no requirements (good values) max..2 max. 4 - none max. 3 = registered trademark Edition November 212 Our technical advice - whether verbal, in writing or by way of trials - is given in good faith but without warranty, and this also applies where proprietary rights of third parties are involved. It does not release you from the obligation to test the products supplied by us as to their suitability for the intended processes and uses. The application, use and processing of the products are beyond our control and, therefore, entirely your own responsibility. Should, in spite of this, liability be established for any damage, it will be limited to the value of the goods delivered by us and used by you. We will, of course, provide products of consistent quality within the scope of our General Conditions of Sale and Delivery. Rhein Chemie Rheinau GmbH Postfach Düsseldorfer Strasse D Mannheim Germany Telephone: Telefax: info@rheinchemie.com group II Chevron base stock page 3 of 3 Edition November 212

11 Performance Data according to: DIN (KAA, KE) DIN 5156 (VBL, VCL, VDL) ISO / DP 6521 (DAA, DAB, DAH, DAG) Additin Applications for Compressor Oils Base oil: group I, III and IV base oil ISO VG 46 Additive:.6 wt Additin Base Stock Characteristics Test method Unit Test results Source of Base Oil Group I paraffinic mineral oil Group III IDW-VHVI Group IV PAO 8 Viscosity ISO VG Viscosity Index C (aromatic) C (paraffinic) C (naphthenic-monoring) C (naphthenic-multiring) Sulphur ppm 2. < 5 < 5 Flash Point COC (ASTM D 92) C Lubricant Characteristics Base stock.6 wt group I.6 wt group III.6 wt group IV Acid number (ASTM D 974) mgkoh/g Viscosity at 4 C (ASTM D 445) mm²/s compressor oil Edition September 211 page 1 of 4

12 DIN 5156 VBL For air compressor up to 14 C Test method Unit Test results Requirement base stock.6 wt group I.6 wt group III.6 wt group IV Conradson carbon residue after aging by passing air (DIN 51352, p. 1) carbon residue after aging max. 2. DIN 5156 VCL For air compressor up to 16 C (mobile up to 22 C) Conradson carbon residue after aging by passing air (DIN 51352, p. 1) carbon residue after aging max. 1.5 Residue after distillation of 8 vol (DIN 51356, DIN 51551) conradson carbon residue <.1 <.1 <.1 max..3 DIN 5156 VDL For air compressor up to 22 C Conradson carbon residue after aging air in the presence of Fe 2O3 (DIN 51352, p. 2) carbon residue after aging max. 2.5 Residue after distillation of 8 vol (DIN 51356, DIN 51551) conradson carbon residue viscosity at 4 C before distillation viscosity at 4 C after distillation mm²/s mm²/s < < < max ratio of viscosity max. 5 compressor oil Edition September 211 page 2 of 4

13 ISO/DP 6521 DAA, DAB, DAH, DAG Copper corrosion (ASTM D 13) 3 h / 1 C 24 h / 1 C 1a 1b - 2a 1a 1b - 2a 1a 1b - 2a DAA/DAB/DAH/DAG max. 1b - Steel corrosion (ASTM D 665) procedure A (distilled water) procedure B (synthetic sea water) DAA/DAB/DAH/DAG pass/ not required Test method Unit Test results Requirement ISO/DP 6521 base stock.6 wt group I.6 wt group III.6 wt group IV Demulsification capacity / 54 C (ASTM D 141) oil-water-emulsion separation time ml min DAB/DAH/DAG min max. 3 Conradson carbon residue after ageing by passing air (DIN 51352, p. 1) carbon residue after ageing evaporation loss DAA max. 1.5 max. 15 Conradson carbon residue after ageing air in the presence of Fe 2O 3 (DIN 51352, p. 2) carbon residue after ageing evaporation loss DAB max. 2.5 max. 2 Residue after distillation of 8 vol (DIN 51356, DIN 51551) conradson carbon residue viscosity at 4 C before distillation viscosity at 4 C after distillation mm²/s mm²/s < < < DAB max ratio of viscosity max. 5 compressor oil Edition September 211 page 3 of 4

