Engine Performance and Economic Impact Study of Gasoline-Like Tyre Pyrolysis Oil in Thailand

Transcription

1 Engine Performance and Economic Impact Study of -Like Tyre Pyrolysis Oil in Thailand C. Wongkhorsub, N. Chindaprasert, S. Peanprasit Abstract The purpose of is paper is to study e comparing performance and efficiency of small gasoline engine using gasoline blended wi -like tyre pyrolysis oil () in difference blended ratios. The comparisons of economic impact of using e blended oils are also investigate. The Blended s are compared wi gasoline produced in Thailand by testing in gasoline engine (Honda GX140, four stoke, multi-purpose one cylinder, 144 CC). The testing is done by comparing performance of fuel which are torque, engine break power, fuel flow rate, generator output, BSFC (brake specific fuel consumption) based on e 3000 rpm engine rate. The result of e experiment shows at e torque output of e 100% blended is 94.2% lower compare to e normal gasoline, e BSFC of e 100% blended is 1.3% higher an normal gasoline but e ermal efficiency of e 100% blended is 1.86% higher an normal gasoline. Therefore, it is found at e 100% can be used to replace e normal gasoline in small engine but e best blended use in e engine is 25% blended ratio as e engine run smooly in long term wiout wax and tars in e Index Terms Pyrolysis, -Like Tyre Pyrolysis Oil, Engine Performance, Energy Cost. I. INTRODUCTION The fast depletion of petroleum fuel and e environmental issues have led to an intensive search for alternate fuels for internal combustion engines. One of e meods to derive alternate fuels is e conversion of waste substances to energy. Biomass based fuels like meanol, eanol etc. are some of e examples in which waste to energy is adopted, and ese are used as alternate fuels for e internal combustion engines. On e oer hand, due to e increase in automotive vehicle population, e disposal of waste automobile tyres has become essential. In Thailand, it is found at ere are about millions tyres has been discarded per year or approximately 1.7 million tons per year [1]. Different alternatives for tyre recycling, such as retreading, reclaiming, incineration, grinding, etc., have been used. However, all ese meods have significant drawbacks and limitations. Pyrolysis can be considered as a non-conventional meod for tyre recycling, which is currently receiving renewed attention. In e pyrolysis process mainly e rubber polymers are heated and decomposed to low molecular weight products, like liquid or Manuscript received April 5, This work was supported in part by Thailand Institute of Scientific and Technological Research and e Department of Mechanical Engineering, Faculty of Engineering, Rajamangala University of Technology Phra Nakhon, Thailand C. Wongkhorsub, N. Chindaprasert, and S. Peanprasit are wi e Department of Mechanical Engineering, Faculty of Engineering, Rajamangala University of Technology Phra Nakhon, Thailand ( chonlakarn.w@rmutp.ac., nataporn.c@rmutp.ac.) gases, which can be useful as fuels or chemicals source. In e past, several laboratory, pilot plant and even commercial attempts have been made to establish economic units for pyrolysis of tyres[2]. Tire pyrolysis has been investigated for more an 20 years. The process converts waste tire into potentially recyclable materials such as flammable gas, pyrolysis oil and carbon black [3]. Composition of e oil depends on reactor design and operating condition. Tire pyrolysis oil plant has been established around e world in order to produce e substitute liquid fuel for heating purpose as found at e tire pyrolysis oil have a high gross calorific value (GCV) of around MJ/kg [4]. Desulfurization process is needed for tire pyrolysis oil as e high concentration of sulfur in pyrolysis oil leads e emission of SO 2 and sulfate particular matter. The main purpose of e commercial scale of e pyrolysis oil is used as a replacement of bunker oil. Therefore, e tyre pyrolysis plant is not widely established due to e product usage and economic of scale. However, e attempt of developing tyre pyrolysis oil has been made by applying some catalysts for e purpose of product yield distribution and quality of e oil[5], distilling e tyre pyrolysis oil to become diesel-like tyre pyrolysis[6][7]. The use of e tyre pyrolysis oil has been research in diesel engine and found e potential of using e diesel-like tyre pyrolysis to replace e diesel oil in small diesel engine [8][9]. However, one of e by-product of distilling e pyrolysis oil is napha oil. It is used primarily as feedstock for producing gasoline. Thus, e researcher is investigating e potential of using e napha or e gasoline-like tyre pyrolysis oil in small gasoline engine in order to be an alternative fuel for e small scale agriculture This