14 Ammonia Compatibility base stock.6 wt group I.6 wt group III.6 wt group IV TOST modified* (ASTM-D943 mod.) Fresh Oil TAN Color mgkoh/g Oil after 15h TAN Color Heptane insoluble Copper weight change Soluble copper Copper appearance mgkoh/g mg mg ppm < 5 1b < 5 3a.1 < 3mg 1ppm Test conditions Mixture of air and ammonia gas Catalyst Temperature Duration Water 8.6L/h / 1.4L/h Copper 125 C 15h 1mL + 1mL every 24 hours = registered trademark Edition September 211 Our technical advice - whether verbal, in writing or by way of trials - is given in good faith but without warranty, and this also applies where proprietary rights of third parties are involved. It does not release you from the obligation to test the products supplied Rhein Chemie Rheinau GmbH Postfach Düsseldorfer Strasse D Mannheim Germany by us as to their suitability for the intended processes and uses. The application, use and processing of the products are beyond our control and, therefore, entirely your own responsibility. Should, in spite of this, liability be established for any damage, Telephone: Telefax: info@rheinchemie.com it will be limited to the value of the goods delivered by us and used by you. We will, of course, provide products of consistent quality within the scope of our General Conditions of Sale and Delivery. compressor oil Edition September 211 page 4 of 4

15 Performance Data according to: MORGOIL Lubricant New Oil Revision January 25 (for normal service oils) MORGOIL Advanced Lubricant New Oil Revision June 28 (for advanced service oils) Additin ashless package for Morgoil Base oil: group I mineral oil ISO VG 15 or ISO VG 46 Additive: 1.5 wt Additin Base Stock Characteristics Test method Unit Test results Source of Base Oil Exxon Mobil: Blend of core 6 and brightstock Exxon Mobil: Blend of core 6 and brightstock Viscosity ISO VG Viscosity Index C (aromatic) C (paraffinic) C (naphthenic) Sulphur.5.8 Lubricant Characteristics Exxon Mobil Base Stock 1.5 wt ISO VG wt ISO VG 46 Requirements Acid number (ASTM D 974) mgkoh/g.24.2 report Viscosity at 4 C (ASTM D 445) mm²/s ISO VG 15: 135 to 165 ISO VG 46: 414 to 56 Viscosity Index min. 9 Pourpoint (ASTM D 97) C ISO VG 15: max. -6 ISO VG 46: max. Flash Point (ASTM D 92) C min. 195 Morgoil page 1 of 3 Edition September 211

16 Surface Characteristics Test method Unit Test results Requirements In Exxon Mobil Base Stock (Low Temperature) Demulsibility (ASTM D 2711 and modified) free water water in oil emulsion ml ml 1.5 wt ISO VG wt ISO VG Normal Oil ISO VG 15 3 report 1. ISO VG report 1. Advanced Oil min. 3 max. 1.5 max. 1. Dynamic Demulsibility Endurance (UEC Dyn. Demuls. End. Test) water in oil after centrifuging oil in water after centrifuging Source for testing: UEC CMS Labs 4 Tech Center Drive Pittsburgh, PA (412) / 293 (412) (fax) not required not required max. 1 max. 1 Demulsification capacity / 82 C (ASTM D 141) oil-water-emulsion separation time ml min 4/4/ 15 4/4/ 15 4/ 37/ 3 <2 (ISO 15) <4 (ISO 46) not required Foaming behavior Surface foam (ASTM D 892) sequence I 25 C sequence II 95 C sequence III 25 C / / / / / / 15 / not required not required 5 / 5 / 5 / Corrosion Protection Copper corrosion (ASTM D 13) 3 h / 1 C 1a - 1b 1a - 1b max. 1 max. 1 Steel corrosion (ASTM D 665) procedure A (distilled water) procedure B (synthetic sea water) (optional) (optional) Thermo - Oxidative Stability RPVOT (ASTM D 2272) [15 C, H 2O, O 2, Cu catalyst] life time min 8 78 min. 8 min. 8 Morgoil page 2 of 3 Edition September 211

17 = registered trademark Edition September 211 Our technical advice - whether verbal, in writing or by way of trials - is given in good faith but without warranty, and this also applies where proprietary rights of third parties are involved. It does not release you from the obligation to test the products supplied by us as to their suitability for the intended processes and uses. The application, use and processing of the products are beyond our control and, therefore, entirely your own responsibility. Should, in spite of this, liability be established for any damage, it will be limited to the value of the goods delivered by us and used by you. We will, of course, provide products of consistent quality within the scope of our General Conditions of Sale and Delivery. Rhein Chemie Rheinau GmbH Postfach Düsseldorfer Strasse D Mannheim Germany Telephone: Telefax: info@rheinchemie.com Morgoil page 3 of 3 Edition September 211