paper presents e engine performances wi energy output in kilowatt-hour applying blended various compositions of gasoline-like tire pyrolysis oil () and diesel oil in agriculture gasoline The gasoline-like tire pyrolysis oil was researched by distilled e tyre pyrolysis oil between C so as to obtain e gasoline-like tyre pyrolysis oil. The economic analysis is investigated in terms of cost of fuel compare wi energy output in kilowatt-hour applying blended various percentage of e and gasoline in small gasoline engine in order to predict e behavior of cost in each blended oil. II. TYRE PYROLYSIS A. -like Tyre Pyrolysis Oil() Pyrolysis process is a chemical and ermal process at reacts to decompose organic material under oxygen-free conditions. The products of pyrolysis include oils, gases and char. For tire pyrolysis oil, it has been researched at e tire ISBN:

2 pyrolysis oil is a complex mixture of organic compounds of 5-20 carbons wi high proportion of aromatics [10]. The process of tyre pyrolysis is started from collecting e waste tyre and shred it to small pieces to be suitable to feed in to e pyrolysis reactor. In general, product yields from pyrolysis are varied wi temperature. The oil production yield of tire pyrolysis process has a maximum at 350 C and decomposes rapidly above 400 C [11]. The pyrolysis oil used in is research is processed from a batch pyrolysis reactor wi desulfurization process. The tyre pyrolysis oil sample was prepared using a commercial tyre pyrolysis plant in Thailand. The average product yield of tyre pyrolysis process is distinguished into 3 types of product as shown in Fig % by Weight of Wire Scrap and Carbon Black Recycle Waste Tyres Shredder Pyrolysis Process 35.8% by Weight of Pyrolysis Oil Distill o C -Liked Tyre Pyrolysis Oil () 7.5% by weight of Gas Product Fig. 1. Process and Avarage Product Yield of Tyre Pyrolysis Process. The sample oil was distilled by flash distillation meod at temperatures between C respect to e distill temperature of light to heavy napha (C6-C14) wiout reforming process and additives. B. Blending and Properties The from pyrolysis and distill process is blended wi e commercial in Thailand in e variation of 10%, 25%, 50%, 100% by volume. The basic properties of e blended oil in ratio variation were analyzed and compared to gasoline by e loboratory of Energy Technology Department, Thailand Institute of Scientific and Technological Research, as shown in Table 1. TABLE I: THE PROPERTIES OF THE BLENDED WITH GASOLINE LHV Density Flash (Kcal/kg) Point C H O o C 100% 12, > % 11, > , > , > , > A. Engine Performance III. METHODOLOGY Engine performance indicates e effects of a oil in e The determination of e engine performance in is experiment are break torque (T ), engine break power ( P ), break specific fuel consumption ( Bsfc ), and break ermal efficiency ( ). These several parameters can be obtained by measuring air and fuel consumption, torque and speed of e engine, and heating value of e oil. The performance parameters can be calculated by equations as followed [12][13]. Break torque (T ) is an indicator of e function of break torque in Nm calculated by e moment of engine arm connected to weight scale as: T Fd (1) Where F is force of engine arm applied to e load in N, and d is e distance of engine arm from center of e rotor to e load. Engine break power ( P ) is delivered by engine and absorbed load. It is e product of torque and angular engine speed where P is engine break power in kw, N is angular speed of e engine in rpm as: 2 NT P Break specific fuel consumption ( Bsfc ) is e comparison of engine to show e efficiency of e engine against wi fuel consumption of e engine in g/kw-hr where ( m ) is e fuel consumption rate in g/hr as: Bsfc m f P The percentage of break ermal efficiency of e engine ( ) is related to engine break power ( P ) and e total energy input to e engine which is Q LHV lower heating value of fuel in kj/kg applied to e fuel consumption rate as: P m f Q LHV 3600 B. Economic Impact The economic impact of is research is done under e approach of comparing e energy cost of using e variation of as a fuel for gasoline However, e energy consumption rate of each fuel are difference erefore, e best indicator at is suitable for all situations to predict e use of oil in terms of economic analysis should be energy cost consumption per power output as: Cost PO bsfc E PO (2) (3) (4) (5) f ISBN:

3 Where E is e cost of energy consumption per power output in Baht/kW-hr, PO is e density of calculating oil. Equation (5) shows e cost of energy compared regarding to e efficiency. IV. EXPERIMENTAL SET UP This experimental research is designated to apply e in small scale engine and study e experimental result of using e variation of as fuels. Therefore, engine specification, schematic of e engine measurement, engine operating condition and experimental results are described in is part. A multi-purpose agricultural 4-stroke, overhead single cylinder gasoline engine (Honda GX140) is used for e experiment. The engine specifications are shown in Table II. Engine Description Engine Brand Bore x Stroke Swept Volume /Cylinder TABLE II: ENGINE SPECIFICATION Specification Honda GX mm. x 45 mm. 144 cc. Max. Output, HP/rpm 5(3.7) /3600 rpm Ignition system Heat Exchanger Sytem Consumption Weight 1.0 kg-m Ignition Coil Air Type 0.81 Gallon/Hr. 14 Kg. Schematic of e experimental set up is shown in Fig. 2. The engine equipped wi measuring elements including weighing device, manometer, orifice plate, tachometer, ermocouple and ermocouple at e exhaust. Weighting Device Air Box Orifice Air inlet Engine Generator Load Torque meter Thermocouple Exhaust Tachometer Fig. 2. Schematic of e experimental setup Amp Meter, Volt Meter As e experiment was operate in constant speed, e torque output from e experiment is measured by e breaking force absorbed by e load. The absorbed load is produced by a set of 5x100W light bulbs and 13x500W light bulbs connect in series togeer in order to vary e absorbed load. The blended s wi e commercial in Thailand in e variation of 10%, 25% 50% 100% by volume were applied in e experiment. The experiments were conducted by starting engine wi e sample fuel. The operating conditions were set at a rated engine speed 3000 rpm. Loads were applied from 500 W and stepped up until reached e maximum load. The power output is measured by e watt meter which is lower an e load regarding to e efficiency of e generator. The air box is applied to stabilize e air flow into e engine as e air box volume is 500 times e volume of e engine cylinder. Orifice plate flow meter is applied for air flow measurement. consumption is measured from e differential of e fuel in time. A chromel-alumel ermocouple was installed to measure e exhaust gas temperature. At e end of e test e engine was run wi gasoline fuel for a while to flush out from e V. EXPERIMENTAL RESULT The Stoichiometric Air-fuel Ratio of fuel is calculated regarding to e properties of e blended oil in table I are shown in Table III. TABLE III: STOICHIOMETRIC AIR-FUEL RATIO OF FUEL 10% 25% 50% 100% AF Stoich The stoichiometric air fuel ratio of e variation of e fuels in is experiment shows at e obtains e highest number whereas e 100% is e lowest number. Therefore, is number could predict e trend of fuel consumption rate of each fuel. The more ratio of causes e high fuel consumption. The experimental testing shows at e engine performance of variation of blended fuels are comparable to e gasoline. The trend of engine performance which are torque, break specific fuel consumption and e ermal efficiency of all testing oils including 100% is in e same direction. It shows at e is able to use as a replacement of e gasoline in term of engine efficiency. Fig.3. illustrates e relation of e break specific fuel consumption and e engine break power. Fig. 4 illustrates e ermal efficiency of e fuels in various engine break power. The ermal efficiency of e is higher an e gasoline by reason of e wide range of distillation temperature might cause pre-ignition and knocking. Though e engine performance of e is comparable to gasoline, ere are some physical limitation at found in e experiment at might affect using e in long term. It is shown in Fig. 5. at e exhaust temperature of e is slightly higher an gasoline also, e engine needs to be flushed off wi gasoline after e experimental testing of due to e wax occurred in The optimum load for using blended and gasoline in is experiment is at e engine brake power range of medium load, 1,300-1,700 W as it performs well in terms of Bsfc and ermal efficiency. The ermal efficiency of gasoline is lower an e blended s due to e lower heating value as shown in table I. The result of e experiment shows at e torque output of e 100% blended is 94.2% lower, e BSFC of e 100% blended is 1.3% higher an normal gasoline but e ermal efficiency of e 100% blended is 1.86% higher an normal gasoline in average load. ISBN:

4 Bsfc (g/kw hr) % % Fig. 3. Variation of brake specific fuel consumption wi engine brake power. ηt(%) ,100 1,300 1,500 1,700 1,900 2,100 50% 100% Fig. 4. Variation of ermal efficiency wi engine brake power. Exhaust Temperature ( C) E (Baht/kW-Hr) % 100% Fig.5. Variation of exhaust temperature wi engine brake power % 100% ,100 1,300 1,500 1,700 1,900 2,100 Fig. 6. Variation of e cost of energy consumption per power output wi engine brake power. The torque output of e 25% blended is 98.2% lower compare to e normal gasoline, e BSFC of e 25% blended is 0.32% higher an normal gasoline in medium load but e ermal efficiency of e 100% blended is 0.27% higher an normal gasoline in average load. It shows at e 25% blended has engine performance similar to e pure gasoline. As found in e experiment at e is potentially replacing gasoline, e cost of is anoer concerned factor. Since e fuel consumption of e sample fuels are varies, e research use energy cost consumption per power output to indicate e economic impact of e samples. The cost is 20 Baht per liter whereas e gasoline cost is 48 Baht per liter. The energy consumption cost indicates at e use of is economically comparable to gasoline. Though e engine performance of e blended s is slightly lower an gasoline, e cost of fuel is significantly lower as shown in Fig. 6. VI. CONCLUSION Regarding to e engine performance, operating condition and e economic comparison, e potential blended is 25% blended as e engine performance is similar to normal gasoline but e cost of oil is 16.6% lower an gasoline. However, e experimental testing of e compares to gasoline demonstrates at e is a potentially substitution of e gasoline in terms of engine efficiency. The in is research has been distilled by flash distillation which might cause e instability effect of e oil. Therefore, e should be improved by chemical process and distill in commercial scale distillation plant in order to obtain quality if e purpose of e oil production is for sale in commercial scale. It should be respected at e is produce from one source of waste. The using is one of e options to turn waste to energy which not only obtain e energy but also reduce e waste from e area. The environmental value of e product should be added to e economic impact study. The environmental impact in terms of pollution at e exhaust is also anoer concerning factor as e tyre pyrolysis process requires desulfurization. ACKNOWLEDGMENT The auors would like to acknowledge a tire pyrolysis plant to sponsor us e oils. The auors are also grateful for e laboratory support of Energy Technology Department, Thailand Institute of Scientific and Technological Research. The research was conducted by researchers in e pyrolysis research group, in support of Rajamangala University of Technology Phra Nakhon.. REFERENCES (Periodical style) [1] N.A. Dung, R. Klaewkla, S. Wongkasemjit, S Jitkarnka, ".Light olefins and light oil production from catalytic pyrolysis of waste tire" Journal of Analytical and Applied Pyrolysis, Volume 86, issue 2, pp November, 2009,. ISSN: DOI: /j.jaap [2] G. O. Young Synetic structure of industrial plastics (Book style wi paper title and editor) in Plastics, 2nd ed. vol. 3, J. Peters, Ed. New York: McGraw-Hill, pp , [3] Miltner W. Wukovits T. Pröll and A. Friedl Renewable hydrogen production: a technical evaluation based on process simulation Journal of Cleaner Production, vol 18, pp , [4] P. T. Williams R. P. Bottrill and A. M. Cunliffe Combustion of tire pyrolysis oil Trans IChemE vol. 76, pp , Nov [5] S. Boxiong W. Chunfei L. Cai G. Binbin W. Rui Pyrolysis of waste tyres: The influence of USY catalyst/tyre ratio on products Journal of Analytical and Applied Pyrolysis, Volume 78, Issue 2, pp , Mar [6] S. Murugan, M. C. Ramaswamy, and G Narajan, The Use of Oil in Diesel Engines, Waste Management, Vol.28, , [7] C. Wongkhorsub, N. Chindaprasert and S. Peanprasit, Engine Performance and Economic Impact Study of Diesel-Like Tire Pyrolysis Oil. 7Th International Conference on Renewable Energy Sources (RES 13) ISBN: , , [8] S. Murugan M. C. Ramaswamy and G. Narajan Performance emission and combustion studies of a di diesel engine using distilled ISBN:

5 tyre pyrolysis oil-diesel blends Processing Technology, vol. 89, pp , [9] C. Wongkhorsub and N. Chindaprasert, A Comparison of e Use of Pyrolysis Oils in Diesel Engine, Energy and Power Engineering Part I, Volume 5, Number 4B, , July [10] Isabel de Marco Rodriquez, M. F. Laresgoiti, M. A. Cabrero, A. Torres M. J. Chomon B. Caballero Pyrolysis of scrap tyres Processing Technology, vol. 72, pp. 9-22, [11] Y. M. Chang On pyrolysis of waste tire: degradation rate and product yields Resources Conservation and Recycling, vol. 17 pp , [12] O. Arpa R. Yumrutas Z. Argunhan Experimental investigation of e effects of diesel-like fuel obtained from waste lubrication oil on engine performance and exhaust emission Process Technology vol. 91, pp , [13] I. Sezer Thermodynamic performance and emission investigation of a diesel engine running on dimeyl eer and dieyl eer International Journal of Thermal Sciences, vol. 50, pp , C. Wongkhorsub is a lecturer in Mechnical Engineering Department, Faculty of Engineering, Rajamangala University of Technology Phra Nakhon, Thailand. She received her Ph.D. in Renewable Energy from e University of Nottingham in Her research focuses on renewable energy related on biomass and ermal system. ISBN: